BURDGE CHEMISTRY VALUE ED (LL)
4th Edition
ISBN: 9781259995958
Author: VALUE EDITION
Publisher: MCG CUSTOM
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Chapter 10, Problem 171AP
In a constant-pressure calorimetry experiment, a 2.675-g piece of zinc metal is dropped into 100.0 mL of 1.75 M hydrochloric acid in a closed vessel with a movable piston. The pressure and temperature in the laboratory are 769 torr and
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Predict the major products of this organic reaction:
HBr (1 equiv)
Δ
?
Some important notes:
• Draw the major product, or products, of this reaction in the drawing area below.
• You can draw the products in any arrangement you like.
• Pay careful attention to the reaction conditions, and only include the major products.
• Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers.
• Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions.
Explanation
Check
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For the structure below, draw the resonance structure that is indicated by the curved arrow(s). Be sure to include formal charges.
:ÖH
Modify the second structure given to draw the new resonance structure. Include lone pairs and charges in your structure. Use the +
and - tools to add/remove charges to an atom, and use the single bond tool to add/remove double bonds.
Using the table of Reactants and Products provided in the Hints section, provide the major product
(with the correct stereochemistry when applicable) for questions below by selecting the letter that
corresponds to the exact chemical structures for the possible product.
OH conc Hydrochloric
acid
40°C Temp
A/
Chapter 10 Solutions
BURDGE CHEMISTRY VALUE ED (LL)
Ch. 10.1 - Practice ProblemATTEMPT What pressure (in atm) is...Ch. 10.1 - Prob. 1PPBCh. 10.1 - Prob. 1PPCCh. 10.1 - Express a pressure of 1 .15 atm in units of bar....Ch. 10.1 - Prob. 2CPCh. 10.1 - Prob. 3CPCh. 10.1 - Prob. 4CPCh. 10.1 - Prob. 5CPCh. 10.2 - Prob. 1PPACh. 10.2 - Practice ProblemBUILD At what pressure would a...
Ch. 10.2 - Prob. 1PPCCh. 10.2 - 10.2.1 Given .
Ch. 10.2 - Prob. 2CPCh. 10.2 - 10.2.3 At what temperature will a gas sample...Ch. 10.2 - What volume of NH 3 will be produced when 180 mL...Ch. 10.2 - Prob. 5CPCh. 10.2 - Prob. 6CPCh. 10.3 - Practice ProblemATTEMPT A sample of gas originally...Ch. 10.3 - Practice ProblemBUILD At what temperature (in °C )...Ch. 10.3 - Prob. 1PPCCh. 10.3 - Prob. 1CPCh. 10.3 - Prob. 2CPCh. 10.3 - Prob. 3CPCh. 10.3 - Prob. 4CPCh. 10.4 - Practice ProblemATTEMPT What volume (in liters) of...Ch. 10.4 - Practice ProblemBUILD What volumes (in liters) of...Ch. 10.4 - Practice Problem CONCEPTUALIZE
A hypothetical...Ch. 10.4 - Prob. 1CPCh. 10.4 - Prob. 2CPCh. 10.5 - Practice Problem ATTEMPT
What would be the volume...Ch. 10.5 - Prob. 1PPBCh. 10.5 - Prob. 1PPCCh. 10.5 - Prob. 1CPCh. 10.5 - Prob. 2CPCh. 10.5 - Prob. 3CPCh. 10.5 - 10.5.4 What mass of acetylene is produced by the...Ch. 10.5 - In the following diagram, each color represents a...Ch. 10.5 - Prob. 6CPCh. 10.6 - Practice ProblemATTEMPT What is the volume of 5.12...Ch. 10.6 - Practice ProblemBUILD At what temperature ( in °C...Ch. 10.6 - Practice Problem CONCEPTUALIZE
The diagram shown...Ch. 10.6 - Prob. 1CPCh. 10.6 - Prob. 2CPCh. 10.7 - Practice Problem ATTEMPT
Calculate the density of...Ch. 10.7 - Prob. 1PPBCh. 10.7 - Prob. 1PPCCh. 10.7 - Prob. 1CPCh. 10.7 - Prob. 2CPCh. 10.8 - Practice Problem ATTEMPT Determine the molar mass...Ch. 10.8 - Practice Problem BUILD
A sample of the volatile...Ch. 10.8 - Practice ProblemCONCEPTUALIZE These models...Ch. 10.9 - Practice Problem ATTEMPT
What volume (in liters)...Ch. 10.9 - Practice Problem BUILD What mass (in grams) of Na...Ch. 10.9 - Prob. 1PPCCh. 10.10 - Practice Problem ATTEMPT Using all the same...Ch. 10.10 - Practice ProblemBUILD By how much would the...Ch. 10.10 - Prob. 1PPCCh. 10.11 - Prob. 1PPACh. 10.11 - Prob. 1PPBCh. 10.11 - Prob. 1PPCCh. 10.12 - Practice Problem ATTEMPT Determine the partial...Ch. 10.12 - Practice Problem BUILD
Determine the number of...Ch. 10.12 - Prob. 1PPCCh. 10.13 - Prob. 1PPACh. 10.13 - Practice ProblemBUILD Determine the partial...Ch. 10.13 - Prob. 1PPCCh. 10.14 - Practice Problem ATTEMPT
Calculate the mass of ...Ch. 10.14 - Practice ProblemBUILD Determine the volume of gas...Ch. 10.14 - Practice ProblemCONCEPTUALIZE The first diagram...Ch. 10.15 - Prob. 1PPACh. 10.15 - Practice ProblemBUILD What chamber pressure would...Ch. 10.15 - Practice ProblemCONCEPTUALIZE The diagram on the...Ch. 10.16 - Prob. 1PPACh. 10.16 - Practice ProblemBUILD Determine the molar mass and...Ch. 10.16 - Practice ProblemCONCEPTUALIZE The diagram on the...Ch. 10.17 - Practice ProblemATTEMPT Using data from Table...Ch. 10.17 - Practice ProblemBUILD Calculate the pressure...Ch. 10.17 - Practice ProblemCONCEPTUALIZE What properties of...Ch. 10 - Determine the mole fraction of helium in a gaseous...Ch. 10 - Prob. 2KSPCh. 10 - Determine the mole fraction of water in a solution...Ch. 10 - Prob. 4KSPCh. 10 - Prob. 1QPCh. 10 - Prob. 2QPCh. 10 - Prob. 3QPCh. 10 - Prob. 4QPCh. 10 - Prob. 5QPCh. 10 - Prob. 6QPCh. 10 - Prob. 7QPCh. 10 - Prob. 8QPCh. 10 - Prob. 9QPCh. 10 - Prob. 10QPCh. 10 - Prob. 11QPCh. 10 - Prob. 12QPCh. 10 - Prob. 13QPCh. 10 - Prob. 14QPCh. 10 - Calculate the height of a column of methanol (C H...Ch. 10 - Prob. 16QPCh. 10 - What pressure (in atm) is exerted by a column of...Ch. 10 - What pressure (in atm) is exerted by a column of...Ch. 10 - Prob. 19QPCh. 10 - Prob. 20QPCh. 10 - Prob. 21QPCh. 10 - Prob. 22QPCh. 10 - Prob. 23QPCh. 10 - A sample of air occupies 3.8 L when the pressure...Ch. 10 - Prob. 25QPCh. 10 - 10.26 Under constant-pressure conditions a sample...Ch. 10 - 10.27 Ammonia bums in oxygen gas to form nitric...Ch. 10 - Molecular chlorine and molecular fluorine combine...Ch. 10 - A gaseous sample of a substance is cooled at...Ch. 10 - Consider the following gaseous sample in a...Ch. 10 - Prob. 31QPCh. 10 - Prob. 32QPCh. 10 - Prob. 33QPCh. 10 - Prob. 34QPCh. 10 - 10.35 Given that 6.9 moles of carbon monoxide gas...Ch. 10 - What volume will 9.8 moles of sulfur hexafluoride...Ch. 10 - Prob. 37QPCh. 10 - Prob. 38QPCh. 10 - Prob. 39QPCh. 10 - An ideal gas originally at 0.85 atm and 66°C was...Ch. 10 - Calculate the volume (in liters) of 124.3 g of CO...Ch. 10 - Prob. 42QPCh. 10 - Prob. 43QPCh. 10 - Prob. 44QPCh. 10 - At 741 torr and 44°C, 7.10 g of a gas occupies a...Ch. 10 - Prob. 46QPCh. 10 - Assuming that air contains 78 percent N 2 , 21...Ch. 10 - 10.48 A 2.10-L vessel contains 4.65 g of a gas at...Ch. 10 - Calculate the density of hydrogen bromide ( HBr )...Ch. 10 - A certain anesthetic contains 64.9 percent C, 13.5...Ch. 10 - A compound has the empirical formula SF 4 . At...Ch. 10 - Prob. 52QPCh. 10 - Prob. 53QPCh. 10 - Prob. 54QPCh. 10 - Methane, the principal component of natural gas,...Ch. 10 - Prob. 56QPCh. 10 - In alcohol fermentation, yeast converts glucose to...Ch. 10 - A compound of P and F was analyzed as follows:...Ch. 10 - 10.59 A quantity of 0.225 g of a metal M (molar...Ch. 10 - Prob. 60QPCh. 10 - Prob. 61QPCh. 10 - Prob. 62QPCh. 10 - Ethanol ( C 2 H 5 OH ) burns in air: C 2 H 5 OH( l...Ch. 10 - Prob. 64QPCh. 10 - Prob. 65QPCh. 10 - Prob. 66QPCh. 10 - A 2.5-L flask at 15°C contains a mixture of N 2 ,...Ch. 10 - Dry air near sea level has the following...Ch. 10 - Prob. 69QPCh. 10 - Prob. 70QPCh. 10 - 10.71 A sample of zinc metal reacts completely...Ch. 10 - Prob. 72QPCh. 10 - Prob. 73QPCh. 10 - Prob. 74QPCh. 10 - 10.75 The volume of the box on the right is twice...Ch. 10 - Prob. 76QPCh. 10 - Prob. 77QPCh. 10 - Prob. 78QPCh. 10 - Prob. 79QPCh. 10 - Prob. 80QPCh. 10 - Prob. 81QPCh. 10 - Compare the root-mean-square speeds of O 2 and U F...Ch. 10 - Prob. 83QPCh. 10 - Prob. 84QPCh. 10 - 10.85 At a certain temperature the speeds of six...Ch. 10 - Prob. 86QPCh. 10 - Prob. 87QPCh. 10 - Prob. 88QPCh. 10 - Prob. 89QPCh. 10 - Cite two pieces of evidence to show that gases do...Ch. 10 - Figure 10.25(a) shows that at o°C , with the...Ch. 10 - 10.92 Write the van der Waals equation for a real...Ch. 10 - Prob. 93QPCh. 10 - Prob. 94QPCh. 10 - Prob. 95QPCh. 10 - 10.96 Discuss the following phenomena in terms of...Ch. 10 - Prob. 97APCh. 10 - Prob. 98APCh. 10 - Prob. 99APCh. 10 - Prob. 100APCh. 10 - Prob. 101APCh. 10 - Prob. 102APCh. 10 - On heating, potassium chlorate ( KClO 3 )...Ch. 10 - Prob. 104APCh. 10 - Prob. 105APCh. 10 - Prob. 106APCh. 10 - Prob. 107APCh. 10 - Prob. 108APCh. 10 - Prob. 109APCh. 10 - Prob. 110APCh. 10 - A mixture of Na 2 CO 3 and MgCO 3 of mass 7.63 g...Ch. 10 - Prob. 112APCh. 10 - Prob. 113APCh. 10 - Prob. 114APCh. 10 - Prob. 115APCh. 10 - Prob. 116APCh. 10 - Prob. 117APCh. 10 - Prob. 118APCh. 10 - Prob. 119APCh. 10 - Prob. 120APCh. 10 - Prob. 121APCh. 10 - Prob. 122APCh. 10 - Prob. 123APCh. 10 - Prob. 124APCh. 10 - Prob. 125APCh. 10 - Prob. 126APCh. 10 - Prob. 127APCh. 10 - Prob. 128APCh. 10 - Prob. 129APCh. 10 - Prob. 130APCh. 10 - Prob. 131APCh. 10 - Prob. 132APCh. 10 - Prob. 133APCh. 10 - Prob. 134APCh. 10 - Prob. 135APCh. 10 - Prob. 136APCh. 10 - Prob. 137APCh. 10 - Prob. 138APCh. 10 - Prob. 139APCh. 10 - Given that the van der Waals constant b is the...Ch. 10 - Prob. 141APCh. 10 - Prob. 142APCh. 10 - Prob. 143APCh. 10 - Prob. 144APCh. 10 - Prob. 145APCh. 10 - Prob. 146APCh. 10 - Prob. 147APCh. 10 - Prob. 148APCh. 10 - A 5.00-mol sample of NH 3 gas is kept in a 1.92-L...Ch. 10 - In the metallurgical process of refining nickel,...Ch. 10 - Some commercial drain cleaners contain a mixture...Ch. 10 - Prob. 152APCh. 10 - Prob. 153APCh. 10 - Prob. 154APCh. 10 - Prob. 155APCh. 10 - 10. 156 Air entering the lungs ends up in tiny...Ch. 10 - Prob. 157APCh. 10 - Prob. 158APCh. 10 - Prob. 159APCh. 10 - Prob. 160APCh. 10 - The percent by mass of bicarbonate ( HCO 3 ) in a...Ch. 10 - Prob. 162APCh. 10 - Prob. 163APCh. 10 - Prob. 164APCh. 10 - Prob. 165APCh. 10 - Prob. 166APCh. 10 - Prob. 167APCh. 10 - Venus's atmosphere is composed of 96.5 percent CO...Ch. 10 - Acidic oxides such as carbon dioxide react with...Ch. 10 - Prob. 170APCh. 10 - 10.171 In a constant-pressure calorimetry...Ch. 10 - Prob. 2SEPPCh. 10 - Prob. 3SEPPCh. 10 - Prob. 4SEPP
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