Atkins' Physical Chemistry
11th Edition
ISBN: 9780198769866
Author: ATKINS, P. W. (peter William), De Paula, Julio, Keeler, JAMES
Publisher: Oxford University Press
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Chapter 10, Problem 10B.5BE
Interpretation Introduction
Interpretation:
The symmetry species of the
Concept introduction:
The systematic discussion of symmetry is known as group theory. The table showing all the characters of the operations of a group are termed as character tables. The character of an operation in a particular matrix is the sum of the diagonal elements of the representative of that operation.
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NO2 (g) = N2O4(g)
AGº = -5.4 kJ
Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system:
Under these conditions, will the pressure of N2O4 tend to rise or fall?
Is it possible to reverse this tendency by adding NO2?
In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
'2'
rise by adding NO2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO 2 needed to reverse it.
Round your answer to 2 significant digits.
00
rise
☐ x10
fall
yes
no
☐ atm
G
Ar
1
Why do we analyse salt?
Curved arrows are used to illustrate the flow of electrons. Using
the provided starting and product structures, draw the curved
electron-pushing arrows for the following reaction or
mechanistic step(s).
Be sure to account for all bond-breaking and bond-making
steps.
H
H
CH3OH, H+
H
Select to Add Arrows
H°
0:0
'H
+
Q
HH
■ Select to Add Arrows
CH3OH,
H*
H.
H
CH3OH, H+
HH
■ Select to Add Arrows i
Please select a drawing or reagent from the question area
Chapter 10 Solutions
Atkins' Physical Chemistry
Ch. 10 - Prob. 10B.2STCh. 10 - Prob. 10C.1STCh. 10 - Prob. 10C.2STCh. 10 - Prob. 10C.3STCh. 10 - Prob. 10A.1DQCh. 10 - Prob. 10A.2DQCh. 10 - Prob. 10A.3DQCh. 10 - Prob. 10A.4DQCh. 10 - Prob. 10A.1AECh. 10 - Prob. 10A.1BE
Ch. 10 - Prob. 10A.2AECh. 10 - Prob. 10A.2BECh. 10 - Prob. 10A.3AECh. 10 - Prob. 10A.3BECh. 10 - Prob. 10A.4AECh. 10 - Prob. 10A.4BECh. 10 - Prob. 10A.5AECh. 10 - Prob. 10A.5BECh. 10 - Prob. 10A.6AECh. 10 - Prob. 10A.6BECh. 10 - Prob. 10A.7AECh. 10 - Prob. 10A.1PCh. 10 - Prob. 10A.2PCh. 10 - Prob. 10A.3PCh. 10 - Prob. 10A.4PCh. 10 - Prob. 10A.5PCh. 10 - Prob. 10B.1DQCh. 10 - Prob. 10B.2DQCh. 10 - Prob. 10B.3DQCh. 10 - Prob. 10B.4DQCh. 10 - Prob. 10B.5DQCh. 10 - Prob. 10B.1AECh. 10 - Prob. 10B.1BECh. 10 - Prob. 10B.2AECh. 10 - Prob. 10B.2BECh. 10 - Prob. 10B.3AECh. 10 - Prob. 10B.3BECh. 10 - Prob. 10B.4AECh. 10 - Prob. 10B.4BECh. 10 - Prob. 10B.5AECh. 10 - Prob. 10B.5BECh. 10 - Prob. 10B.6AECh. 10 - Prob. 10B.6BECh. 10 - Prob. 10B.7AECh. 10 - Prob. 10B.7BECh. 10 - Prob. 10B.1PCh. 10 - Prob. 10B.2PCh. 10 - Prob. 10B.3PCh. 10 - Prob. 10B.4PCh. 10 - Prob. 10B.5PCh. 10 - Prob. 10B.6PCh. 10 - Prob. 10B.7PCh. 10 - Prob. 10B.8PCh. 10 - Prob. 10B.9PCh. 10 - Prob. 10B.10PCh. 10 - Prob. 10C.1DQCh. 10 - Prob. 10C.2DQCh. 10 - Prob. 10C.1AECh. 10 - Prob. 10C.1BECh. 10 - Prob. 10C.2AECh. 10 - Prob. 10C.2BECh. 10 - Prob. 10C.3AECh. 10 - Prob. 10C.3BECh. 10 - Prob. 10C.4AECh. 10 - Prob. 10C.4BECh. 10 - Prob. 10C.5AECh. 10 - Prob. 10C.6AECh. 10 - Prob. 10C.6BECh. 10 - Prob. 10C.7AECh. 10 - Prob. 10C.7BECh. 10 - Prob. 10C.8AECh. 10 - Prob. 10C.8BECh. 10 - Prob. 10C.9AECh. 10 - Prob. 10C.9BECh. 10 - Prob. 10C.1PCh. 10 - Prob. 10C.2PCh. 10 - Prob. 10C.3PCh. 10 - Prob. 10C.4PCh. 10 - Prob. 10C.5PCh. 10 - Prob. 10C.6P
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