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Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter21: Transition Metals And Coordination Chemistry

Section: Chapter Questions

Problem 1ALQ

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Question 66 of 80
Write the chemical formula for iridium(III) hydrogen sulfite
2+
3+
4+
14-
1
2
3
4
7
O3
O5
O6
(1)
(g) (aq)
H
HSO,
HSO,
SO,
Ir
4
SO,
Reset
• x H,O
Delete
2
+
2.
2.

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Complete and balance the following equations: (a) CaO(s) + H2O(1) (b) Al>O3(s) + H*(aq) (c) NazO2(s) + H20(I) (d) N2O3(8) + H20(1) (e) KO2(s) + H,0(1) (f) NO(8) + O(8)
Q4(iv)
(ii) Br NH HNO₂ H2SO4
1) The net ionic equation for formation of an aqueous solution of Nil2 accompanied by evolution of Coz gas via mixing solid NICO3 and aqueous hydriodic acid is A) 2NICO, (s) + HI (aq) → 2H,O (1) + CO, (g) + 2Ni (aq) B) NİCO, (s) + I- (aq) → 2H,O (1) + CO, (g) + Ni* (aq) + HI (aq) C) NICO, (s) + 2H* (aq) → H,O (1) + CO, (g) + Ni* (aq) D) NICO, (s) + 2HI (aq) → 2H,O (1) + CO, (g) + Nil (aq) E) NICO, (s) + 2HI (aq) → H,O (1) + CO, (g) + Ni* (aq) + 21 (aq) Answer: C 2) The net ionic equation for formation of an aqueous solution of Al(NO,), via mixing solid Al(OH); and aqueous nitric acid is A) Al(OH), (s) + 3HNO, (aq) 3H,0 (1) + Al(NO,), (aq) B) Al(OH), (s) + 3NO; (aq) → 3OH- (aq) + Al(NO,); (aq) C) Al(OH), (s) + 3NO,"(aq) → 30H- (aq) + Al(NO,), (s) D) Al(OH), (s) + 3H' (aq) → 3H,0 (1) + Al³* (aq) E) Al(OH), (s) + 3HNO, (aq) → 3H,0 (1) + Al* (aq) + NO, (aq) Answer: D 3) The balanced reaction between aqueous nitric acid and aqueous strontium hydroxide is Sr(NO3)2 (aq) + H2 (g) A) HNO3 (aq)…
Write a balanced equation to show the reaction of aqueous aluminum acetate with aqueous ammonium phosphate to form solid aluminum phosphate and aqueous ammonium acetate. O Al(CH,O), (aq) + (NH4) PO, (ag) → AIPO, (s) + 2 NH,C2H3O3 (aq) O Al(CH,0), (aq) + (NH),PO, (aq) → AIPO, (s) + 2 NH,CH,O, (aq) • Al(CH,O), (aa) + (NH.)PO, (aq)→ AIPO, s) + 3 NH,CH,O, (aq) O Al(CO), (aq) + (NH)PO, (aq) → AIPO, (s) + 3 NH,CO, (aq) O Al(CO, (aq) + (NH,PO, (an) → AIPO, (s) + 2 NH,CO, (aq)
Write the expression Kc for the following reactions. (a) Fe2+(aq) + Ce4+(aq) ⇋ Fe3+(aq) + Ce3+(aq) (b) CaCO3(s) ⇋ CaO(s) + CO3(g)
In aqueous solution, hydrogen sulfide reduces (a) Fe3 + toFe2+ , (b) Br2 to Br - , (c) MnO4- to Mn2 + , (d) HNO3 to NO2.In all cases, under appropriate conditions, the product iselemental sulfur. Write a balanced net ionic equation foreach reaction.
Write a balanced chemical equation for the reaction that occurs when (a) Mg(s) reacts with Cl21g2; (b) barium carbonate decomposes into barium oxide and carbon dioxide gas when heated; (c) the hydrocarbon styrene, C8H81l2, is combusted in air; (d) dimethylether, CH3OCH31g2, is combustedin air.
Magnesium reacts with oxygen to form magnesium oxide according to the following reaction: 2 Mg + O2 2M9O (a) What is the oxidation state of magnesium in Mg? (b) What is the oxidation state of magnesium in MgO? (c) Which species is oxidized? (d) Which species is reduced? (e) Name the oxidizing agent.
Solid boron can be extracted from solid boron oxide by reac- tion with magnesium metal at a high temperature. A second prod- uct is solid magnesium oxide. (a) Write a balanced equation for the reaction. (b) What mass of boron can be produced when 125 kg of boron oxide is heated with 125 kg of magnesium?
Which of the following statements are true?(a) Si can form an ion with six fluorine atoms, SiF62-,whereas carbon cannot.(b) Si can form three stable compounds containing two Siatoms each, Si2H2, Si2H4, and Si2H6.(c) In HNO3 and H3PO4 the central atoms, N and P, havedifferent oxidation states.(d) S is more electronegative than Se.
The oxidation state of chromium in CrAsO4 is: (a) 0 (b) +1 (c) +2 (d) +3 (e) -3

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