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- Draw the skeletal structures for the compounds in a. (Z)-1,3,5-tribromo-2-pentene b. (Z)-3-methyl-2-heptenec. (E)-1,2-dibromo-3-isopropyl-2-hexene d. vinyl bromidee. 1,2-dimethylcyclopentene f. diallylaminePlease draw the chemical structures of the following compounds a. (3Z,5S)-non-3-en-1-in-5-ole b. (1R,3S)-1-chloro-3-ethylcyclohexaneDraw structures for the following: a. (2E,4E)-1-chloro-3-methyl-2,4-hexadiene c. (3Z,5Z)-4,5-dimethyl-3,5-nonadiene b. (3Z,5E)-4-methyl-3,5-nonadiene d. (3E,5E)-2,5-dibromo-3,5-octadiene
- 1. Draw structures for a) (2E,4Z) - hepta-2,4-diene b) (S) - 2-bromobutaneWhich of the following compound is expected to burn with sooty flame but classified as aliphatic alkyl halide? O a. CH3CH2CH(CI)CH3 O b. CGH5CH2CH,CI O c. 2-Chloro-2-methylpropane O d. ChlorobenzeneDescribe (meaning what you would do and observe) simple (not including melting points, boiling points, cleaving reactions, or instrumental analyses) chemical tests(if any) that would distinguish between the compounds named below. [hint doing a table may be helpful] A. 1,3-pentadiene and 1-pentyne B. Ally bromide and 2,3- dimethyl-1,3-butadiene
- 18. Which carbanion is the most stable A. methyl carbanion (CH3-) B. ethyl carbanion (CH3CH2-) C. isopropyl carbanion ((CH3)2CH-) D.Chloromethyl carbanion (CICH2-) 19. Which structural effect best explains the observed trend below: Compound C-CI bond length (A) 1.78 1.77 1.76 H3C-CI CIH₂C-CI Cl₂HC-CI FH₂C-CI 1.76 A. resonance B. C-H hyperconjugation C. Inductive effect D. steric effect 20. Assuming that each methyl/hydrogen 1,3-diaxial interaction destabilizes the methyl substituted cyclohexane by 0.9 kcal/mole; then what is the energy difference between 2 chair conformations of cis-1,3-dimethylcyclohexane. A. 0.9 kcal/mol B. 1.8 kcal/mol C. 2.7 kcal/mol D. 3.6 kcal/mol4. Outline the following synthesis (a). Butane to 2-butanol (b). 1,2-dibromopropane from 2-propanol (c). 1-butanol to 2-butanol (d). Propane to Propene4. Resonance. For each of the following structural formulas, provide the indicated number of resonance structures. Use curved arrows to show the electron movement between each structure, use double headed arrow to separate the structures, and enclose all of them in a single set of brackets []. a) N204 (O₂N-NO2) (4 structures)
- Describe (meaning what you would do and observe) simple (not including melting points, boiling points, cleaving reactions, or instrumental analyses) chemical tests (if any) that would distinguish between the compounds named below. [ Hint: using a table may be helpful ] A. 1,3-pentadiene & 1-pentyne B. allyl bromide & 2,3-dimethyl-1,3-butadieneunambiguous b. 2. Name the following in an manner. С. a. : Br: H3C (CH2)2CH3 CH,C(CH3)3 C.5. Draw structures for the following alkenes.a. E-2,4-dimethyl-1,4-hexadieneb. (2E, 5S)-5-bromo-3-butyl-2-heptenec. (3E,5Z)-2,6-dimethyl-1,3,5,7-octatetraened. Z-3,3-dimethyl-4-propyl-1,5-octadiene
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