Concept explainers
The early alchemists used to do an experiment in which water was boiled for several days in a sealed glass container. Eventually, some solid residue would appear in the bottom of the flask, which was interpreted to mean that some of the water in the flask had been converted into “earth.” When Lavoisier repeated this experiment, he found that the water weighed the same before and after heating and the mass of the flask plus the solid residue equaled the original mass of the flask. Were the alchemists correct? Explain what happened. (This experiment is described in the article by A. F. Scott in Scientific American, January 1984.)
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Chapter 1 Solutions
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- The early alchemists used to do an experiment in which water was boiled for several days in a sealed glass container. Eventually. some solid residue would appear in die bottom of the flask, which was interpreted to mean that some of the water in the flask had been converted into earth. When Lavoisier repeated this experiment, he found that the water weighed the same before and after heating, and the mass of die flask plus the solid residue equaled the original mass of the flask. Were the alchemists correct? Explain what really happened. (This experiment is described in the article by A. F. Scott in Scientific American, January 1984.)arrow_forwardThere are 2.619 1022 atoms in 1.000 g of sodium. Assume that sodium atoms are spheres of radius 1.86 and that they are lined up side by side. How many miles in length is the line of sodium atoms?arrow_forwardWhen a sample of phosphorus burns in air, the compound P4O10 forms. One experiment showed that 0.744 g of phosphorus formed 1.704 g of P4O10. Use this information to determine the ratio of the atomic weights of phosphorus and oxygen (mass P/mass O). If the atomic weight of oxygen is assumed to be 16.000, calculate the atomic weight of phosphorus.arrow_forward
- Each of the following statements is true, but Dalton might have had trouble explaining some of them with his atomic theory. Give explanations for the following statements. a. The space-filling models for ethyl alcohol and dimethyl ether are shown below. These two compounds have die same composition by mass (52% carbon, 13% hydrogen, and 35% oxygen), yet the two have different melting points, boiling points, and solubilities in water. b. Burning wood leaves an ash that is only a small fraction of the mass of the original wood. c. Atoms can be broken down into smaller particles. d. One sample of lithium hydride is 87.4% lithium by mass, while another sample of lithium hydride Ls 74.9% lithium by mass. However, the two samples have the same chemical properties.arrow_forwardMass spectrometric analysis showed that there are four isotopes of an unknown element having the following masses and abundances: Three elements in the periodic table that have atomic weights near these values are lanthanum (La), atomic number 57, atomic weight 138.9055; cerium (Ce), atomic number 58, atomic weight 140.115; and praseodymium (Pr), atomic number 59, atomic weight 140.9076. Using the data above, calculate the atomic weight, and identify the element if possible.arrow_forwardDefine the term atomic weight. Why might the values of atomic weights on a planet elsewhere in the universe be different from those on earth?arrow_forward
- Calculate the atomic mass of each of the following elements using the given data for the percentage abundance and mass of each isotope. a. Silver: 51.82% 107Ag (106.9 amu) and 48.18% 109Ag (108.9 amu) b. Silicon: 92.21% 28Si (27.98 amu), 4.70% 29Si (28.98 amu), and 3.09% 30Si (29.97 amu)arrow_forwardChlorine has two isotopes, Cl-35 and Cl-37. Their abundances are 75.53% and 24.47%, respectively. Assume that the only hydrogen isotope present is H-1. (a) How many different HCI molecules are possible? (b) What is the sum of the mass numbers of the two atoms in each molecule? (c) Sketch the mass spectrum for HCI if all the positive ions are obtained by removing a single electron from an HCI molecule.arrow_forwardGive the complete symbol (XZA), including atomic number and mass number, of (a) a nickel atom with 31 neutrons, and (b) a tungsten atom with 110 neutrons.arrow_forward
- Define mass number. What is the difference between mass number and atomic mass?arrow_forwardA sample of metallic element X, weighing 4.315 g, combines with 0.4810 L of Cl2 gas (at normal pressure and 20.0C) to form the metal chloride with the formula XCl. If the density of Cl2 gas under these conditions is 2.948 g/L, what is the mass of the chlorine? The atomic weight of chlorine is 35.45 amu. What is the atomic weight of X? What is the identity of X?arrow_forwardThere are 1.699 1022 atoms in 1.000 g of chlorine. Assume that chlorine atoms are spheres of radius 0.99 and that they are lined up side by side in a 0.5-g sample. How many miles in length is the line of chlorine atoms in the sample?arrow_forward
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