Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: Structure and Properties (2nd Edition)
2nd Edition
ISBN: 9780134566290
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 10, Problem 10E
Interpretation Introduction
To determine:
Explain why the second story of a building is hotter than the ground story.
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2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Interpreting NMR spectra is a skill that often requires some
amount of practice, which, in turn, necessitates access to a
collection of NMR spectra. Beyond Labz Organic Synthesis and
Organic Qualitative Analysis have spectral libraries containing
over 700 1H NMR spectra. In this assignment, you will take
advantage of this by first predicting the NMR spectra for two
closely related compounds and then checking your predictions
by looking up the actual spectra in the spectra library. After
completing this assignment, you may wish to select other
compounds for additional practice.
1. Write the IUPAC names for the following two structures:
Question 2
Question 3
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
11:14
...
worksheets.beyondlabz.com
3. To check your predictions, click this link for Interpreting
NMR Spectra 1. You will see a list of all the
-
compounds in the spectra library in alphabetical order by
IUPAC name. Hovering over a name in the list will show
the structure on the chalkboard. The four buttons on the
top of the Spectra tab in the tray are used to select the
different spectroscopic techniques for the selected
compound. Make sure the NMR button has been selected.
4. Scroll through the list of names to find the names for the
two compounds you have been given and click on the
name to display the NMR spectrum for each. In the NMR
tables below, list the chemical shift, the splitting, and
the number of hydrogens associated with each peak for
each compound. Compare your answers to your
predictions.
**Not all slots must be filled**
Peak
Chemical Shift (d)
Multiplicity
1
2
3
4
5
Chapter 10 Solutions
Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: Structure and Properties (2nd Edition)
Ch. 10 - Prob. 1ECh. 10 - Prob. 2ECh. 10 - Prob. 3ECh. 10 - Prob. 4ECh. 10 - Prob. 5ECh. 10 - Prob. 6ECh. 10 - Prob. 7ECh. 10 - Prob. 8ECh. 10 - Prob. 9ECh. 10 - Prob. 10E
Ch. 10 - Prob. 11ECh. 10 - Prob. 12ECh. 10 - Prob. 13ECh. 10 - Prob. 14ECh. 10 - Prob. 15ECh. 10 - Prob. 16ECh. 10 - Prob. 17ECh. 10 - Prob. 18ECh. 10 - Prob. 19ECh. 10 - Prob. 20ECh. 10 - Prob. 21ECh. 10 - Prob. 22ECh. 10 - If a reaction occurs in the gas phase at STP, the...Ch. 10 - Prob. 24ECh. 10 - Prob. 25ECh. 10 - Prob. 26ECh. 10 - Prob. 27ECh. 10 - Prob. 28ECh. 10 - Prob. 29ECh. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - Prob. 32ECh. 10 - A 48.3-mL sample of gas in a cylinder is warmed...Ch. 10 - A syringe containing 1.55 mL of oxygen gas is...Ch. 10 - A balloon contains 0.158 mol of gas and has a...Ch. 10 - Prob. 36ECh. 10 - Prob. 37ECh. 10 - Prob. 38ECh. 10 - Prob. 39ECh. 10 - Prob. 40ECh. 10 - Prob. 41ECh. 10 - Prob. 42ECh. 10 - Prob. 43ECh. 10 - Prob. 44ECh. 10 - Prob. 45ECh. 10 - Prob. 46ECh. 10 - A wine-dispensing system uses argon canisters to...Ch. 10 - Prob. 48ECh. 10 - Prob. 49ECh. 10 - Prob. 50ECh. 10 - Aerosol cans carry clear warnings against...Ch. 10 - Prob. 52ECh. 10 - Prob. 53ECh. 10 - Use the molar volume of a gas at STP to calculate...Ch. 10 - What is the density (in g/L) of hydrogen gas at...Ch. 10 - Prob. 56ECh. 10 - Prob. 57ECh. 10 - A 113-mL gas sample has a mass of 0.171 g at a...Ch. 10 - A sample of gas has a mass of 38.8 mg. Its volume...Ch. 10 - Prob. 60ECh. 10 - A gas mixture contains each of these gases at the...Ch. 10 - A gas mixture with a total pressure of 745 mmHg...Ch. 10 - We add a 1.20-g sample of dry ice to a 755-mL...Ch. 10 - A 275-mL flask contains pure helium at a pressure...Ch. 10 - A gas mixture contains 1.25 g N2 and 0.85 g O2 in...Ch. 10 - Prob. 66ECh. 10 - The hydrogen gas formed in a chemical reaction is...Ch. 10 - Prob. 68ECh. 10 - Prob. 69ECh. 10 - Prob. 70ECh. 10 - Prob. 71ECh. 10 - Prob. 72ECh. 10 - Prob. 73ECh. 10 - Prob. 74ECh. 10 - Prob. 75ECh. 10 - Prob. 76ECh. 10 - Prob. 77ECh. 10 - Prob. 78ECh. 10 - Prob. 79ECh. 10 - Prob. 80ECh. 10 - Prob. 81ECh. 10 - Prob. 82ECh. 10 - CH3OH can be synthesized by the reaction:...Ch. 10 - Oxygen gas reacts with powered aluminum according...Ch. 10 - Automobile airbags inflate following serious...Ch. 10 - Lithium reacts with nitrogen gas according to the...Ch. 10 - Prob. 87ECh. 10 - Prob. 88ECh. 10 - Prob. 89ECh. 10 - Carbon monoxide gas reacts with hydrogen gas to...Ch. 10 - Prob. 91ECh. 10 - Prob. 92ECh. 10 - Prob. 93ECh. 10 - Use the vander Waals equation and the ideal gas...Ch. 10 - Pennies that are currently being minted are...Ch. 10 - A 2.85 g sample of an unknown chlorofluorocarbon...Ch. 10 - Prob. 97ECh. 10 - A 118 mL flask is evacuated and found to have a...Ch. 10 - Prob. 99ECh. 10 - A gaseous hydrogen- and carbon-containing compound...Ch. 10 - Prob. 101ECh. 10 - Consider the reaction: 2Ag2O(s)4Ag(s)+O2(g) If...Ch. 10 - When hydrochloric acid is poured over potassium...Ch. 10 - Consider the reaction: 2SO2(g)+O2(g)2SO(g)3 If...Ch. 10 - Ammonium carbonate decomposes upon heating...Ch. 10 - Ammonium nitrate decomposes explosively upon...Ch. 10 - Prob. 107ECh. 10 - Prob. 108ECh. 10 - Gaseous ammonia is injected into the exhaust...Ch. 10 - Prob. 110ECh. 10 - Prob. 111ECh. 10 - Prob. 112ECh. 10 - Prob. 113ECh. 10 - Prob. 114ECh. 10 - Prob. 115ECh. 10 - Prob. 116ECh. 10 - Prob. 117ECh. 10 - Prob. 118ECh. 10 - Prob. 119ECh. 10 - Prob. 120ECh. 10 - Prob. 121ECh. 10 - Prob. 122ECh. 10 - Prob. 123ECh. 10 - Prob. 124ECh. 10 - Prob. 125ECh. 10 - Prob. 126ECh. 10 - When 0.583 g of neon is added to an 800-cm3bulb...Ch. 10 - A gas mixture composed of helium and argon has a...Ch. 10 - Prob. 129ECh. 10 - Prob. 130ECh. 10 - Prob. 131ECh. 10 - Prob. 132ECh. 10 - Prob. 133ECh. 10 - Prob. 134ECh. 10 - The atmosphere slowly oxidizes hydrocarbons in a...Ch. 10 - Prob. 136ECh. 10 - Prob. 137ECh. 10 - Prob. 138ECh. 10 - Prob. 139ECh. 10 - Prob. 140ECh. 10 - Prob. 141ECh. 10 - Prob. 142ECh. 10 - Prob. 143ECh. 10 - Which gas would you expect to deviate most from...Ch. 10 - Prob. 145ECh. 10 - Prob. 146ECh. 10 - Prob. 147ECh. 10 - Prob. 148ECh. 10 - Prob. 149ECh. 10 - Prob. 150ECh. 10 - Prob. 151ECh. 10 - Calculate the pressure exerted by 1 mol of an...Ch. 10 - Prob. 153ECh. 10 - Prob. 1SAQCh. 10 - Prob. 2SAQCh. 10 - Prob. 3SAQCh. 10 - Prob. 4SAQCh. 10 - Prob. 5SAQCh. 10 - Prob. 6SAQCh. 10 - Prob. 7SAQCh. 10 - A gas mixture is a 1.55-L container at 298 K...Ch. 10 - Prob. 9SAQCh. 10 - Prob. 10SAQCh. 10 - Prob. 11SAQCh. 10 - Prob. 12SAQCh. 10 - Prob. 13SAQCh. 10 - Prob. 14SAQCh. 10 - Prob. 15SAQ
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