Bundle: Chemistry, Loose-Leaf Version, 10th + OWLv2 with Student Solutions Manual, 4 terms (24 months) Printed Access Card
10th Edition
ISBN: 9781337538015
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 1, Problem 101AE
This year, like many past years, you begin to feel very sleepy alter eating a large helping of Thanksgiving turkey. Some people attribute this sleepiness to the presence of the amino acid tryptophan in turkey. Tryptophan can be used by the body to produce serotonin, which can calm the brain’s activity and help to bring on sleep.
- a. What mass in grams of tryptophan is in a 0.25-lb serving of turkey? (Assume tryptophan accounts for 1.0% of the turkey mass.)
- b. What mass in grams of tryptophan is in 0.25 quart of milk? (Assume tryptophan accounts for 2.0% of milk by mass and that the density of milk is 1.04 kg/L.)
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each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that:
1. the rate of substitution doesn't depend on nucleophile concentration and
2. the products are a roughly 50/50 mixture of enantiomers.
Substrate A
Substrate B
Faster Rate
X
Ś
CI
(Choose one)
(Choose one)
CI
Br
Explanation
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Br
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
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A
ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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B
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
Chapter 1 Solutions
Bundle: Chemistry, Loose-Leaf Version, 10th + OWLv2 with Student Solutions Manual, 4 terms (24 months) Printed Access Card
Ch. 1 - Define and explain the differences between the...Ch. 1 - Is the scientific method suitable for solving...Ch. 1 - Which of the following statements could be tested...Ch. 1 - For each of the following pieces of glassware,...Ch. 1 - A student performed an analysis of a sample for...Ch. 1 - Compare and contrast the multiplication/division...Ch. 1 - Explain how density can be used as a conversion...Ch. 1 - On which temperature scale (F, C. or K) docs 1...Ch. 1 - Distinguish between physical changes and chemical...Ch. 1 - Why is the separation of mixtures into pure or...
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