ORGANIC CHEMISTRY BOOK& SG/SM
ORGANIC CHEMISTRY BOOK& SG/SM
6th Edition
ISBN: 9781264094493
Author: SMITH
Publisher: MCG
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Chapter 1, Problem 84P
Interpretation Introduction

Interpretation: The resonance structures (at least 10) for acetaminophen are to be drawn.

Concept introduction: Acetaminophen is an analgesic and antipyretic drug that works as an active pain reliever. This metabolite is present in the medicines like Tylenol. It is a derivative of p aminophenol. The molecular formula of acetaminophen is C8H9NO2.

The method by which overall delocalization of electrons can be described in a particular molecule is known as resonance.

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2. Provide a complete retrosynthetic analysis and a complete forward synthetic scheme to make the following target molecule from the given starting material. You may use any other reagents necessary. Br
146. Use the following data for NH3(g) at 273 K to determine B2p (T) at 273 K. P (bar) 0.10 0.20 0.30 0.40 0.50 0.60 (Z -1)/10-4 1.519 3.038 4.557 6.071 7.583 9.002 0.70 10.551
110. Compare the pressures given by (a) the ideal gas law, (b) the van der Waals equation, and (c) the Redlic-Kwong equation for propane at 400 K and p = 10.62 mol dm³. The van der Waals parameters for propane are a = 9.3919 dm6 bar mol-2 and b = 0.090494 dm³ mol−1. The Redlich-Kwong parameters are A = 183.02 dm bar mol-2 and B = 0.062723 dm³ mol-1. The experimental value is 400 bar.

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