Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with QuickPrep 24-Months Printed Access Card
3rd Edition
ISBN: 9781305367388
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Chapter 1, Problem 1.87PAE
1.87 A solution of ethanol in water has a volume of 54.2 mL and a mass of 49.6 g. what information would you need to look up and how would you determine the percentage of ethanol in this solution?
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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
Bond A
Bond C
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
Weakest
Bond
Strongest
Bond
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
c. (5pts) Use principles discussed in lecture, supported by relevant structures, to
succinctly explain the why your part b (i) radical is more stable than your part b(ii)
radical. Written explanation can be no more than one-two succinct sentence(s)!
Google
Print Last Name, First Name Initial
Statifically more chances to abstract one of these 6H
11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4
4th total
• 6H total
래
• 4H total
21 total
ZH
2H
Statistical
H < 3° C-H weakest
-
product
abstraction here
bund
leads to thermo favored
a) (6pts) How many unique mono-chlorinated products can be formed and what are the
structures for the thermodynamically and statistically favored products?
Product
6
Number of Unique
Mono-Chlorinated Products
Thermodynamically
Favored Product
Statistically
Favored Product
b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the
formation of the thermodynamically favored product. Only draw the p-1 step. You do
not need to include lone pairs of electrons. No enthalpy calculation necessary
H
H-Cl
Waterfox
10. (5pts) Provide the complete arrow pushing mechanism for the chemical transformation →
depicted below
Use proper curved arrow notation that explicitly illustrates all bonds being broken, and
all bonds formed in the transformation.
Also, be sure to include all lone pairs and formal charges on all atoms involved in the
flow of electrons.
CH3O
II
HA
H
CH3O-H
H
①
Chapter 1 Solutions
Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with QuickPrep 24-Months Printed Access Card
Ch. 1 - Prob. 1COCh. 1 - Prob. 2COCh. 1 - Draw pictures to illustrate simple chemical...Ch. 1 - Explain the difference between inductive and...Ch. 1 - Use appropriate techniques to convert measurements...Ch. 1 - Express the results of calculations using the...Ch. 1 - Use the web to determine the mass of a steel...Ch. 1 - Prob. 1.2PAECh. 1 - Where does the scientific method start? What is...Ch. 1 - Use the web to determine the amount of aluminum...
Ch. 1 - Use the web to find current prices offered for...Ch. 1 - Use the web to determine the differences in the...Ch. 1 - When we make observations in the laboratory, which...Ch. 1 - Which of the following items are matter and which...Ch. 1 - Which macroscopic characteristics differentiate...Ch. 1 - How can a liquid be distinguished from a fine...Ch. 1 - Some farmers use ammonia, NHS, as a fertilizer....Ch. 1 - 1.10 Do the terms element and atom mean the same...Ch. 1 - 1.11 Label each of the following as either a...Ch. 1 - 1.12 Why do physical properties play a role in...Ch. 1 - 1.13 Physical properties may change because of a...Ch. 1 - 1.14 Which part of the following descriptions of a...Ch. 1 - Use a molecular level description to explain why...Ch. 1 - All molecules attract each other to some extent,...Ch. 1 - 1.15 We used the example of attendance at a...Ch. 1 - 1.16 Complete the following statement: Data that...Ch. 1 - 1.17 Complete the following statement: Data that...Ch. 1 - 1.18 Two golfers are practicing shots around a...Ch. 1 - Prob. 1.23PAECh. 1 - 1.20 Suppose that you are waiting at a corner for...Ch. 1 - 1.21 When a scientist looks at an experiment and...Ch. 1 - 1.22 What is the difference between a hypothesis...Ch. 1 - 1.23 Should the words theory and model be used...Ch. 1 - 1.24 What is a law of nature? Are all scientific...Ch. 1 - 1.25 Describe a miscommunication that can arise...Ch. 1 - 1.26 What is the difference between a qualitative...Ch. 1 - 1.27 Identify which of the following units are...Ch. 1 - 1.28 What is a “derived” unit?Ch. 1 - 1.29 Rank the following prefixes in order of...Ch. 1 - 1.30 The largest computers now include disk...Ch. 1 - Prob. 1.35PAECh. 1 - 1.32 Use the web to determine how the Btu was...Ch. 1 - 1.33 How many micrograms are equal to one gram?Ch. 1 - 1.34 Convert the value 0.120 ppb into ppm.Ch. 1 - 1.35 How was the Fahrenheit temperature scale...Ch. 1 - Superconductors are materials that have no...Ch. 1 - 1.37 Express each of the following temperatures in...Ch. 1 - 1.38 Express (a) 275 oC in K, (b) 25.55 K in oC,...Ch. 1 - 1.39 Express each of the following numbers in...Ch. 1 - 1.40 How many significant figures are there in...Ch. 1 - 1.41 How many significant figures are present in...Ch. 1 - Perform these calculations and express the result...Ch. 1 - 1.43 Calculate the following to the correct number...Ch. 1 - 1.44 In an attempt to determine the velocity of a...Ch. 1 - 1.45 A student finds that the mass of an object is...Ch. 1 - 1.46 Measurements indicate that 23.6% of the...Ch. 1 - 1.47 A student weighs 10 quarters and finds that...Ch. 1 - 1.48 A rock is placed on a balance and its mass is...Ch. 1 - 1.49 A package of eight apples has a mass of 1.00...Ch. 1 - Prob. 1.54PAECh. 1 - 1.51 A person measures 173 cm in height. What is...Ch. 1 - 1.52 The distance between two atoms in a molecule...Ch. 1 - 1.53 Carry out the following unit conversions. (a)...Ch. 1 - 1.54 Carry out each of the following conversions....Ch. 1 - 1.55 Convert 22.3 mL to (a) liters, (b) cubic...Ch. 1 - 1.56 If a vehicle is travelling 92 m/s, what is...Ch. 1 - 1.57 A load of asphalt weights 245 lb. and...Ch. 1 - 1.58 One square mile contains exactly 640 acres....Ch. 1 - 1.59 A sample of crude oil has a density of 0.87...Ch. 1 - 1.60 Mercury has a density of 13.6 g/mL. What is...Ch. 1 - 1.61 The area of the 48 contiguous states is...Ch. 1 - 1.62 The dimensions of aluminium foil in a box for...Ch. 1 - Prob. 1.67PAECh. 1 - 1.64 Wire is often sold in pound spools according...Ch. 1 - 1.65 An industrial engineer is designing a process...Ch. 1 - 1.66 An engineer is working with archaeologists to...Ch. 1 - Draw a molecular scale picture to show how a...Ch. 1 - Prob. 1.72PAECh. 1 - 1.67 On average, Earth’s crust contains about 8.1...Ch. 1 - Prob. 1.74PAECh. 1 - 1.69 The “Western Stone” in Jerusalem is one of...Ch. 1 - A load of bauxite has a density of 3.15 g/cm3. If...Ch. 1 - Prob. 1.77PAECh. 1 - Prob. 1.78PAECh. 1 - Prob. 1.79PAECh. 1 - Prob. 1.80PAECh. 1 - Prob. 1.81PAECh. 1 - Use the web to research the elastic modulus and...Ch. 1 - Prob. 1.83PAECh. 1 - 1.84 A student was given two metal cubes that...Ch. 1 - 1.85 Battery acid has a density of 1.285 g/mL and...Ch. 1 - 1.86 Unfermented grape juice used to make wine is...Ch. 1 - 1.87 A solution of ethanol in water has a volume...Ch. 1 - 1.88 Legend has it that Archimedes, a famous...Ch. 1 - 1.89 Imagine that you place a cork measuring...Ch. 1 - 1.90 A calibrated flask was filled to the 25.00-mL...
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