ORGANIC CHEMISTRY W/CONNECT & ALEKS
6th Edition
ISBN: 9781264683888
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 1, Problem 75P
Anacin is an over-the-counter pain reliever that contains aspirin and caffeine. Answer the following
questions about each compound.
a. What is the molecular formula?
b. How many lone pairs are present on heteroatoms?
c. Label the hybridisation state of each carbon.
d. Draw three additional resonance structures.
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LABORATORY REPORT FORM
Part I. Determination of the Formula of a Known Hydrate
1. Mass of empty evaporating dish
3. Mass of hydrate
Using subtraction
or mass by difference,
find the mass of
the hydrate
76.96
-75.40
75.40g
76.968
1.568
01.56
76.90 g
2. Mass of evaporating dish + hydrate
4. Mass of evaporating dish + hydrate (after heating)
First 76.98 g
Third 76.66g
Second
Fourth (if necessary) 76.60g
5. Mass of anhydrate
6. Mass of water lost by the hydrate
7. Percent of water of hydration
(Show Calculations)
8. Moles of water
(Show Calculations)
mol
mass of water
=
MM of water (g/m)
9. Moles of anhydrate
(Show Calculations)
10. Ratio of moles of water to moles of anhydrate
11 F(Show Calculations)
11. Formula of hydrate
- Mass of water (g) x 100
% water hydration
g
g
%
Mass of hydrate (9) x IC
% = (Mass of hydrate- mass of an)
mass of hydrate (g)
% = (1.569-
× 100=
mol
1.569
mol Mol Mass of
anhydrate/MM
of anhydrate
12. What was the color of the hydrate?
blue
What was the color of the…
compared t-critical with t-calculated and 95% confidence interval to answer this question
Comparing two means. Horvat and co-workers used atomic absorption spectroscopy to determine the concentration of Hg in coal fly ash. Of particular interest to the authors was developing an appropriate procedure for digesting samples and releasing the Hg for analysis. As part of their study they tested several reagents for digesting samples. Their results using HNO3 and using a 1+3 mixture of HNO3 and HCl are shown here. All concentrations are given as ppb Hg sample.
HNO3: 161, 165, 160, 167, 166
1+3 HNO3–HCl: 159, 145, 140, 147, 143, 156
Determine whether there is a significant difference between these methods at the 95% confidence interval.
Chapter 1 Solutions
ORGANIC CHEMISTRY W/CONNECT & ALEKS
Ch. 1.1 - While the most common isotope of nitrogen has a...Ch. 1.2 - Label each bond in the following compounds as...Ch. 1.3 - Draw a valid Lewis structure for each species. a....Ch. 1.3 - Prob. 9PCh. 1.4 - Draw Lewis structures for each molecular formula....Ch. 1.6 - Classify each pair of compounds as isomers or...Ch. 1.6 - Prob. 12PCh. 1.6 - Prob. 13PCh. 1.6 - Prob. 14PCh. 1.6 - Prob. 16P
Ch. 1.6 - Prob. 17PCh. 1.7 - Prob. 18PCh. 1.7 - Prob. 19PCh. 1.7 - Using the principles of VSEPR theory, you can...Ch. 1.8 - Convert each condensed formula to a Lewis...Ch. 1.8 - Prob. 22PCh. 1.8 - Prob. 23PCh. 1.8 - Convert each skeletal structure to a complete...Ch. 1 - Citric acid is responsible for the tartness of...Ch. 1 - Zingerone gives ginger its pungent taste. a.What...Ch. 1 - Assign formal charges to each and atom in the...Ch. 1 - Prob. 44PCh. 1 - Prob. 46PCh. 1 - Draw all possible isomers for each molecular...Ch. 1 - 1.45 Draw Lewis structures for the nine isomers...Ch. 1 - Prob. 52PCh. 1 - Prob. 53PCh. 1 - Prob. 54PCh. 1 - Consider compounds A-D, which contain both a...Ch. 1 - Draw in all the carbon and hydrogen atoms in each...Ch. 1 - 1.61 Convert each molecule into a skeletal...Ch. 1 - Prob. 65PCh. 1 - Predict the hybridization and geometry around each...Ch. 1 - Prob. 68PCh. 1 - Ketene, , is an unusual organic molecule that has...Ch. 1 - Rank the following bonds in order of increasing...Ch. 1 - Two useful organic compounds that contain Cl atoms...Ch. 1 - Use the symbols + and to indicate the polarity of...Ch. 1 - Prob. 74PCh. 1 - Anacin is an over-the-counter pain reliever that...Ch. 1 - 1.77 Stalevo is the trade name for a medication...Ch. 1 - 1.78 and are two highly reactive carbon...Ch. 1 - 1.79 The N atom in (acetamide) is hybridized,...Ch. 1 - Prob. 83PCh. 1 - Prob. 84PCh. 1 - Prob. 85PCh. 1 - Prob. 86PCh. 1 - Prob. 87PCh. 1 - Prob. 88P
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