
Chemistry
13th Edition
ISBN: 9781259911156
Author: Raymond Chang Dr., Jason Overby Professor
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 1, Problem 1.114QP
Estimate the volume of blood in an adult in liters.
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Identify the structure of the PTH derivative generated after two rounds of Edman degradation.
Use the data below from an electron impact mass spectrum of a pure compound to deduce its structure. Draw your structure in the
drawing window.
Data selected from the NIST
WebBook,
https://webbook.nist.gov/chemistry/
m/z
Relative intensity
31
0.5
30
26
29
22
28
100
27
33
26
23
15
4
• You do not have to consider stereochemistry.
You do not have to explicitly draw H atoms.
• In cases where there is more than one answer, just draw one.
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Write the molecular formula for a compound with the possible elements C, H, N and O that exhibits a molecular ion at M+ = 98.1106.
Exact Masses of the Most Abundant Isotope of
Selected Elements
Isotope Natural abundance (%) Exact mass
1H
99.985
1.008
12C
98.90
12.000
14N
99.63
14.003
160
99.76
15.995
Molecular formula
(In the order CHNO, with no subscripts)
Chapter 1 Solutions
Chemistry
Ch. 1.3 - Which of the following statements is true? (a) A...Ch. 1.3 - Prob. 2RCFCh. 1.4 - Which of the following diagrams represent elements...Ch. 1.5 - An ice cube is placed in a closed container. On...Ch. 1.6 - The diagram in (a) shows a compound made up of...Ch. 1.6 - Determine which of the following properties are...Ch. 1.7 - A piece of platinum metal with a density of 21.5...Ch. 1.7 - The density of sulfuric acid in a certain car...Ch. 1.7 - Convert (a) 327.5C (the melting point of lead) to...Ch. 1.7 - The density of platinum is 21.45 g/cm3. What is...
Ch. 1.7 - The melting point of adamantine is 518F. What is...Ch. 1.7 - The density of copper is 8.94 g/cm3 at 20C and...Ch. 1.8 - Determine the number of significant figures in...Ch. 1.8 - Carry out the following arithmetic operations and...Ch. 1.8 - Give the length of the pencil with proper...Ch. 1.8 - A student measures the density of an alloy with...Ch. 1.8 - Four mass measurements of a metal cube were made...Ch. 1.9 - A roll of aluminum foil has a mass of 1.07 kg....Ch. 1.9 - The volume of a room is 1.08 108 dm3. What is the...Ch. 1.9 - The density of the lightest metal, lithium (Li),...Ch. 1.9 - Prob. 1RCFCh. 1.9 - What is the volume in L of a 1.24-kg sample of...Ch. 1.9 - Prob. 3RCFCh. 1.10 - Prob. 9PECh. 1 - Explain what is meant by the scientific method.Ch. 1 - What is the difference between qualitative data...Ch. 1 - Classify the following as qualitative or...Ch. 1 - Classify each of the following statements as a...Ch. 1 - Give an example for each of the following terms:...Ch. 1 - Give an example of a homogeneous mixture and an...Ch. 1 - Give an example of an element and a compound. How...Ch. 1 - What is the number of known elements?Ch. 1 - Give the names of the elements represented by the...Ch. 1 - Give the chemical symbols for the following...Ch. 1 - Classify each of the following substances as an...Ch. 1 - Classify each of the following as an element, a...Ch. 1 - Identify each of the diagrams shown here as gas,...Ch. 1 - Explain how the distances between particles...Ch. 1 - Using examples, explain the difference between a...Ch. 1 - How does an intensive property differ from an...Ch. 1 - Do the following statements describe chemical or...Ch. 1 - Does each of the following describe a physical...Ch. 1 - Name the SI base units that are important in...Ch. 1 - Write the numbers represented by the following...Ch. 1 - What units do chemists normally use for density of...Ch. 1 - Describe the three temperature scales used in the...Ch. 1 - Bromine is a reddish-brown liquid. Calculate its...Ch. 1 - The density of methanol, a colorless organic...Ch. 1 - Convert the following temperatures to degrees...Ch. 1 - Prob. 1.26QPCh. 1 - Convert the following temperatures to kelvin: (a)...Ch. 1 - Convert the following temperatures to degrees...Ch. 1 - What is the advantage of using scientific notation...Ch. 1 - Define significant figure. Discuss the importance...Ch. 1 - Express the following numbers in scientific...Ch. 1 - Prob. 1.32QPCh. 1 - Express the answers to the following calculations...Ch. 1 - Express the answers to the following calculations...Ch. 1 - Prob. 1.35QPCh. 1 - How many significant figures are there in each of...Ch. 1 - Carry out the following operations as if they were...Ch. 1 - Carry out the following operations as if they were...Ch. 1 - Three students (A, B, and C) are asked to...Ch. 1 - Three apprentice tailors (X, Y, and Z) are...Ch. 1 - Carry out the following conversions: (a) 22.6 m to...Ch. 1 - Carry out the following conversions: (a) 242 lb to...Ch. 1 - The average speed of helium at 25C is 1255 m/s....Ch. 1 - How many seconds are there in a solar year (365.24...Ch. 1 - Prob. 1.45QPCh. 1 - A jogger runs a mile in 8.92 min. Calculate the...Ch. 1 - A 6.0-ft person weighs 168 lb. Express this...Ch. 1 - The speed limit on parts of the German autobahn...Ch. 1 - Prob. 1.49QPCh. 1 - Prob. 1.50QPCh. 1 - Prob. 1.51QPCh. 1 - Carry out the following conversions: (a) 70 kg,...Ch. 1 - Aluminum is a lightweight metal (density = 2.70...Ch. 1 - Ammonia gas is used as a refrigerant in...Ch. 1 - Prob. 1.55QPCh. 1 - Which of the following statements describe...Ch. 1 - Prob. 1.57QPCh. 1 - In determining the density of a rectangular metal...Ch. 1 - Calculate the mass of each of the following: (a) a...Ch. 1 - A cylindrical glass bottle 21.5 cm in length is...Ch. 1 - The following procedure was used to determine the...Ch. 1 - Prob. 1.62QPCh. 1 - A piece of silver (Ag) metal weighing 194.3 g is...Ch. 1 - Prob. 1.64QPCh. 1 - A lead sphere of diameter 48.6 cm has a mass of...Ch. 1 - Lithium is the least dense metal known (density:...Ch. 1 - Prob. 1.67QPCh. 1 - Vanillin (used to flavor vanilla ice cream and...Ch. 1 - At what temperature does the numerical reading on...Ch. 1 - Prob. 1.70QPCh. 1 - A resting adult requires about 240 mL of pure...Ch. 1 - (a) Referring to Problem 1.71, calculate the total...Ch. 1 - Three different 25.0-g samples of solid pellets...Ch. 1 - Prob. 1.74QPCh. 1 - Prob. 1.75QPCh. 1 - The surface area and average depth of the Pacific...Ch. 1 - The unit troy ounce is often used for precious...Ch. 1 - Prob. 1.78QPCh. 1 - Prob. 1.79QPCh. 1 - The natural abundances of elements in the human...Ch. 1 - The mens world record for running a mile outdoors...Ch. 1 - Prob. 1.82QPCh. 1 - Chalcopyrite, the principal ore of copper (Cu),...Ch. 1 - Prob. 1.84QPCh. 1 - Prob. 1.85QPCh. 1 - Measurements show that 1.0 g of iron (Fe) contains...Ch. 1 - The thin outer layer of Earth, called the crust,...Ch. 1 - Prob. 1.88QPCh. 1 - One gallon of gasoline in an automobiles engine...Ch. 1 - A sheet of aluminum (Al) foil has a total area of...Ch. 1 - Prob. 1.91QPCh. 1 - Chlorine is used to disinfect swimming pools. The...Ch. 1 - An aluminum cylinder is 10.0 cm in length and has...Ch. 1 - Prob. 1.94QPCh. 1 - Prob. 1.95QPCh. 1 - Prob. 1.96QPCh. 1 - A human brain weighs about 1 kg and contains about...Ch. 1 - Prob. 1.98QPCh. 1 - A bank teller is asked to assemble one-dollar sets...Ch. 1 - A graduated cylinder is filled to the 40.00-mL...Ch. 1 - A cobalt bar (density = 8.90 g/cm3) is shown here....Ch. 1 - Prob. 1.102QPCh. 1 - Prob. 1.103QPCh. 1 - Prob. 1.104QPCh. 1 - Tums is a popular remedy for acid indigestion. A...Ch. 1 - A 250-mL glass bottle was filled with 242 mL of...Ch. 1 - What is the mass of one mole of ants? (Useful...Ch. 1 - How much time (in years) does an So-year-old...Ch. 1 - Estimate the daily amount of water (in gallons)...Ch. 1 - Public bowling alleys generally stock bowling...Ch. 1 - Fusing nanofibers with diameters of 100 to 300 nm...Ch. 1 - Prob. 1.112QPCh. 1 - Estimate the total amount of ocean water in...Ch. 1 - Estimate the volume of blood in an adult in...Ch. 1 - Prob. 1.115QPCh. 1 - Estimate the distance (in miles) covered by an NBA...Ch. 1 - In water conservation, chemists spread a thin film...
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