x. The oxidation shown below. PCC = Ci-Cr-o: H-N But for the mechanism you can use chromic acid = HO-Cr-OH PCC Dry CH,Cl,

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
icon
Concept explainers
Question
## Oxidation Reaction Mechanism

### The Oxidation Shown Below

The oxidation process depicted in the diagram uses Pyridinium Chlorochromate (PCC) as the oxidizing agent. PCC has the chemical formula ClCrO3NH+ and is commonly used in organic chemistry for the oxidation of primary alcohols to aldehydes and secondary alcohols to ketones.

#### PCC Chemical Structure
- **PCC** = ![PCC structure](https://app.api-stability.ai/api/v3/docs/Integrations/uploads/diagram.png)
  - The structure consists of a pyridinium ion (C5H5NH+), chloride ion (Cl-), and a chromate ion (CrO3).

For the oxidation mechanism, you can use chromic acid (H2CrO4) as an alternative, which has the structure given by:

- **Chromic Acid** = ![Chromic Acid structure](https://app.api-stability.ai/api/v3/docs/Integrations/uploads/structure.png)
  - Chromic acid is an inorganic acid with the formula H2CrO4.

#### Reaction Equation

The specific reaction illustrated in the diagram is:

\[ \text{1-Pentanol (C}_5\text{H}_11\text{OH)} \overset{\text{PCC, Dry CH}_2\text{Cl}_2}{\longrightarrow} \text{Pentanal (C}_5\text{H}_{10}\text{O)} \]

- **Reactant**: 1-Pentanol (an alcohol) 
  \[ \text{CH}_3(\text{CH}_2)_3\text{CH}_2\text{OH} \]

- **Reagent**: PCC in Dry Dichloromethane (CH₂Cl₂)

- **Product**: Pentanal (an aldehyde)
  \[ \text{CH}_3(\text{CH}_2)_3\text{CHO} \]

In summary, the primary alcohol (1-pentanol) is oxidized to the aldehyde (pentanal) using PCC in the presence of dry dichloromethane. This specific oxidation prevents the further oxidation of the aldehyde to a carboxylic acid, which is a distinct advantage of using PCC. 

### Diagram Explanation

- **Chemical Structures**: The chemical structures are shown for both 1-Pent
Transcribed Image Text:## Oxidation Reaction Mechanism ### The Oxidation Shown Below The oxidation process depicted in the diagram uses Pyridinium Chlorochromate (PCC) as the oxidizing agent. PCC has the chemical formula ClCrO3NH+ and is commonly used in organic chemistry for the oxidation of primary alcohols to aldehydes and secondary alcohols to ketones. #### PCC Chemical Structure - **PCC** = ![PCC structure](https://app.api-stability.ai/api/v3/docs/Integrations/uploads/diagram.png) - The structure consists of a pyridinium ion (C5H5NH+), chloride ion (Cl-), and a chromate ion (CrO3). For the oxidation mechanism, you can use chromic acid (H2CrO4) as an alternative, which has the structure given by: - **Chromic Acid** = ![Chromic Acid structure](https://app.api-stability.ai/api/v3/docs/Integrations/uploads/structure.png) - Chromic acid is an inorganic acid with the formula H2CrO4. #### Reaction Equation The specific reaction illustrated in the diagram is: \[ \text{1-Pentanol (C}_5\text{H}_11\text{OH)} \overset{\text{PCC, Dry CH}_2\text{Cl}_2}{\longrightarrow} \text{Pentanal (C}_5\text{H}_{10}\text{O)} \] - **Reactant**: 1-Pentanol (an alcohol) \[ \text{CH}_3(\text{CH}_2)_3\text{CH}_2\text{OH} \] - **Reagent**: PCC in Dry Dichloromethane (CH₂Cl₂) - **Product**: Pentanal (an aldehyde) \[ \text{CH}_3(\text{CH}_2)_3\text{CHO} \] In summary, the primary alcohol (1-pentanol) is oxidized to the aldehyde (pentanal) using PCC in the presence of dry dichloromethane. This specific oxidation prevents the further oxidation of the aldehyde to a carboxylic acid, which is a distinct advantage of using PCC. ### Diagram Explanation - **Chemical Structures**: The chemical structures are shown for both 1-Pent
Expert Solution
steps

Step by step

Solved in 3 steps with 3 images

Blurred answer
Knowledge Booster
Lipids
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY