CHEMISTRY: THE MOLECULAR NATURE OF MATTE
9th Edition
ISBN: 9781265974688
Author: SILBERBERG
Publisher: MCG
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Chapter 10, Problem 10.30P
Interpretation Introduction
Interpretation:
The name of all the molecular shapes that have a tetrahedral electron-group arrangement is to be determined.
Concept introduction:
VSEPR theory is based on the repulsions between the electrons pair in the valence shell. According to VSEPR theory, the shape of a molecule depends on the position of the electron pairs to minimize the repulsion, and maximize the stability.
According to VSEPR theory, the table for molecular geometries when the central atom has no lone pair is as follows:
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There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS).
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SV, arb. units
20.0
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A mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C.
H₂O(g) + C₁₂O(g) = 2 HOCl(g)
K = 0.0900 at 25°C
с
Calculate the equilibrium concentrations of each gas at 25 °C.
[H₂O]=
[C₁₂O]=
[HOCI]=
M
Σ
M
What units (if any) does the response factor (K) have? Does the response factor (K) depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)?
Chapter 10 Solutions
CHEMISTRY: THE MOLECULAR NATURE OF MATTE
Ch. 10.1 - Write a Lewis structure for
H2S;
;
SOCl2.
Ch. 10.1 - Prob. 10.1BFPCh. 10.1 - Prob. 10.2AFPCh. 10.1 - Prob. 10.2BFPCh. 10.1 - Prob. 10.3AFPCh. 10.1 - Prob. 10.3BFPCh. 10.1 - Prob. 10.4AFPCh. 10.1 - Prob. 10.4BFPCh. 10.1 - Write a Lewis structure with minimal formal...Ch. 10.1 - Prob. 10.5BFP
Ch. 10.2 - Prob. 10.6AFPCh. 10.2 - Prob. 10.6BFPCh. 10.2 - Prob. 10.7AFPCh. 10.2 - Prob. 10.7BFPCh. 10.2 - Prob. 10.8AFPCh. 10.2 - Prob. 10.8BFPCh. 10.3 - Prob. 10.9AFPCh. 10.3 - Prob. 10.9BFPCh. 10 - Prob. 10.1PCh. 10 - When is a resonance hybrid needed to adequately...Ch. 10 - Prob. 10.3PCh. 10 - Prob. 10.4PCh. 10 - Draw a Lewis structure for (a) SiF4; (b) SeCl2;...Ch. 10 - Draw a Lewis structure for (a) ; (b) C2F4; (c)...Ch. 10 - Prob. 10.7PCh. 10 - Prob. 10.8PCh. 10 - Prob. 10.9PCh. 10 - Draw Lewis structures of all the important...Ch. 10 - Prob. 10.11PCh. 10 - Draw Lewis structures of all the important...Ch. 10 - Prob. 10.13PCh. 10 - Prob. 10.14PCh. 10 - Draw the Lewis structure with lowest formal...Ch. 10 - Draw the Lewis structure with lowest formal...Ch. 10 - Prob. 10.17PCh. 10 - Prob. 10.18PCh. 10 - Prob. 10.19PCh. 10 - Prob. 10.20PCh. 10 - These species do not obey the octet rule. Draw a...Ch. 10 - These species do not obey the octet rule. Draw a...Ch. 10 - Molten beryllium chloride reacts with chloride ion...Ch. 10 - Prob. 10.24PCh. 10 - Prob. 10.25PCh. 10 - Phosgene is a colorless, highly toxic gas that was...Ch. 10 - If you know the formula of a molecule or ion, what...Ch. 10 - In what situation is the name of the molecular...Ch. 10 - Prob. 10.29PCh. 10 - Prob. 10.30PCh. 10 - Consider the following molecular shapes. (a) Which...Ch. 10 - Use wedge-bond perspective drawings (if necessary)...Ch. 10 - Prob. 10.33PCh. 10 - Determine the electron-group arrangement,...Ch. 10 - Determine the electron-group arrangement,...Ch. 10 - Prob. 10.36PCh. 10 - Prob. 10.37PCh. 10 - Prob. 10.38PCh. 10 - Prob. 10.39PCh. 10 - Determine the shape, ideal bond angle(s), and the...Ch. 10 - Prob. 10.41PCh. 10 - Determine the shape around each central atom in...Ch. 10 - Prob. 10.43PCh. 10 - Prob. 10.44PCh. 10 - Prob. 10.45PCh. 10 - Prob. 10.46PCh. 10 - Arrange the following ACln species in order of...Ch. 10 - State an ideal value for each of the bond angles...Ch. 10 - Prob. 10.49PCh. 10 - Prob. 10.50PCh. 10 - Prob. 10.51PCh. 10 - Prob. 10.52PCh. 10 - How can a molecule with polar covalent bonds not...Ch. 10 - Prob. 10.54PCh. 10 - Consider the molecules SCl2, F2, CS2, CF4, and...Ch. 10 - Consider the molecules BF3, PF3, BrF3, SF4, and...Ch. 10 - Prob. 10.57PCh. 10 - Prob. 10.58PCh. 10 - Prob. 10.59PCh. 10 - Prob. 10.60PCh. 10 - Prob. 10.61PCh. 10 - Prob. 10.62PCh. 10 - Prob. 10.63PCh. 10 - Prob. 10.64PCh. 10 - Prob. 10.65PCh. 10 - Prob. 10.66PCh. 10 - When SO3 gains two electrons, forms. (a) Which...Ch. 10 - The actual bond angle in NO2 is 134.3°, and in it...Ch. 10 - Prob. 10.69PCh. 10 - Propylene oxide is used to make many products,...Ch. 10 - Prob. 10.71PCh. 10 - Prob. 10.72PCh. 10 - Prob. 10.73PCh. 10 - Prob. 10.74PCh. 10 - Prob. 10.75PCh. 10 - Prob. 10.76PCh. 10 - Prob. 10.77PCh. 10 - A gaseous compound has a composition by mass of...Ch. 10 - Prob. 10.79PCh. 10 - Prob. 10.80PCh. 10 - Prob. 10.81PCh. 10 - Prob. 10.82PCh. 10 - Pure HN3 (atom sequence HNNN) is explosive. In...Ch. 10 - Prob. 10.84PCh. 10 - Prob. 10.85PCh. 10 - Oxalic acid (H2C2O4) is found in toxic...Ch. 10 - Prob. 10.87PCh. 10 - Hydrazine (N2H4) is used as a rocket fuel because...Ch. 10 - Prob. 10.89PCh. 10 - Prob. 10.90PCh. 10 - Prob. 10.91PCh. 10 - Consider the following molecular shapes:
Match...Ch. 10 - Prob. 10.93PCh. 10 - Prob. 10.94PCh. 10 - Prob. 10.95PCh. 10 - Phosphorus pentachloride, a key industrial...
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