Chemistry: A Molecular Approach Selected Solutions Manual, Books a la Carte Edition
4th Edition
ISBN: 9780134554259
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 10, Problem 23E
Interpretation Introduction
Interpretation: The number of molecular orbitals are approximated by a linear combination of atomic orbitals which are related to the number of atomic orbitals used in the approximation.
Concept Introduction:
The number of molecular orbitals estimated by a linear combination of atomic orbitals(LCAO) is equal to the number of atomic orbitals used in the calculation.
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4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how
you confirmed the structure.
5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of
Limonene.
6. (1 pts) Predict the 1H NMR spectral data of R-Limonene.
Proton NMR: 5.3 pon multiplet (H Ring
Part VI.
Ca H 10 O is the molecular formula of compound Tom and gives the
in the table below. Give a possible structure for compound Tom.
13C
Signals summarized
C1
C2
C3
C4
C5
C6
C7
13C shift (ppm)
23.5
27.0
33.0
35.8
127
162
205
DEPT-90
+
DEPT-135
+
+
2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at
373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and
molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.
Chapter 10 Solutions
Chemistry: A Molecular Approach Selected Solutions Manual, Books a la Carte Edition
Ch. 10 - Prob. 1SAQCh. 10 - Prob. 2SAQCh. 10 - Prob. 3SAQCh. 10 - Prob. 4SAQCh. 10 - Prob. 5SAQCh. 10 - Prob. 6SAQCh. 10 - Prob. 7SAQCh. 10 - Prob. 8SAQCh. 10 - Prob. 9SAQCh. 10 - Q10. Apply molecular orbital theory to predict...
Ch. 10 - Q11. Apply molecular orbital theory to determine...Ch. 10 - Q12. Which hybridization scheme occurs about...Ch. 10 - Q13. Which molecular geometry results when a...Ch. 10 - Prob. 14SAQCh. 10 - Prob. 15SAQCh. 10 - 1. Why is molecular geometry important? Cite some...Ch. 10 - 2. According to VSEPR theory, what determines the...Ch. 10 - 3. Name and sketch the five basic electron...Ch. 10 - 4. Explain the difference between electron...Ch. 10 - 5. Give the correct electron and molecular...Ch. 10 - 6. How do you apply VSEPR theory to predict the...Ch. 10 - Prob. 7ECh. 10 - Prob. 8ECh. 10 - 9. In valence bond theory, what determines the...Ch. 10 - 10. In valence bond theory, the interaction energy...Ch. 10 - Prob. 11ECh. 10 - Prob. 12ECh. 10 - 13. How is the number of hybrid orbitals related...Ch. 10 - Prob. 14ECh. 10 - Prob. 15ECh. 10 - 16. Name the hybridization scheme that corresponds...Ch. 10 - Prob. 17ECh. 10 - Prob. 18ECh. 10 - 19. What is a bonding molecular orbital?
Ch. 10 - 20. What is an antibonding molecular orbital?
Ch. 10 - 21. What is the role of wave interference in...Ch. 10 - Prob. 22ECh. 10 - 23. How is the number of molecular orbitals...Ch. 10 - 24. Sketch each molecular orbital.
a. σ2s
b.
c....Ch. 10 - Prob. 25ECh. 10 - Prob. 26ECh. 10 - Prob. 27ECh. 10 - Prob. 28ECh. 10 - Prob. 29ECh. 10 - 30. Write a short paragraph describing chemical...Ch. 10 - 31. A molecule with the formula AB3 has a trigonal...Ch. 10 - 32. A molecule with the formula AB3 has a trigonal...Ch. 10 - 33. For each molecular geometry, list the number...Ch. 10 - Prob. 34ECh. 10 - 35. Determine the electron geometry, molecular...Ch. 10 - 36. Determine the electron geometry, molecular...Ch. 10 - 37. Which species has the smaller bond angle, H3O...Ch. 10 - Prob. 38ECh. 10 - 39. Determine the molecular geometry and sketch...Ch. 10 - Prob. 40ECh. 10 - Prob. 41ECh. 10 - Prob. 42ECh. 10 - 43. Each ball-and-stick model shows the electron...Ch. 10 - 44. Each ball-and-stick model shows the electron...Ch. 10 - 45. Determine the geometry about each interior...Ch. 10 - Prob. 46ECh. 10 - Prob. 47ECh. 10 - Prob. 48ECh. 10 - Prob. 49ECh. 10 - Prob. 50ECh. 10 - 51. Determine whether each molecule is polar or...Ch. 10 - Prob. 52ECh. 10 - 53. The valence electron configurations of several...Ch. 10 - 54. The valence electron configurations of several...Ch. 10 - 55. Write orbital diagrams (boxes with arrows in...Ch. 10 - Prob. 56ECh. 10 - 57. Write orbital diagrams (boxes with arrows in...Ch. 10 - Prob. 58ECh. 10 - 59. Which hybridization scheme allows the...Ch. 10 - Prob. 60ECh. 10 - Prob. 61ECh. 10 - 62. Write a hybridization and bonding scheme for...Ch. 10 - Prob. 63ECh. 10 - 64. Write a hybridization and bonding scheme for...Ch. 10 - 65. Write a hybridization and bonding scheme for...Ch. 10 - Prob. 66ECh. 10 - 67. Consider the structure of the amino acid...Ch. 10 - 68. Consider the structure of the amino acid...Ch. 10 - 69. Sketch the bonding molecular orbital that...Ch. 10 - Prob. 70ECh. 10 - 71. Draw an MO energy diagram and predict the bond...Ch. 10 - Prob. 72ECh. 10 - Prob. 73ECh. 10 - Prob. 74ECh. 10 - Prob. 75ECh. 10 - 76. Using the molecular orbital energy ordering...Ch. 10 - 77. Use molecular orbital theory to predict if...Ch. 10 - 78. Use molecular orbital theory to predict if...Ch. 10 - Prob. 79ECh. 10 - Prob. 80ECh. 10 - 81. Draw an MO energy diagram for CO. (Use the...Ch. 10 - Prob. 82ECh. 10 - 83. For each compound, draw the Lewis structure,...Ch. 10 - 84. For each compound, draw the Lewis structure,...Ch. 10 - 85. Amino acids are biological compounds that link...Ch. 10 - 86. The genetic code is based on four different...Ch. 10 - 87. The structure of caffeine, present in coffee...Ch. 10 - 88. The structure of acetylsalicylic acid...Ch. 10 - 89. Most vitamins can be classified as either fat...Ch. 10 - 90. Water does not easily remove grease from...Ch. 10 - Prob. 91ECh. 10 - Prob. 92ECh. 10 - 93. Bromine can form compounds or ions with any...Ch. 10 - 94. The compound C3H4 has two double bonds....Ch. 10 - Prob. 95ECh. 10 - Prob. 96ECh. 10 - Prob. 97ECh. 10 - 98. Indicate which orbitals overlap to form the s...Ch. 10 - 99. In VSEPR theory, which uses the Lewis model to...Ch. 10 - 100. The results of a molecular orbital...Ch. 10 - 101. The results of a molecular orbital...Ch. 10 - Prob. 102ECh. 10 - Prob. 103ECh. 10 - Prob. 104ECh. 10 - Prob. 105ECh. 10 - 106. Neither the VSEPR model nor the hybridization...Ch. 10 - 107. Draw the Lewis structure for acetamide...Ch. 10 - Prob. 108ECh. 10 - 109. Which statement best captures the fundamental...Ch. 10 - 110. Suppose that a molecule has four bonding...Ch. 10 - 111. How does each of the three major bonding...Ch. 10 - Prob. 112ECh. 10 - Prob. 113QGWCh. 10 - Prob. 114QGWCh. 10 - Prob. 115QGWCh. 10 - Prob. 116QGWCh. 10 - Prob. 117QGWCh. 10 - Prob. 118DIA
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