GENERAL, ORGANIC, BIOCHEM (ACCESS CARD)
10th Edition
ISBN: 9781260886023
Author: Denniston
Publisher: INTER MCG
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Chapter 1, Problem 1.28QP
Interpretation Introduction
Interpretation:
The term energy has to be defined and the importance of energy in chemistry has to be explained.
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-AG|F=2E|V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
Acidic solution
-0.93
+0.38
-0.51 -0.06
H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3
-0.28
-0.50
→
-0.50
Basic solution
3-1.12
-1.57
-2.05 -0.89
PO HPO →→H2PO2 P PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5 PH,
0.0
-0.5-
2 3 9 3
-1.5
-2.0
Pa
H,PO
H,PO
H,PO
-3
-1 0
2
4
Oxidation state, N
2
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…
These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?
What would be the best choices for the missing reagents 1 and 3 in this synthesis?
1. PPh3
3
1
2
2. n-BuLi
• Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like.
• Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is.
• Note: if one of your reagents needs to contain a halogen, use bromine.
Explanation
Check
Click and drag to start drawing a structure.
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Chapter 1 Solutions
GENERAL, ORGANIC, BIOCHEM (ACCESS CARD)
Ch. 1.2 - Prob. 1.1PPCh. 1.3 - Is each of the following materials a pure...Ch. 1.3 - Intravenous therapy may be used to introduce a...Ch. 1.3 - Cloudy urine can be a symptom of a bladder...Ch. 1.3 - Classify each of the following as either a...Ch. 1.3 - Prob. 1.5QCh. 1.3 - Prob. 1.6QCh. 1.3 - Prob. 1.4PPCh. 1.3 - Label each property as intensive or extensive:
the...Ch. 1.3 - Label each property as intensive or extensive:
the...
Ch. 1.5 - How many significant figures are contained in each...Ch. 1.5 - Prob. 1.10QCh. 1.5 - Prob. 1.11QCh. 1.5 - Prob. 1.12QCh. 1.5 - Prob. 1.13QCh. 1.5 - Prob. 1.14QCh. 1.5 - Prob. 1.15QCh. 1.5 - Prob. 1.16QCh. 1.5 - Prob. 1.5PPCh. 1.5 - Prob. 1.17QCh. 1.5 - Prob. 1.18QCh. 1.5 - Prob. 1.6PPCh. 1.5 - Prob. 1.19QCh. 1.5 - Prob. 1.20QCh. 1.6 - Convert 360 ft to mi.
Ch. 1.6 - Convert:
750 cm to mm
1.5 × 108 μL to cL
0.00055...Ch. 1.6 - Convert:
0.50 in to m
0.75 qt to L
56.8 g to...Ch. 1.6 - Convert:
1.5 cm2 to m2
3.6 m2 to cm2
Ch. 1.6 - Convert 0.791 g/mL to kg/L.
Ch. 1.7 - The freezing temperature of water is 32°F....Ch. 1.7 - Prob. 1.21QCh. 1.7 - Prob. 1.22QCh. 1.7 - Prob. 1.13PPCh. 1.7 - Prob. 1.14PPCh. 1.7 - Prob. 1.15PPCh. 1.7 - Calculate the volume, in mL, of 10.0 g of a saline...Ch. 1 - Prob. 1.23QPCh. 1 - Consider the Study Cycle. Explain how you will...Ch. 1 - Define chemistry and explain how burning wood is...Ch. 1 - Prob. 1.28QPCh. 1 - Why is experimentation an important part of the...Ch. 1 - Prob. 1.30QPCh. 1 - What data would be required to estimate the total...Ch. 1 - What data would be required to estimate the mass...Ch. 1 - What are the characteristics of methane emphasized...Ch. 1 - Discuss the difference between hypothesis and...Ch. 1 - Discuss the difference between theory and...Ch. 1 - We use aspects of the scientific method in our...Ch. 1 - Experimentation has shown that stem cell research...Ch. 1 - Observed increases in global temperatures are...Ch. 1 - Prob. 1.41QPCh. 1 - List the three states of matter.
Ch. 1 - Explain the differences among the three states of...Ch. 1 - Prob. 1.45QPCh. 1 - Prob. 1.46QPCh. 1 - Prob. 1.47QPCh. 1 - Prob. 1.48QPCh. 1 - Explain the difference between chemical properties...Ch. 1 - List the differences between chemical changes and...Ch. 1 - Label each of the following as pertaining to...Ch. 1 - Prob. 1.52QPCh. 1 - Label each of the following as either a...Ch. 1 - Prob. 1.54QPCh. 1 - Prob. 1.55QPCh. 1 - Prob. 1.56QPCh. 1 - Label each of the following as either a physical...Ch. 1 - Prob. 1.58QPCh. 1 - Label each of the following properties of sodium...Ch. 1 - Prob. 1.60QPCh. 1 - Label each of the following as either a pure...Ch. 1 - Prob. 1.62QPCh. 1 - Prob. 1.63QPCh. 1 - Prob. 1.64QPCh. 1 - Prob. 1.65QPCh. 1 - Prob. 1.66QPCh. 1 - Prob. 1.67QPCh. 1 - Mass is the measure of what property of matter?
Ch. 1 - Explain the difference between mass and weight.
Ch. 1 - Prob. 1.71QPCh. 1 - Prob. 1.72QPCh. 1 - How is the metric unit of L defined?
Ch. 1 - What English unit of volume is similar to a L?
Ch. 1 - Rank the following from shortest to longest...Ch. 1 - Rank the following from least to greatest mass.
Ch. 1 - Determine the temperature reading of the following...Ch. 1 - Prob. 1.78QPCh. 1 - Prob. 1.79QPCh. 1 - Prob. 1.80QPCh. 1 - How many significant figures are represented in...Ch. 1 - Prob. 1.82QPCh. 1 - Round the following numbers to three significant...Ch. 1 - Round the following numbers to three significant...Ch. 1 - Perform each of the following operations,...Ch. 1 - Prob. 1.86QPCh. 1 - Prob. 1.87QPCh. 1 - Prob. 1.88QPCh. 1 - Prob. 1.89QPCh. 1 - Prob. 1.90QPCh. 1 - Prob. 1.91QPCh. 1 - Prob. 1.92QPCh. 1 - Give the abbreviation and meaning of the following...Ch. 1 - Fill in the blank with the missing abbreviation...Ch. 1 - Write the two conversion factors that can be...Ch. 1 - Write the two conversion factors that can be...Ch. 1 - Prob. 1.97QPCh. 1 - Prob. 1.98QPCh. 1 - Convert 1.50 × 104 μg to mg.
Ch. 1 - Prob. 1.100QPCh. 1 - Prob. 1.101QPCh. 1 - Prob. 1.102QPCh. 1 - A typical office has 144 ft2 of floor space....Ch. 1 - Prob. 1.104QPCh. 1 - Prob. 1.105QPCh. 1 - Prob. 1.106QPCh. 1 - Prob. 1.107QPCh. 1 - Prob. 1.108QPCh. 1 - Prob. 1.109QPCh. 1 - Prob. 1.110QPCh. 1 - Which mass is smaller: 5.0 mg or 5.0 μg?
Ch. 1 - Which volume is smaller: 1.0 L or 1.0 qt?
Ch. 1 - Prob. 1.113QPCh. 1 - Prob. 1.114QPCh. 1 - Prob. 1.115QPCh. 1 - Prob. 1.116QPCh. 1 - Prob. 1.117QPCh. 1 - Prob. 1.118QPCh. 1 - Prob. 1.119QPCh. 1 - Prob. 1.120QPCh. 1 - Convert 50.0°F to:
°C
K
Ch. 1 - The weather station posted that the low for the...Ch. 1 - The thermostat shows that the room temperature is...Ch. 1 - Convert 300.0 K to:
°C
°F
Ch. 1 - Prob. 1.125QPCh. 1 - Prob. 1.126QPCh. 1 - Calculate the density of a 3.00 × 102 g object...Ch. 1 - Calculate the density of 50.0 g of an isopropyl...Ch. 1 - What is the mass, in g, of a piece of iron that...Ch. 1 - What is the mass of a femur (leg bone) having a...Ch. 1 - What volume, in L, will 8.00 × 102 g of air occupy...Ch. 1 - Prob. 1.132QPCh. 1 - For the treatment of cystic fibrosis, it has been...Ch. 1 - You are given a piece of wood that is either...Ch. 1 - You are given three bars of metal. Each is labeled...Ch. 1 - Refer to Question 1.135. Suppose that each of the...Ch. 1 - The density of methanol at 20°C is 0.791 g/mL....Ch. 1 - Prob. 1.138QPCh. 1 - The density of methanol at 20°C is 0.791 g/mL....Ch. 1 - Prob. 1.140QPCh. 1 - Prob. 1.141QPCh. 1 - The specific gravity of a patient’s urine sample...Ch. 1 - The density of grain alcohol is 0.789 g/mL. Given...Ch. 1 - The density of whole human blood in a healthy...Ch. 1 - Aspirin has been recommended to minimize the...Ch. 1 - Prob. 2MCPCh. 1 - Consider the Chapter Map, and explain these...Ch. 1 - An instrument used to detect metals in drinking...Ch. 1 - Prob. 5MCPCh. 1 - Prob. 6MCPCh. 1 - Prob. 7MCPCh. 1 - A balloon is filled with helium at a temperature...Ch. 1 - The diameter of an aluminum atom is 250 picometers...
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- Draw the anti-Markovnikov product of the hydration of this alkene. this problem. Note for advanced students: draw only one product, and don't worry about showing any stereochemistry. Drawing dash and wedge bonds has been disabled for esc esc ☐ Explanation Check F1 1 2 F2 # 3 F3 + $ 14 × 1. BH THE BH3 2. H O NaOH '2 2' Click and drag to start drawing a structure. F4 Q W E R A S D % 905 LL F5 F6 F7 © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility < & 6 7 27 8 T Y U G H I F8 F9 F10 F11 F12 9 0 J K L P + // command option Z X C V B N M H H rol option commandarrow_forwardAG/F-2° V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: -0.93 +0.38 -0.50 -0.51 -0.06 H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3 Acidic solution Basic solution -0.28 -0.50 3--1.12 -1.57 -2.05 -0.89 PO HPO H₂PO₂ →P → PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH P 0.0 -0.5 -1.0- -1.5- -2.0 H.PO, -2.3+ -3 -2 -1 1 2 3 2 H,PO, b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) H,PO 4 S Oxidation stale, Narrow_forward4. For the following complexes, draw the structures and give a d-electron count of the metal: a) Tris(acetylacetonato)iron(III) b) Hexabromoplatinate(2-) c) Potassium diamminetetrabromocobaltate(III) (6 points)arrow_forward
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- What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1 1. PPh3 2. n-BuLi 3 2 • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure. Xarrow_forwardWhat is the missing reactant R in this organic reaction? N N H3O+ +R + • Draw the structure of R in the drawing area below. • Be sure to use wedge and dash bonds if it's necessary to draw one particular enantiomer. Click and drag to start drawing a structure. fmarrow_forwardThe product on the right-hand side of this reaction can be prepared from two organic reactants, under the conditions shown above and below the arrow. Draw 1 and 2 below, in any arrangement you like. 1+2 NaBH3CN H+ N Click and drag to start drawing a structure. 5arrow_forward
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