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Chapter 10, Problem 11E
Interpretation Introduction
To explain: why hot air-balloons float above the ground.
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
Ar
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
2.2 mol of NaOH is added to
1.0 L of a 1.4M HF
solution.
acids:
П
bases:
Х
other: ☐
ப
acids:
0.51 mol of KOH is added to
1.0 L of a solution that is
bases:
1.3M in both HF and NaF.
other: ☐
00.
18
Ar
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
N2O4 (g) 2NO2 (g)
AG⁰ = 5.4 kJ
Now suppose a reaction vessel is filled with 1.68 atm of dinitrogen tetroxide (N204) at 148. °C. Answer the following questions about this system:
rise
Under these conditions, will the pressure of N2O4 tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO2?
In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
rise by adding NO2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO 2 needed to reverse it.
Round your answer to 2 significant digits.
yes
no
0.42 atm
☑
5
0/5
?
مله
Ar
Chapter 10 Solutions
Chemistry: Structure and Properties, Books a la Carte PACKAGE W/MasteringChemistry, 2nd Edition
Ch. 10 - Prob. 1ECh. 10 - Prob. 2ECh. 10 - Prob. 3ECh. 10 - Prob. 4ECh. 10 - Prob. 5ECh. 10 - Prob. 6ECh. 10 - Prob. 7ECh. 10 - Prob. 8ECh. 10 - Prob. 9ECh. 10 - Prob. 10E
Ch. 10 - Prob. 11ECh. 10 - Prob. 12ECh. 10 - Prob. 13ECh. 10 - Prob. 14ECh. 10 - Prob. 15ECh. 10 - Prob. 16ECh. 10 - Prob. 17ECh. 10 - Prob. 18ECh. 10 - Prob. 19ECh. 10 - Prob. 20ECh. 10 - Prob. 21ECh. 10 - Prob. 22ECh. 10 - If a reaction occurs in the gas phase at STP, the...Ch. 10 - Prob. 24ECh. 10 - Prob. 25ECh. 10 - Prob. 26ECh. 10 - Prob. 27ECh. 10 - Prob. 28ECh. 10 - Prob. 29ECh. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - Prob. 32ECh. 10 - A 48.3-mL sample of gas in a cylinder is warmed...Ch. 10 - A syringe containing 1.55 mL of oxygen gas is...Ch. 10 - A balloon contains 0.158 mol of gas and has a...Ch. 10 - Prob. 36ECh. 10 - Prob. 37ECh. 10 - Prob. 38ECh. 10 - Prob. 39ECh. 10 - Prob. 40ECh. 10 - Prob. 41ECh. 10 - Prob. 42ECh. 10 - Prob. 43ECh. 10 - Prob. 44ECh. 10 - Prob. 45ECh. 10 - Prob. 46ECh. 10 - A wine-dispensing system uses argon canisters to...Ch. 10 - Prob. 48ECh. 10 - Prob. 49ECh. 10 - Prob. 50ECh. 10 - Aerosol cans carry clear warnings against...Ch. 10 - Prob. 52ECh. 10 - Prob. 53ECh. 10 - Use the molar volume of a gas at STP to calculate...Ch. 10 - What is the density (in g/L) of hydrogen gas at...Ch. 10 - Prob. 56ECh. 10 - Prob. 57ECh. 10 - A 113-mL gas sample has a mass of 0.171 g at a...Ch. 10 - A sample of gas has a mass of 38.8 mg. Its volume...Ch. 10 - Prob. 60ECh. 10 - A gas mixture contains each of these gases at the...Ch. 10 - A gas mixture with a total pressure of 745 mmHg...Ch. 10 - We add a 1.20-g sample of dry ice to a 755-mL...Ch. 10 - A 275-mL flask contains pure helium at a pressure...Ch. 10 - A gas mixture contains 1.25 g N2 and 0.85 g O2 in...Ch. 10 - Prob. 66ECh. 10 - The hydrogen gas formed in a chemical reaction is...Ch. 10 - Prob. 68ECh. 10 - Prob. 69ECh. 10 - Prob. 70ECh. 10 - Prob. 71ECh. 10 - Prob. 72ECh. 10 - Prob. 73ECh. 10 - Prob. 74ECh. 10 - Prob. 75ECh. 10 - Prob. 76ECh. 10 - Prob. 77ECh. 10 - Prob. 78ECh. 10 - Prob. 79ECh. 10 - Prob. 80ECh. 10 - Prob. 81ECh. 10 - Prob. 82ECh. 10 - CH3OH can be synthesized by the reaction:...Ch. 10 - Oxygen gas reacts with powered aluminum according...Ch. 10 - Automobile airbags inflate following serious...Ch. 10 - Lithium reacts with nitrogen gas according to the...Ch. 10 - Prob. 87ECh. 10 - Prob. 88ECh. 10 - Prob. 89ECh. 10 - Carbon monoxide gas reacts with hydrogen gas to...Ch. 10 - Prob. 91ECh. 10 - Prob. 92ECh. 10 - Prob. 93ECh. 10 - Use the vander Waals equation and the ideal gas...Ch. 10 - Pennies that are currently being minted are...Ch. 10 - A 2.85 g sample of an unknown chlorofluorocarbon...Ch. 10 - Prob. 97ECh. 10 - A 118 mL flask is evacuated and found to have a...Ch. 10 - Prob. 99ECh. 10 - A gaseous hydrogen- and carbon-containing compound...Ch. 10 - Prob. 101ECh. 10 - Consider the reaction: 2Ag2O(s)4Ag(s)+O2(g) If...Ch. 10 - When hydrochloric acid is poured over potassium...Ch. 10 - Consider the reaction: 2SO2(g)+O2(g)2SO(g)3 If...Ch. 10 - Ammonium carbonate decomposes upon heating...Ch. 10 - Ammonium nitrate decomposes explosively upon...Ch. 10 - Prob. 107ECh. 10 - Prob. 108ECh. 10 - Gaseous ammonia is injected into the exhaust...Ch. 10 - Prob. 110ECh. 10 - Prob. 111ECh. 10 - Prob. 112ECh. 10 - Prob. 113ECh. 10 - Prob. 114ECh. 10 - Prob. 115ECh. 10 - Prob. 116ECh. 10 - Prob. 117ECh. 10 - Prob. 118ECh. 10 - Prob. 119ECh. 10 - Prob. 120ECh. 10 - Prob. 121ECh. 10 - Prob. 122ECh. 10 - Prob. 123ECh. 10 - Prob. 124ECh. 10 - Prob. 125ECh. 10 - Prob. 126ECh. 10 - When 0.583 g of neon is added to an 800-cm3bulb...Ch. 10 - A gas mixture composed of helium and argon has a...Ch. 10 - Prob. 129ECh. 10 - Prob. 130ECh. 10 - Prob. 131ECh. 10 - Prob. 132ECh. 10 - Prob. 133ECh. 10 - Prob. 134ECh. 10 - The atmosphere slowly oxidizes hydrocarbons in a...Ch. 10 - Prob. 136ECh. 10 - Prob. 137ECh. 10 - Prob. 138ECh. 10 - Prob. 139ECh. 10 - Prob. 140ECh. 10 - Prob. 141ECh. 10 - Prob. 142ECh. 10 - Prob. 143ECh. 10 - Which gas would you expect to deviate most from...Ch. 10 - Prob. 145ECh. 10 - Prob. 146ECh. 10 - Prob. 147ECh. 10 - Prob. 148ECh. 10 - Prob. 149ECh. 10 - Prob. 150ECh. 10 - Prob. 151ECh. 10 - Calculate the pressure exerted by 1 mol of an...Ch. 10 - Prob. 153ECh. 10 - Prob. 1SAQCh. 10 - Prob. 2SAQCh. 10 - Prob. 3SAQCh. 10 - Prob. 4SAQCh. 10 - Prob. 5SAQCh. 10 - Prob. 6SAQCh. 10 - Prob. 7SAQCh. 10 - A gas mixture is a 1.55-L container at 298 K...Ch. 10 - Prob. 9SAQCh. 10 - Prob. 10SAQCh. 10 - Prob. 11SAQCh. 10 - Prob. 12SAQCh. 10 - Prob. 13SAQCh. 10 - Prob. 14SAQCh. 10 - Prob. 15SAQ
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