Student Solutions Manual for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th
11th Edition
ISBN: 9781305081055
Author: Bettelheim, Frederick A.
Publisher: Cengage Learning
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Chapter 1, Problem 1.94P
Interpretation Introduction
Interpretation:
Once during waiting for coffee in a coffee shop you notice a label on decaffeinated coffee as “chemical free”. Elaborate and comment on the label with the knowledge of materials as studied in previous sections.
Concept Introduction:
In chemistry we study the nature, synthesis and properties of any matter.
Matter is made up of chemicals. Any matter around us, with us, within us all is made up of chemicals.
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Question 11 of 18 (1 point) Question Attempt: 3 of
How many signals do you expect in the 'H NMR spectrum for this molecule?
Br
Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: In this question, any multiplet is counted as one signal.
Number of signals in the 'H NMR spectrum.
1
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in top
molecule
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box…
Organic Chemistry
Esterification reactions
1. Write the steps to prepare ester.
2. Write complete reaction of ethanol and acetic acid to make ester.
3. What does ester smell like? What are the uses of ester.
4. What the role of sulfuric acid in the esterification reaction
11. Complete the following esterification reaction with names of all the reactants and products under.
Hint: Remove the water and end up with ester
R-C-OH + ROH
R-C-OR + H₂O
A carboxylic acid
An alcohol
An ester
Water
BYJU'S
H-C-C
O-H
Нин
C-C-C-H
HAAA
H O-C-C-C-H
AAA
Ethanoic acid
Propanol
Water Propyl ethanoate
By com
CH3COOH + CH3CH2CH2CH₂CH₂OH →
Practice for alcohols aldehydes and ketones:
12. Draw the structures from the following names mixed of alcohol/aldehyde and ketone:
a. 4-methyl cyclohexanone
b. 3-methyl-2-pentenal
c. 2,3-dimethylcyclohexanone
d. 1,3propanediol or Propane 1,3 diol
13. Write systematic names for the following compounds identify
functional group:
a.
b. (CH3)2CH-C
OH
c) CH(CH₂)--
OH
-,-,
Chapter 1 Solutions
Student Solutions Manual for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th
Ch. 1.3 - Problem 1-1 Multiply: (a) (6.49107)(7.22103) (b)...Ch. 1.4 - Problem 1-2 Convert: (a) 64.0oC to Fahrenheit (b)...Ch. 1.5 - Prob. 1.3PCh. 1.5 - Problem 1-4 Convert the speed of sound, 332 m/s to...Ch. 1.5 - Problem 1-5 An intensive care patient is receiving...Ch. 1.7 - Problem 1-6 The density of titanium is 4.54 g/mL....Ch. 1.7 - Problem 1-7 An unknown substance has a mass of...Ch. 1.7 - Prob. 1.8PCh. 1.9 - Problem 1-9 How many calories are required to heat...Ch. 1.9 - Problem 1-10 A 100 g piece of iron at 25oC is...
Ch. 1.9 - Prob. 1.11PCh. 1 - 1-12 The life expectancy of a citizen in the...Ch. 1 - 1-13 Define the following terms: (a) Matter (b)...Ch. 1 - 1-14 In Table 1-4, you find four metals (iron,...Ch. 1 - 1-15 In a newspaper, you read that Dr. X claimed...Ch. 1 - Prob. 1.16PCh. 1 - 1-17 Write in exponential notation: (a) 0.351 (b)...Ch. 1 - 1-18 Write out in full: (a) 4.03 × l05 (b) 3.2 ×...Ch. 1 - 1-19 Multiply: (a) (2.16 × 105) (3.08 × 1012) (b)...Ch. 1 - Prob. 1.20PCh. 1 - Prob. 1.21PCh. 1 - Prob. 1.22PCh. 1 - Prob. 1.23PCh. 1 - Prob. 1.24PCh. 1 - 1-25 How many significant figures are in the...Ch. 1 - 1-26 How many significant figures are in the...Ch. 1 - 1-27 Round off to two significant figures: (a)...Ch. 1 - 1-28 Multiply these numbers, using the correct...Ch. 1 - 1.29 Divide these numbers, using the correct...Ch. 1 - 1-30 Add these groups of measured numbers using...Ch. 1 - 1-31 In the SI system, the second is the base unit...Ch. 1 - 1-32 How many grams are in the following? (a)1 kg...Ch. 1 - 1-33 Estimate without actually calculating which...Ch. 1 - 1-34 For each of these, tell which figure is...Ch. 1 - 1-35 You are taken for a helicopter ride in Hawaii...Ch. 1 - Prob. 1.36PCh. 1 - Prob. 1.37PCh. 1 - 1-38 Make the following conversions (conversion...Ch. 1 - 1.39 Make the following metric conversions: (a)964...Ch. 1 - There are 2 bottles of cough syrup available on...Ch. 1 - 1-41 A humidifier located at a nursing station...Ch. 1 - 1-42 You drive in Canada where the distances are...Ch. 1 - 1-43 The speed limit in some European cities is 80...Ch. 1 - 1-44 Your car gets 25.00 miles on a gallon of gas....Ch. 1 - 145 Children’s Chewable Tylenol contains 80. mg of...Ch. 1 - 1-46 A patient weighs 186 lbs. She must receive an...Ch. 1 - 1-47 The doctor orders administration of a drug at...Ch. 1 - 1-48 The recommended pediatric dosage of Velosef...Ch. 1 - 1-49 A critical care physician prescribes an IV of...Ch. 1 - 1-50 If an IV is mixed so that each 150 mL...Ch. 1 - 1-51 A nurse practitioner orders isotonic sodium...Ch. 1 - 1-52 An order for a patient reads Give 40. mg of...Ch. 1 - Prob. 1.53PCh. 1 - Prob. 1.54PCh. 1 - 1-55 Does the chemical nature of a substance...Ch. 1 - 1-56 The volume of a rock weighing 1.075 kg is...Ch. 1 - 1-57 The density of manganese is 7.21 g/mL, that...Ch. 1 - 1.58 The density of titanium is 4.54 g/mL. What is...Ch. 1 - 1-59 An injection of 4 mg of Valium has been...Ch. 1 - 1-60 The density of methanol at 20oC is 0.791...Ch. 1 - 1-61 The density of dichloromethane, a liquid...Ch. 1 - 1-62 A sample of 10.00 g of oxygen has a volume of...Ch. 1 - Prob. 1.63PCh. 1 - Prob. 1.64PCh. 1 - 1-65 While you drive your car, your battery is...Ch. 1 - 1-66 How many calories are required to heat the...Ch. 1 - 1-67 If 168 g of an unknown liquid requires 2750...Ch. 1 - 1-68 The specific heat of steam is 0.48 cal/g oC....Ch. 1 - Prob. 1.69PCh. 1 - 1-70 (Chemical Connections IA) The average lethal...Ch. 1 - Prob. 1.71PCh. 1 - Prob. 1.72PCh. 1 - 1-73 (Chemical Connections 1C) Which would make a...Ch. 1 - Prob. 1.74PCh. 1 - 1-75 A brain weighing 1.0 lb occupies a volume of...Ch. 1 - 1-76 If the density of air is 1.25 10-3 g/cc,...Ch. 1 - 1-77 Classify these as kinetic or potential...Ch. 1 - 1-78 The kinetic energy possessed by an object...Ch. 1 - 1-79 A European car advertises an efficiency of 22...Ch. 1 - Prob. 1.80PCh. 1 - Prob. 1.81PCh. 1 - 1-82 When the astronauts walked on the Moon, they...Ch. 1 - 1-83 Which of the following is the largest mass...Ch. 1 - 1-84 Which quantity is bigger in each of the...Ch. 1 - 1-85 In Japan, high-speed “bullet trains” move...Ch. 1 - 1-86 The specific heats of some elements at 25oC...Ch. 1 - 1-87 Water that contains deuterium rather than...Ch. 1 - 1-88 One quart of milk costs 80 cents and one...Ch. 1 - 1-89 Consider butter, density 0.860 g/mL, and...Ch. 1 - 1-90 Which speed is the fastest? (a) 70 mi/h (b)...Ch. 1 - 1-91 In calculating the specific heat of a...Ch. 1 - 1-92 A solar cell generates 500. kJ of energy per...Ch. 1 - 1-93 The specific heat of urea is 1.339 J/g . If...Ch. 1 - Prob. 1.94PCh. 1 - 1-95 You receive an order for 60. mg of meperidine...Ch. 1 - Prob. 1.96PCh. 1 - Prob. 1.97PCh. 1 - 1-98 The antifreeze-coolant compound used in cars...Ch. 1 - Prob. 1.99PCh. 1 - Prob. 1.100PCh. 1 - Prob. 1.101PCh. 1 - Prob. 1.102PCh. 1 - Prob. 1.103PCh. 1 - Prob. 1.104PCh. 1 - Prob. 1.105PCh. 1 - Prob. 1.106PCh. 1 - Prob. 1.107PCh. 1 - Prob. 1.108PCh. 1 - Prob. 1.109PCh. 1 - Prob. 1.110PCh. 1 - 1-111 In the hospital, your doctor orders 100. mg...Ch. 1 - 1-112 A febrile, pediatric patient weighs 42...
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- may you please show all steps! i am having a hard time understanding and applying in this format, thank you!arrow_forward10. Complete the substitution reaction of 2 pentanol with these reagents. Reagents & Reaction Conditions use practice sheet. Please write only major products, minor product like water, other gases are not required. Hint: In substitution of alcohol, we generally substitute OH group with Halogens like cl, Br, F using some reagent containing halogens. Ensure to add halogens to the same carbon number where you are removing OH from Examples Alcohols can be converted to Alkyl Halides with HX acids HBr H₂O HCI + H₂O HI + H₂O CH,CH₂OH + SOCI₂ CH,CH₂OH + PCI₁₂ A BBYJU'S CH CHCI + SO₂+ HCI CH₂CH CIP(OH), + HCI CH,CH₂OH + PCI CHCHCI + POCI + HCI CH,CH₂OH + PBr, CH,CH,Br + P(OH), + HBr 1. Reaction with HBr with 2 Pentanol 2.Reaction with HI with 2 pentanol © Byjus.com 3.Reaction with HCI+ZnCl,, with 2 pentanol (Zncl2 is catalyst no role) 4.Reaction with SOCI,, with 2 Pentanol 5.Reaction with PBr; or PCl, with 2 pentanolarrow_forward3. Is 2-methyl-2-propanol a primary, secondary, or tertiary alcohol? Write out the structures of 2-methyl-2-propanol and also any oxidation products of 2- methyl-2- propanol. If there is more than one oxidation product, give the structure of each of the products. 4. 2-Propanol is the IUPAC systematic name of this alcohol. It has a common name by which it is much better known (You'll see it in the grocery store or pharmacy). Give that common name 5. Aldehydes can be synthesized by the oxidation of. Please choose from below choices A. Primary alcohols B. Secondary alcohols C. Organic acids D. Inorganic acids 6. Tertiary alcohol Can undergo oxidation. yes or no. ? If yes then answer the product.arrow_forward
- Finish the reactions hand written pleasearrow_forwardPart A Identify each alcohol as primary, secondary, or tertiary Drag the appropriate items to their respective bins. CH₂ H₂C- -C-OH HO CH₂ Primary Он OH CH₂ OH CCH₂OH CH₂ сн Secondary Tertiary Reset Help CH,CH₂ (CH)CHCH,OH CH,CH,CH,CCH, CHOH CH₂ Different types of alcohol groups Alcohol and its reaction: 8. Combing two alcohol molecules below and completing the reaction with Product .( Hint Reaction called etherification as ether is formed and name the ether once you complete the reaction. Hint.: R-O-H+H-O-RR-O-R Do the reaction: CH₂OH + CH₂OH---→ + H-O-H 9. Write the reaction of formation of alcohol from alkene by adding water: Addition reaction also called hydration reaction as we are adding water which occur always in presence of acid Hint: Break the double bond and add H and OH if symmetrical then add anywhere if unsymmetrical then follow Markovnikov rule H should go to that double bone carbon which has more hydrogen CH2=CH2 + H₂O-→arrow_forwardComplete the reaction hand written pleasearrow_forward
- Predict the major products of this organic reaction: HBr (1 equiv) cold ? Some important notes: • Draw the major product, or products, of this reaction in the drawing area below. • You can draw the products in any arrangement you like. • Pay careful attention to the reaction conditions, and only include the major products. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. • Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions. dm Re Explanation Check ©2025 McGraw Hill LLC. All Rights Reserved. Termarrow_forwardb) Use curved arrows to show the reaction of the radical with hydrogen bromide. Br: Br H .. Answer Bankarrow_forwardIndicate the reaction products when CH3COCH2COOCH2COOC2H5 (ethyl acetoacetoacetate) reacts with 1º OH-/H2O and 2º H3O+arrow_forward
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