Answered: zn²+ CH₂CH3 OCH 3

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

Interestingly, reduction of the complex shown above mostly gives the
alcohol enantiomer shown below after workup.

a. Draw the other minor diastereomeric alcohol product.

b. Briefly explain the diastereoselectivity of the reduction – why is one
enantiomer heavily favored? Draw a structure or structures to support your
answer.

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Follow-up Question

Will the bonding of the Zn2+ ion to the ketone oxygen lone pair make the ketone C=O easier or more difficult to reduce? Why

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