
Concept explainers
(a)
Interpretation:
Change in the pressure (P) when volume (V) of a gas is decreased is to be stated.
Concept introduction:
To study the molecules in gaseous state different laws have been given by different scientists which relates different variables to each other. Boyle’s law which relates pressure and temperature states that when temperature is kept constant for a gas then the pressure and temperature follows the inverse relation. According to Boyle’s law, relation between pressure and volume is written below.
P∝1V, T is constantP=kVPV=k

Answer to Problem 10E
Pressure increases with decrease in volume.
Explanation of Solution
According to the equation of Boyle’s law if volume is decreased for a particular or constant temperature then the pressure of the gas will be increased to keep the PV constant Boyle’s law for the gaseous molecule is stated as below.
P∝1V, T is constantP=kVPV=kP1V1=P2V2
• k is a proportionality constant
• P1 is the initial pressure of the gas.
• P2 is the final pressure of the gas.
• V1 is the initial volume of the container or gas
• V2 is the final volume of the container or gas
Therefore, net value of pressure increases with decrease in volume.
Net value of pressure increases with decrease in volume.
(b)
Interpretation:
Change in the pressure (P) when temperature (T) of a gas is decreased is to be stated.
Concept introduction:
To study the molecules in gaseous state different laws have been given by different scientists which relates different variables to each other. Gay Lussac’s law one of the
P∝T, V is constantP=kT,V is constantPT=k

Answer to Problem 10E
The pressure values decreases with decrease in the temperature of the gas.
Explanation of Solution
Relation given by Gay Lussac’s for the gaseous molecule is stated as below.
P∝T, V is constantP=kT,V is constantPT=kP1T1=P2T2
• k is a proportionality constant
• P1 is the initial pressure of the gas.
• P2 is the final pressure of the gas.
• T1 is the initial temperature of the gas
• T2 is the final temperature of the gas
Ratio of pressure and temperature is constant. Pressure will be decreased with the decrease in value of temperature to keep the ratio PT constant.
Therefore, net value of pressure decreases with decrease in volume.
Pressure of a gas decreases with decrease in temperature.
(c)
Interpretation:
Change in the pressure when moles of a gas are decreased is to be stated.
Concept introduction:
To study the molecules in gaseous state different laws have been given by different scientists which relates different variables to each other.
P∝T, V is constantP∝1V,T is constantV∝n, (P,T are constant)P∝n×TV.

Answer to Problem 10E
Net value of pressure decreases with decrease in number of moles.
Explanation of Solution
Relation given by all the variables of a gas is stated as below.
P∝n×TVP=n×T×RV
Gas law is written below.
PV=nRT …(1)
Gas law for two different gases is shown below.
P1×V1n1×T1×R=P2×V2n2×T2×R …(2)
At constant volume and temperature, equation (2) is shown below.
P1n1=P2n2
Where,
• P1 is the initial pressure exerted by gas molecules.
• P2.is the final pressure exerted by gas molecules.
• n1 is the initial number of moles of gas.
• n2 is final number of moles of a gas.
According to the relation given in equation (1), pressure is directly proportional to the number of moles. Pressure will be decreased with the decrease in number of moles to maintain the gas law when all other variables are kept constant.
Therefore, pressure of a gas decreases with decrease in number of moles.
Net value of pressure decreases with decrease in number of moles (n) of a gas.
Want to see more full solutions like this?
Chapter 10 Solutions
EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM
- Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**arrow_forward11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5arrow_forwardО δα HO- H -Br δα HO-- + + -Br [B] 8+ HO- -Br δα नarrow_forward
- 1/2 - 51% + » GAY Organic Reactions Assignment /26 Write the type of reaction that is occurring on the line provided then complete the reaction. Only include the major products and any byproducts (e.g. H₂O) but no minor products. Please use either full structural diagrams or the combination method shown in the lesson. Skeletal/line diagrams will not be accepted. H3C 1. 2. CH3 A Acid OH Type of Reaction: NH Type of Reaction: + H₂O Catalyst + HBr 3. Type of Reaction: H3C 4. Type Reaction: 5. H3C CH2 + H2O OH + [0] CH3 Type of Reaction: 6. OH CH3 HO CH3 + Type of Reaction: 7. Type of Reaction: + [H]arrow_forwardhumbnai Concentration Terms[1].pdf ox + New Home Edit Sign in Comment Convert Page Fill & Sign Protect Tools Batch +WPS A Free Trial Share Inter Concreting Concentration forms. Hydrogen peroxide is a powerful oxidizing agent wed in concentrated solution in rocket fuels and in dilute solution as a hair bleach. An aqueous sulation of H2O2 is 30% by mass and has density of #liligime calculat the Ⓒmolality ⑥mole fraction of molarity. 20 9. B. A sample of Commercial Concentrated hydrochloric ETarrow_forwardIf a reaction occurs, what would be the major products? Please include a detailed explanation as well as a drawing showing how the reaction occurs and what the final product is.arrow_forward
- Would the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.arrow_forward(a) Sketch the 'H NMR of the following chemical including the approximate chemical shifts, the multiplicity (splitting) of all signals and the integration (b) How many signals would you expect in the 13C NMR? CH3arrow_forwardDraw the Show the major and minor product(s) for the following reaction mechanisms for both reactions and show all resonance structures for any Explain why the major product is favoured? intermediates H-Brarrow_forward
- Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning
- Introductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningLiving By Chemistry: First Edition TextbookChemistryISBN:9781559539418Author:Angelica StacyPublisher:MAC HIGHER




