Your goal is to make a buffer with a pH of 4.75 from acetic acid and sodium acetate.  Assume the pKa for acetic acid is 4.74.  What is the volume of 1 M sodium acetate added to make your buffer? Report your answer to the tenths place.   To do this, we use the Henderson-Hasselbach Equation pH = pkA + log (base/acid) where pkA = 4.74 for acetic acid,  pH = target pH and [base] /[acid] = x/(1-x)  since we don't know the concentration of the base, we will call it x  the acid is just 1-x, assuming the two add  up to 100% solve for x, and then you know the mL of base and acid to add.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter15: Acid–base Equilibria
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Your goal is to make a buffer with a pH of 4.75 from acetic acid and sodium acetate.  Assume the pKa for acetic acid is 4.74.  What is the volume of 1 M sodium acetate added to make your buffer? Report your answer to the tenths place.

 

To do this, we use the Henderson-Hasselbach Equation

pH = pkA + log (base/acid)

where pkA = 4.74 for acetic acid, 

pH = target pH

and [base] /[acid] = x/(1-x)

 since we don't know the concentration of the base, we will call it x 

the acid is just 1-x, assuming the two add  up to 100%

solve for x, and then you know the mL of base and acid to add.

 

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