You are presented with a white solid and told that, because of careless labeling, it is not clear whether the substance is lead nitrate, calcium carbonate, or aluminum nitrate. When you transfer the solid to a beaker and add water, the solid dissolves to give a clear solution. Next, a Na2 SO4(aq) solution is added and a white precipitate forms.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question

What is the identity of the unknown white solid? 

A: lead nitrate

B: calcium carbonate

C: aluminum nitrate

You are presented with a white solid and told that,
because of careless labeling, it is not clear whether the
substance is lead nitrate, calcium carbonate, or
aluminum nitrate. When you transfer the solid to a
beaker and add water, the solid dissolves to give a
clear solution. Next, a Na2 SO4(aq) solution is added
and a white precipitate forms.
Add
Add
HO
Na SOdag)
Transcribed Image Text:You are presented with a white solid and told that, because of careless labeling, it is not clear whether the substance is lead nitrate, calcium carbonate, or aluminum nitrate. When you transfer the solid to a beaker and add water, the solid dissolves to give a clear solution. Next, a Na2 SO4(aq) solution is added and a white precipitate forms. Add Add HO Na SOdag)
Expert Solution
Step 1

According to the solubility rules-

  • All carbonates are insoluble.(Therefore compound can't be calcium carbonate, as the question says that clear solution is formed on addition of water)
  • All sulphates are soluble except Ag(Silver), Mercury (Hg) and Lead(Pb). (Therefore, the compound can't be aluminium nitrate, because its sulphate is soluble and would not form ppt)
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