
Chemistry: Atoms First
18th Edition
ISBN: 9781938168154
Author: Richard Langley, Klaus Theopold, Paul Flowers
Publisher: OpenStax College
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
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ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 1 Solutions
Chemistry: Atoms First
Ch. 1 - Explain how you could experimentally determine...Ch. 1 - Identify each of the following statements as being...Ch. 1 - Identify each of the following statements as being...Ch. 1 - Identify each of the underlined items as a part of...Ch. 1 - Identify each of the underlined items as a part of...Ch. 1 - According to one theory, the pressure of a gas...Ch. 1 - The amount of heat required to melt 2 lbs of ice...Ch. 1 - Why do we use an objects mass, rather than its...Ch. 1 - What properties distinguish solids from liquids?...Ch. 1 - How does a heterogeneous mixture differ from a...
Ch. 1 - How does a homogeneous mixture differ from a pure...Ch. 1 - How does an element differ from a compound? How...Ch. 1 - How do molecules of elements and molecules of...Ch. 1 - How does an atom differ from a molecule? In what...Ch. 1 - Many of the items you purchase are mixtures of...Ch. 1 - Classify each of the following as an element, a...Ch. 1 - Classify each of the following as an element, a...Ch. 1 - A sulfur atom and a sulfur molecule are not...Ch. 1 - How are the molecules in oxygen gas, the molecules...Ch. 1 - Why are astronauts in space said to be weightless,...Ch. 1 - Prepare a list of the principal chemicals consumed...Ch. 1 - Matter is everywhere around us. Make a list by...Ch. 1 - When elemental iron corrodes it combines with...Ch. 1 - As stated in the text, convincing examples that...Ch. 1 - Yeast converts glucose to ethanol and carbon...Ch. 1 - Classify the six underlined properties in the...Ch. 1 - Classify each of the following changes as physical...Ch. 1 - Classify each of the following changes as physical...Ch. 1 - The volume of a sample of oxygen gas changed from...Ch. 1 - A 2.0-mer volume of hydrogen gas combined with 1.0...Ch. 1 - Explain the difference between extensive...Ch. 1 - Identify the following properties as either...Ch. 1 - The density (d) of a substance is an intensive...Ch. 1 - Is one liter about an ounce, a pint, a quart, or a...Ch. 1 - Is a meter about an inch, a foot, a yard, or a...Ch. 1 - Indicate the SI base units or derived units that...Ch. 1 - Indicate the SI base units or derived units that...Ch. 1 - Give the name and symbol of the prefixes used with...Ch. 1 - Give the name of the prefix and the quantity...Ch. 1 - A large piece of jewelry has a mass of 132.6 g. A...Ch. 1 - Visit this PhET density simulation...Ch. 1 - Visit this PhET density simulation...Ch. 1 - Visit this PhET density simulation...Ch. 1 - Express each of the following numbers in...Ch. 1 - Express each of the following numbers in...Ch. 1 - Indicate whether each of the following can be...Ch. 1 - Indicate whether each of the following can be...Ch. 1 - How many significant figures are contained in each...Ch. 1 - How many significant figures are contained in each...Ch. 1 - The following quantities were reported on the...Ch. 1 - Round off each of the following numbers to two...Ch. 1 - Round off each of the following numbers to two...Ch. 1 - Perform the following calculations and report each...Ch. 1 - Perform the following calculations and report each...Ch. 1 - Consider the results of the archery contest shown...Ch. 1 - Classify the following sets of measurements as...Ch. 1 - Write conversion factors (as ratios) for the...Ch. 1 - Write conversion factors (as ratios) for the...Ch. 1 - The label on a soft drink boule gives the volume...Ch. 1 - The label on a box of cereal gives the mass of...Ch. 1 - Soccer is played with a round ball having a...Ch. 1 - A woman’s basketball has a circumference between...Ch. 1 - How many milliliters of a soft drink are contained...Ch. 1 - A barrel of oil is exactly 42 gal. How many liters...Ch. 1 - The diameter of a red blood cell is about 3104 in....Ch. 1 - The distance between the centers of the two oxygen...Ch. 1 - Is a 197-lb weight lifter light enough to compete...Ch. 1 - A very good 197-Ib weight lifter lifted 192 kg in...Ch. 1 - Many medical laboratory tests are run using 5.0 L...Ch. 1 - If an aspirin tablet Contains 325 mg aspirin, how...Ch. 1 - Use scientific (exponential) notation to express...Ch. 1 - Complete the following conversions between SI...Ch. 1 - Gasoline is sold by the liter in many countries....Ch. 1 - Milk is sold by the liter in many Countries. What...Ch. 1 - A long ton is defined as exactly 2240 lb. What is...Ch. 1 - Make the conversion indicated in each of the...Ch. 1 - Make the conversion indicated in each of the...Ch. 1 - Many chemistry conferences have held a 50-Trillion...Ch. 1 - Many chemistry conferences have held a 50-Trillion...Ch. 1 - The gas tank of a certain luxury automobile holds...Ch. 1 - As an instructor is preparing for an experiment,...Ch. 1 - To prepare for a laboratory period, a student lab...Ch. 1 - A chemistry student is 159 cm tall and weighs 45.8...Ch. 1 - In a recent Grand Prix, the winner completed the...Ch. 1 - Solve these problems about lumber dimensions. To...Ch. 1 - The mercury content of a stream was believed to be...Ch. 1 - Calculate the density of aluminum if 27.6 cm3 has...Ch. 1 - Osmium is one of the densest elements known. What...Ch. 1 - Calculate these masses. What is the mass of 6.00...Ch. 1 - Calculate these masses. What is the mass of 4.00...Ch. 1 - Calculate these volumes. What is the volume of 25...Ch. 1 - Calculate these volumes. What is the volume of...Ch. 1 - Convert the boiling temperature of gold, 2966 C,...Ch. 1 - Convert the temperature of scalding water, 54 C,...Ch. 1 - Convert the temperature of the coldest area in a...Ch. 1 - Convert the temperature of dry ice, 77 C, into...Ch. 1 - Convert the boiling temperature of liquid ammonia....Ch. 1 - The label on a pressurized can of spray...Ch. 1 - The weather in Europe was unusually warm during...
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- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
- true or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forwardtrue or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forward
- true or false, using the following equilibrium, if carbon dioxide is added the equilibrium will shift toward the productsC(s) + CO2(g) ↔ 2CO(g)arrow_forward2S2O2/3- (aq) + I2 (aq) ---> S4O2/6- (aq) +2I- (aq) Experiment I2 (M) S2O3- (M) Initital Rate (M/s) 1 0.01 0.01 0.0004 2 0.01 0.02 0.0004 3 0.02 0.01 0.0008 Calculate the overall order for this reaction using the table data a) 3b) 0c) 2d) 1arrow_forwardthe decomposition of N2O5 is the first order with a half-life of 1.98 minutes. If the inital concentration of N2O5 is 0.200 M, what is the concentration after 6 minutes?a) 0.612 Mb) 0.035 Mc) 0.024 Md) 0.100 Marrow_forward
- 20.00 mL of 0.150 M HCI is titrated with 0.075 M NaOH. What volume of NaOH is needed?a) 50 mLb) 20 mLc) 40 mLd) 26.66 mLarrow_forward20.00 mL of 0.150 M NaOH is titrated with 37.75 mL of HCI. What is the molarity of the HCI?a) 0.150 Mb) 0.079 Mc) 0.025 Md) 0.050 Marrow_forwardin the following reaction, the OH- acts as which of these?NO2- (aq) + H2O (l) ⇌ OH- (aq) + HNO2 (aq)a) not a weak acidb) basec) acidarrow_forward
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