You place 50.0 mL of 0.500 M NaOH in a coffee-cup calorimeter at 25.00°C and carefully add 25.0 mL of 0.500 M HCl, also at 25.00°C. After stirring, the final tem-perature is 27.21°C. Calculate qₛₒₗₙ(in J) and ΔHᵣₓₙ(in kJ/mol). (Assume the total vol-ume is the sum of the individual volumes and that the final solution has the same density and specific heat capacity as water: d=1.00 g/mL and c=4.184 J/gK.)
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
You place 50.0 mL of 0.500 M NaOH in a coffee-cup calorimeter at 25.00°C and carefully add 25.0 mL of 0.500 M HCl, also at 25.00°C. After stirring, the final tem-perature is 27.21°C. Calculate qₛₒₗₙ(in J) and ΔHᵣₓₙ(in kJ/mol). (Assume the total vol-ume is the sum of the individual volumes and that the final solution has the same density and specific heat capacity as water: d=1.00 g/mL and c=4.184 J/gK.)
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