Organic Chemistry, Third Edition Binder Ready Version
Organic Chemistry, Third Edition Binder Ready Version
3rd Edition
ISBN: 9781119110453
Author: Klein
Publisher: WILEY
Question
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Chapter 1, Problem 79CP

(a)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2.  To determine which of the two compound will be more soluble in polar solvent.  To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

Formal charge on a atom is the charge that is associated with the atom that does not have appropriate number of valence electrons.  To find the formal charge on an atom in a compound the total number of valence electrons of the atom must be known.

To identify: To identify whether the two given compounds possess any formal charge.

(b)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2.  To determine which of the two compound will be more soluble in polar solvent.  To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

Formal charge on a atom is the charge that is associated with the atom that does not have appropriate number of valence electrons.  To find the formal charge on an atom in a compound the total number of valence electrons of the atom must be known.

(c)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2.  To determine which of the two compound will be more soluble in polar solvent.  To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

The atomic orbitals mix together to form a hybrid orbital which is suitable for forming bonds between the atoms to form a compound.  This mixing of hybrid orbitals is known as hybridization.  The hybridization determines the geometry of the particular atom in the compound.  Shortly to say

sp3hybridized =tetrahedral

trigonal pyramidal(if one lone pair of electron is present)

bent geometry (if two lone pair of electrons are present)

sp2hybridized =trigonal planar

sp hybridized =linear

Each and every hybridized orbital has its own bond angle,

sp3hybridized = 109.5°

sp2hybridized = 120°

sp hybridized = 180°

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Chapter 1 Solutions

Organic Chemistry, Third Edition Binder Ready Version

Ch. 1.3 - Prob. 8PTSCh. 1.3 - Prob. 9PTSCh. 1.3 - Prob. 10PTSCh. 1.3 - Prob. 11ATSCh. 1.4 - Prob. 4LTSCh. 1.4 - Prob. 12PTSCh. 1.4 - Prob. 13PTSCh. 1.4 - Prob. 14ATSCh. 1.5 - Prob. 5LTSCh. 1.5 - Prob. 15PTSCh. 1.5 - Prob. 16ATSCh. 1.5 - Prob. 17ATSCh. 1.6 - Prob. 6LTSCh. 1.6 - Prob. 18PTSCh. 1.6 - Prob. 19PTSCh. 1.6 - Prob. 20ATSCh. 1.9 - Prob. 21CCCh. 1.9 - Prob. 22CCCh. 1.9 - Prob. 23CCCh. 1.9 - Prob. 7LTSCh. 1.9 - PRACTICE the skill Determine the hybridization...Ch. 1.9 - APPLY the skill Nemotin is a compound that was...Ch. 1.9 - Prob. 26CCCh. 1.10 - 1.8 PREDICTING GEOMETRY LEARN the skill Using...Ch. 1.10 - PRACTICE the skill Use VSEPR theory to Predict the...Ch. 1.10 - Prob. 28PTSCh. 1.10 - Ammonia (NH3) will react with a strong acid, such...Ch. 1.10 - Volatile organic compounds (VOCs) contribute to...Ch. 1.11 - Prob. 9LTSCh. 1.11 - Prob. 31PTSCh. 1.11 - Volatile organic compounds (VOCs) contribute to...Ch. 1.12 - Prob. 10LTSCh. 1.12 - Prob. 33PTSCh. 1.12 - Epichlorohydrin (1) is an epoxide used in the...Ch. 1 - Prob. 35PPCh. 1 - Prob. 36PPCh. 1 - Prob. 37PPCh. 1 - Prob. 38PPCh. 1 - Prob. 39PPCh. 1 - Prob. 40PPCh. 1 - Prob. 41PPCh. 1 - Prob. 42PPCh. 1 - Prob. 43PPCh. 1 - Prob. 44PPCh. 1 - Prob. 45PPCh. 1 - Prob. 46PPCh. 1 - Prob. 47PPCh. 1 - Prob. 48PPCh. 1 - Prob. 49PPCh. 1 - Prob. 50PPCh. 1 - Prob. 51PPCh. 1 - Prob. 52PPCh. 1 - Prob. 53PPCh. 1 - Prob. 54PPCh. 1 - Prob. 55PPCh. 1 - Prob. 56PPCh. 1 - Prob. 57PPCh. 1 - Prob. 58PPCh. 1 - Prob. 59PPCh. 1 - Prob. 60PPCh. 1 - Prob. 61PPCh. 1 - Prob. 62PPCh. 1 - Prob. 63PPCh. 1 - Prob. 64PPCh. 1 - Prob. 65PPCh. 1 - Prob. 66IPCh. 1 - Propose at least two different structures for a...Ch. 1 - Prob. 68IPCh. 1 - Prob. 69IPCh. 1 - Prob. 70IPCh. 1 - Prob. 71IPCh. 1 - Prob. 72IPCh. 1 - Prob. 73IPCh. 1 - Prob. 74IPCh. 1 - Prob. 75IPCh. 1 - Prob. 76IPCh. 1 - Prob. 77IPCh. 1 - Prob. 78CPCh. 1 - Prob. 79CPCh. 1 - Prob. 80CPCh. 1 - Prob. 81CP
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