CHEMISTRY: AN INTRODUCTION TO GENERAL, O
13th Edition
ISBN: 9780137444298
Author: Timberlake
Publisher: PEARSON
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Chapter 10, Problem 10.80UTC
Interpretation Introduction
To explain: The following,
a. How pH of blood is maintained when acid is added to the buffer system.
b. How is pH maintained when base is added to the buffer system?
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C
This question shows how molecular orbital (MO) theory can be used to understand the chemical
properties of elemental oxygen O₂ and its anionic derivative superoxide Oz.
a)
Draw the MO energy diagram for both O2 and O2. Clearly label your diagram with atomic orbital names
and molecular orbital symmetry labels and include electrons.
Draw the Lewis structure of O2. How does the MO description of O2 differ from the Lewis structure, and
how does this difference relate to the high reactivity and magnetic properties of oxygen?
) Use the MO diagram in (a) to explain the difference in bond length and bond energy between superoxide
ion (Oz, 135 pm, 360 kJ/mol) and oxygen (O2, 120.8 pm, 494 kJ/mol).
Please draw
-Page: 8
nsition metal ions have high-spin aqua complexes except one: [Co(HO)₁]".
What is the d-configuration, oxidation state of the metal in [Co(H:O))"? Name and draw the geometry
of [Co(H2O)]?
b)
Draw energy diagrams showing the splitting of the five d orbitals of Co for the two possible electron
configurations of [Co(H2O)]:
Knowing that A = 16 750 cm and Пl. = 21 000 cm, calculate the configuration energy (.e., balance
or ligand-field stabilization energy and pairing energy) for both low spin and high spin configurations of
[Co(H2O)]. Which configuration seems more stable at this point of the analysis? (Note that 349.76 cm = 1
kJ/mol)
Exchange energy (IT) was not taken into account in part (d), but it plays a role. Assuming exchange
an occur within t29 and within eg (but not between tz, and ea), how many exchanges are possible in the low
in configuration vs in the high spin configuration? What can you say about the importance of exchange energy
07
Chapter 10 Solutions
CHEMISTRY: AN INTRODUCTION TO GENERAL, O
Ch. 10.1 - Indicate whether each of the following statements...Ch. 10.1 - Indicate whether each of the following statements...Ch. 10.1 - Name each of the following acids or bases: HCl...Ch. 10.1 - Name each of the following acids or bases: Al(OH)3...Ch. 10.1 - Write formulas for each of the following acids and...Ch. 10.1 - Write formulas for each of the following acids and...Ch. 10.2 - Identify the reactant that is Bronsted-Lowry acid...Ch. 10.2 - Identify the reactant that is Bronsted-Lowry acid...Ch. 10.2 - Write the formula for the conjugate base for each...Ch. 10.2 - Write the formula for the conjugate base for each...
Ch. 10.2 - Prob. 10.11PPCh. 10.2 - Write the formula for the conjugate acid for each...Ch. 10.2 - Identify the Bronsted-Lowry acid-base pairs in...Ch. 10.2 - Identify the Bronsted-Lowry acid-base pairs in...Ch. 10.3 - Using TABLE10.3, identify the stronger acid in...Ch. 10.3 - Using TABLE10.3, identify the stronger acid in...Ch. 10.3 - Using TABLE10.3, identify the weaker acid in each...Ch. 10.3 - Using TABLE10.3, identify the weaker acid in each...Ch. 10.4 - What is meant by the term reversible reaction?Ch. 10.4 - When does a reversible reaction reach equilibrium?Ch. 10.4 - Which of the following are at equilibrium? The...Ch. 10.4 - Which of the following are not at equilibrium? The...Ch. 10.4 - Use Le Ch?telier’s principle to predict whether...Ch. 10.4 - Use Le Châtelier’s principle to predict whether...Ch. 10.5 - Why are the concentrations of H3O+and OH- equal in...Ch. 10.5 - Prob. 10.26PPCh. 10.5 - Prob. 10.27PPCh. 10.5 - If a base is added to pure water, why does the...Ch. 10.5 - Indicate whether each of the following solutions...Ch. 10.5 - Indicate whether each of the following solutions...Ch. 10.5 - Calculate the [OH-] of each aqueous solution with...Ch. 10.5 - Calculate the [OH-] of each aqueous solution with...Ch. 10.5 - Calculate the [H3O+] of each aqueous solution with...Ch. 10.5 - Calculate the [H3O+] of each aqueous solution with...Ch. 10.6 - State whether each of the following is acidic,...Ch. 10.6 - State whether each of the following is acidic,...Ch. 10.6 - Why does a neutral solution have a pH of 7.0?Ch. 10.6 - If you know the [OH-] , how can you determine the...Ch. 10.6 - Calculate the pH of each solution given the...Ch. 10.6 - Calculate the pH of each solution given the...Ch. 10.6 - Complete the following table: [H3O+] [OH-] pH...Ch. 10.6 - Complete the following table: [H3O+] [OH-] pH...Ch. 10.6 - A patient with severe metabolic acidosis has a...Ch. 10.6 - A patient with respiratory alkalosis has a blood...Ch. 10.7 - Complete and balance the equation for each of the...Ch. 10.7 - Prob. 10.46PPCh. 10.7 - Balance each of the following neutralization...Ch. 10.7 - Balance each of the following neutralization...Ch. 10.7 - Write a balanced equation for the neutralization...Ch. 10.7 - Write a balanced equation for the neutralization...Ch. 10.7 - What is the molarity of a solution of HCl if 5.00...Ch. 10.7 - What is the molarity of an acetic acid solution if...Ch. 10.7 - If 32.8 mL of a 0.162 M NaOH solution is required...Ch. 10.7 - If 38.2 mL of a 0.163 M KOH solution is required...Ch. 10.8 - Which of the following represents a buffer system?...Ch. 10.8 - Which of the following represents a buffer system?...Ch. 10.8 - Consider the buffer system of hydrofluoric acid,...Ch. 10.8 - Consider the buffer system of nitrous acid, HNO2,...Ch. 10.8 - Prob. 10.59PPCh. 10.8 -
10.60 Why would the pH of your blood plasma...Ch. 10.8 - Prob. 10.61PPCh. 10.8 - Prob. 10.62PPCh. 10.8 - At rest, the [H3O+] of the stomach fluid is 2.0 ...Ch. 10.8 - Prob. 10.64PPCh. 10.8 - In Larry’s esophageal PH test, a PH value of 3.60...Ch. 10.8 - Prob. 10.66PPCh. 10.8 - Write the balanced chemical equation for the...Ch. 10.8 - Prob. 10.68PPCh. 10.8 - How many grams of CaCO3 are required to neutralize...Ch. 10.8 - Prob. 10.70PPCh. 10 - Identify each of the following as an acid or a...Ch. 10 - Prob. 10.72UTCCh. 10 - Prob. 10.73UTCCh. 10 - Complete the following table: (10.2) Base...Ch. 10 - State whether each of the following solutions is...Ch. 10 - Prob. 10.76UTCCh. 10 - Prob. 10.77UTCCh. 10 - Adding a few drops of a strong acid to water will...Ch. 10 - Prob. 10.79UTCCh. 10 - Prob. 10.80UTCCh. 10 - Prob. 10.81APPCh. 10 - Prob. 10.82APPCh. 10 - Using TABLE10.3, identify the stronger acid in...Ch. 10 - Using TABLEIO.3 , identify the weaker acid in each...Ch. 10 - Prob. 10.85APPCh. 10 - Prob. 10.86APPCh. 10 - Determine the pH for the following solutions:...Ch. 10 - Prob. 10.88APPCh. 10 - Prob. 10.89APPCh. 10 - Prob. 10.90APPCh. 10 - Calculate the {H3O+] and [OH-] for a solution with...Ch. 10 - Calculate the [H3O+] and [OH-] for a solution with...Ch. 10 - Prob. 10.93APPCh. 10 - Prob. 10.94APPCh. 10 - Prob. 10.95APPCh. 10 - A 1O.O-mL sample of vinegar, which is an aqueous...Ch. 10 - Prob. 10.97APPCh. 10 - Calculate the volume, in milliliters, of a 0.2 15...Ch. 10 - Prob. 10.99APPCh. 10 - Prob. 10.100APPCh. 10 - Prob. 10.101CPCh. 10 - Prob. 10.102CPCh. 10 - Prob. 10.103CPCh. 10 - Prob. 10.104CPCh. 10 - Prob. 10.105CPCh. 10 - Prob. 10.106CPCh. 10 - Determine each of the following for a 0.050 M KOH...Ch. 10 - Determine each of the following for a 0.100 M HBr...Ch. 10 - A 0.204 M NaOH solution is used to titrate 50.0 mL...Ch. 10 - A 0.312 M KOH solution is used to titrate 15.0 mL...Ch. 10 - One of the most acidic lakes in the United States...Ch. 10 - Prob. 10.112CP
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