
EBK CHEMISTRY
4th Edition
ISBN: 8220102797864
Author: Burdge
Publisher: YUZU
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Textbook Question
Chapter 1, Problem 30QP
Convert the following temperatures to degrees Celsius: (a)
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each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that:
1. the rate of substitution doesn't depend on nucleophile concentration and
2. the products are a roughly 50/50 mixture of enantiomers.
Substrate A
Substrate B
Faster Rate
X
Ś
CI
(Choose one)
(Choose one)
CI
Br
Explanation
Check
Br
(Choose one)
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
H
O
HỌC—C—0—CH, CH,
2
A
ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
Check
OA
B
OC
ch
B
C
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
Chapter 1 Solutions
EBK CHEMISTRY
Ch. 1.1 - Practice Problem ATTEMPT
Express the freezing...Ch. 1.1 - Practice ProblemBUILD According to the website of...Ch. 1.1 - Prob. 1PPCCh. 1.2 - Prob. 1PPACh. 1.2 - Practice ProblemBUILD In Ray Bradbury's 1953 novel...Ch. 1.2 - Practice ProblemCONCEPTUALIZE If a single degree...Ch. 1.3 - Practice ProblemAttempt Given that 25 .0 mL of...Ch. 1.3 - Practice Problem BUILD
Calculate (a) the density...Ch. 1.3 - Practice ProblemCONCEPTUALIZE Using the picture of...Ch. 1.3 - The coldest temperature ever recorded on Earth was...
Ch. 1.3 - What is the density of an object that has a volume...Ch. 1.3 - A sample of water is heated from room temperature...Ch. 1.3 - Prob. 4CPCh. 1.4 - Prob. 1PPACh. 1.4 - Prob. 1PPBCh. 1.4 - Practice Problem CONCEPTUALIZE
The diagram on the...Ch. 1.4 - Prob. 1CPCh. 1.4 - Prob. 2CPCh. 1.5 - Practice Problem ATTEMPT
Determine the number of...Ch. 1.5 - Practice ProblemBUILD For each of the following...Ch. 1.5 - Prob. 1PPCCh. 1.5 - 1.5.1 What volume of water does the graduated...Ch. 1.5 - Which of the following is the sum of the following...Ch. 1.5 - The true dependence of y on x is represented by...Ch. 1.5 - What is the result of the following calculation to...Ch. 1.6 - Practice ProblemATTEMPT Perform the following...Ch. 1.6 - Practice ProblemBUILD Perform the following...Ch. 1.6 - Practice Problem CONCEPTUALIZE
A citrus dealer in...Ch. 1.6 - The density of lithium metal is 535 kg/m 3 . What...Ch. 1.6 - 1.6.2 Convert to liters.
Ch. 1.6 - 1.6.3 What is the volume of a 5.75-g object that...Ch. 1.6 - How many cubic centimeters are there in a cubic...Ch. 1.7 - Practice Problem ATTEMPT
An empty container with...Ch. 1.7 - Practice Problem BUILD
Another empty container...Ch. 1.7 - Practice ProblemCONCEPTUALIZE Several pieces of...Ch. 1.8 - Practice ProblemATTEMPT The American Heart...Ch. 1.8 - Practice ProblemBUILD An object has a mass of...Ch. 1.8 - Practice ProblemCONCEPTUALIZE The diagram contains...Ch. 1.9 - Practice ProblemATTEMPT The density of silver is...Ch. 1.9 - Practice ProblemBUILD The density of mercury is 13...Ch. 1.9 - Practice ProblemCONCEPTUALIZE Each diagram [ ( i )...Ch. 1 - 1.1
Given that the density of gold is , calculate...Ch. 1 - Prob. 2KSPCh. 1 - Determine the density of the following object in...Ch. 1 - A 28-kg child can consume a maximum of 23...Ch. 1 - Define the terms chemistry and matter.Ch. 1 - 1.2 Explain what is meant by the scientific...Ch. 1 - what is the difference between a hypothesis and a...Ch. 1 - Classify each of the following statements as a...Ch. 1 - Classify each of the following statements as a...Ch. 1 - Identify the elements present in the following...Ch. 1 - Identify the elements present in the following...Ch. 1 - Give an example for each of the following terms:...Ch. 1 - 1.9 Give an example of a homogeneous mixture and...Ch. 1 - Give an example of an element and a compound. How...Ch. 1 - What is the number of known elements?Ch. 1 - Give the names of the elements represented by the...Ch. 1 - 1.13 Give the chemical symbols for the following...Ch. 1 - Classify each of the following substances as an...Ch. 1 - Classify each of the following as an element, a...Ch. 1 - Identify each of the diagrams shown here as a...Ch. 1 - Identify each of the diagrams shown here as an...Ch. 1 - Name the SI base units that are important in...Ch. 1 - 1.19 Write the numbers represented by the...Ch. 1 - 1.20 What units do chemists normally use for the...Ch. 1 - 1.21 What is the difference between mass and...Ch. 1 - 1.22 Describe the three temperature scales used in...Ch. 1 - Bromine is a reddish-brown liquid. Calculate its...Ch. 1 - 1.24 The density of ethanol, a colorless liquid...Ch. 1 - Prob. 25QPCh. 1 - Prob. 26QPCh. 1 - 1.27 The density of water at is . What is the...Ch. 1 - The density of platinum (Pt) is 21 .5 g/cm 3 at...Ch. 1 - Convert the following temperatures to kelvin: (a)...Ch. 1 - Convert the following temperatures to degrees...Ch. 1 - 1.31 Which of the following illustrations best...Ch. 1 - The diagram shows balls of aluminum foil dropped...Ch. 1 - What is the difference between qualitative data...Ch. 1 - Using examples, explain the difference between a...Ch. 1 - How does an intensive property differ from an...Ch. 1 - Determine which of the following properties are...Ch. 1 - Classify the following as qualitative or...Ch. 1 - 1.38 Determine whether the following statements...Ch. 1 - Determine whether each of the following describes...Ch. 1 - 1.40 A student pours 44.3 g of water at into a...Ch. 1 - Prob. 41QPCh. 1 - Comment on whether each of the following...Ch. 1 - What is the advantage of using scientific notation...Ch. 1 - Define significant figure. Discuss the importance...Ch. 1 - Distinguish between the terms accuracy and...Ch. 1 - 1.46 Express the following numbers in scientific...Ch. 1 - Express the following as decimals: (a) 1.52 × 10 −...Ch. 1 - Express the answers to the following calculations...Ch. 1 - 1.49 Express the answers to the following...Ch. 1 - 1.50 Determine the number of significant figures...Ch. 1 - Determine the number of significant figures in...Ch. 1 - Prob. 52QPCh. 1 - Carry out the following operations as if they were...Ch. 1 - Three students ( A, B, and C ) are asked to...Ch. 1 - Three apprentice tailors ( X, Y, and Z ) are...Ch. 1 - Carry out the following conversions: (a) 22.6 m to...Ch. 1 - Carry out the following conversions: (a) 242 lb to...Ch. 1 - The average speed of helium at 25°C is 1255 m/s ....Ch. 1 - Prob. 59QPCh. 1 - Prob. 60QPCh. 1 - Prob. 61QPCh. 1 - 1.62 A 6.0-ft person weighs 168 lb. Express this...Ch. 1 - The highest speed limit in the United States is 85...Ch. 1 - For a fighter jet to take off from the deck of an...Ch. 1 - Prob. 65QPCh. 1 - Prob. 66QPCh. 1 - Carry out the following conversions: (a) 185 nm to...Ch. 1 - 1.68 Aluminum is a lightweight metal used in...Ch. 1 - Prob. 69QPCh. 1 - (a) Carbon monoxide ( CO ) is a poisonous gas...Ch. 1 - Prob. 71QPCh. 1 - A human brain weighs about 1 kg and contains about...Ch. 1 - Using the appropriate number of significant...Ch. 1 - 1.74 A piece of metal with a mass of 13.2 g was...Ch. 1 - 1.75 Which of the following statements describe...Ch. 1 - 1.76 In determining the density of a rectangular...Ch. 1 - Calculate the mass of each of the following: (a) a...Ch. 1 - 1.78 A cylindrical glass tube 12.7 cm in length is...Ch. 1 - The following procedure was used to determine the...Ch. 1 - 1.80 The speed of sound in air at room temperature...Ch. 1 - A piece of silver ( Ag ) metal weighing 194.3 g is...Ch. 1 - The experiment described in Problem 1.81 is a...Ch. 1 - A lead sphere has a mass of 1 .20 × 10 4 g . and...Ch. 1 - Lithium is the least dense metal known ( density =...Ch. 1 - At what temperature does the numerical reading on...Ch. 1 - Prob. 86APCh. 1 - Prob. 87APCh. 1 - A sheet of aluminum ( A1 ) foil hat a total area...Ch. 1 - Prob. 89APCh. 1 - 1.90 The surface area and average depth of the...Ch. 1 - The unit "troy ounce" is often used for precious...Ch. 1 - Prob. 92APCh. 1 - Calculate the percent error for the following...Ch. 1 - In water conservation, chemists spread a thin film...Ch. 1 - 1.95 You are given a liquid. Briefly describe the...Ch. 1 - A gas company in Massachusetts charges $1 .30 for...Ch. 1 - Prob. 97APCh. 1 - 1.98 A bank teller is asked to assemble sets of...Ch. 1 - The men's world record for running a mile outdoors...Ch. 1 - 1.100 Venus, the second closest planet to the sun....Ch. 1 - Comment on whether each of the following is a...Ch. 1 - It has been estimated that 8.0 × 10 4 tons of gold...Ch. 1 - Prob. 103APCh. 1 - 1.104 Measurements show that 1.0 g of iron ...Ch. 1 - 1.105 The thin outer layer of Earth, called the...Ch. 1 - 1.106 The radius of a copper atom is roughly ....Ch. 1 - A graduated cylinder is filled to the 40.00-mL...Ch. 1 - A chemist mixes two liquids A and B to form a...Ch. 1 - A chemist in the nineteenth century prepared an...Ch. 1 - Chlorine is used to disinfect swimming pools. The...Ch. 1 - Prob. 111APCh. 1 - Prob. 112APCh. 1 - Chalcopyrite, the principal one of copper ( Cu ) ,...Ch. 1 - 1.114 Vanillin (used to flavor vanilla ice cream...Ch. 1 - One gallon of gasoline in an automobile’s engine...Ch. 1 - 1.116 Magnesium (Mg) is a valuable metal used in...Ch. 1 - Prob. 117APCh. 1 - The natural abundances of elements in the human...Ch. 1 - A resting adult requires about 240 mL of pure...Ch. 1 - 1.120 (a) Referring to Problem 1.119. calculate...Ch. 1 - The medicinal thermometer commonly used in homes...Ch. 1 - TUMS is a popular remedy for acid indigestion. A...Ch. 1 - Prob. 123APCh. 1 - English writer and essayist Lady Mary Wortley...Ch. 1 - English writer and essayist Lady Mary Wortley...Ch. 1 - English writer and essayist Lady Mary Wortley...Ch. 1 - English writer and essayist Lady Mary Wortley...
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