Introductory Chemistry (6th Edition)
6th Edition
ISBN: 9780134302386
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 1, Problem 5E
Define chemistry.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 1 Solutions
Introductory Chemistry (6th Edition)
Ch. 1 - Where can you find chemicals? a. In a hardware...Ch. 1 - Q2. Which statement best defines chemistry?
a. The...Ch. 1 - According to the scientific method, what is a law?...Ch. 1 - Q4. Which statement is an example of an...Ch. 1 - The graph below shows the area of a circle as a...Ch. 1 - Which characteristic is necessary for success in...Ch. 1 - Why does soda fizz?Ch. 1 - 2. What are chemicals? Give some examples.
Ch. 1 - What do chemists try to do? How do they understand...Ch. 1 - 4. What is meant by the statement, “Matter does...
Ch. 1 - Define chemistry.Ch. 1 - How is chemistry connected to everyday life? How...Ch. 1 - 7. Explain the scientific method.
Ch. 1 - Cite an example from this chapter of the...Ch. 1 - What is the difference between a law and a theory?Ch. 1 - 10. What is the difference between a hypothesis...Ch. 1 - What is wrong with the statement, It is just a...Ch. 1 - What is the law of conservation of mass, and who...Ch. 1 - What is the atomic theory, and who formulated it?Ch. 1 - Prob. 14ECh. 1 - Classify each statement as an observation, a law,...Ch. 1 - 16. Classify each statement as an observation, a...Ch. 1 - 17. A student prepares several samples of the same...Ch. 1 - A student measures the volume of a gas sample at...Ch. 1 - A chemist in an imaginary universe does an...Ch. 1 - 20. A chemist decomposes several samples of water...Ch. 1 - 21. The manufacturer of a particular brand of...Ch. 1 - Prob. 22QGWCh. 1 - 23. In your own words, provide a brief definition...Ch. 1 - 24. How curious are you? How good are your...Ch. 1 - 25. The graph displays world population over time....
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