Write down all the symmetry elements associated with the following molecules and then use the flow chart to determine the point group of the following molecules. a.) b.) с.) d.) trans-ICrBr,(H,O)l ignore the H's) gauche-CH2CICH2CI В-Н. CH(spiropentane) н. Н Н Н. CI Br o в H.O- OH oosM Н H н Br (triangles Н Н to each other) e.) f.) g.) CHS (thiophene) trans-CFCIBrCFCIBr HCOOH (formic acid) H Вr Cl H-C o-H Br (planar) (planar) k) sulfur hexafluoride ) ethane-Br2Cl2 h) Benzotrifuroxan i dinitrogen tetroxide ) hydrazine P) cyclooctatetraene m) ethylene-BrCl n) 1,I-dichlorethylene o) cyclohexane-Br2Ch Molecule Y Linear Two or more C n2? i? coh N i?N Td C? On Select C, with highest n; then, are the nC perpendicular to C? N N Dr N N Dr na? nd n N c. i? Ct IN Cnv na N S2 Y n San C.

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter13: Introduction To Symmetry In Quantum Mechanics
Section: Chapter Questions
Problem 13.26E: Determine the point groups of the following molecules. a Hydrogen peroxide, H2O2 it is not planar. b...
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Write down all the symmetry elements associated with the following molecules and then use the flow
chart to determine the point group of the following molecules.
a.)
b.)
с.)
d.)
trans-ICrBr,(H,O)l ignore the H's) gauche-CH2CICH2CI
В-Н.
CH(spiropentane)
н.
Н
Н
Н.
CI
Br o
в
H.O- OH
oosM
Н
H
н
Br
(triangles
Н
Н
to each other)
e.)
f.)
g.)
CHS (thiophene)
trans-CFCIBrCFCIBr
HCOOH (formic acid)
H
Вr
Cl
H-C
o-H
Br
(planar)
(planar)
k) sulfur hexafluoride
) ethane-Br2Cl2
h) Benzotrifuroxan
i dinitrogen tetroxide ) hydrazine
P) cyclooctatetraene
m) ethylene-BrCl
n) 1,I-dichlorethylene
o) cyclohexane-Br2Ch
Transcribed Image Text:Write down all the symmetry elements associated with the following molecules and then use the flow chart to determine the point group of the following molecules. a.) b.) с.) d.) trans-ICrBr,(H,O)l ignore the H's) gauche-CH2CICH2CI В-Н. CH(spiropentane) н. Н Н Н. CI Br o в H.O- OH oosM Н H н Br (triangles Н Н to each other) e.) f.) g.) CHS (thiophene) trans-CFCIBrCFCIBr HCOOH (formic acid) H Вr Cl H-C o-H Br (planar) (planar) k) sulfur hexafluoride ) ethane-Br2Cl2 h) Benzotrifuroxan i dinitrogen tetroxide ) hydrazine P) cyclooctatetraene m) ethylene-BrCl n) 1,I-dichlorethylene o) cyclohexane-Br2Ch
Molecule
Y
Linear
Two
or more
C n2?
i?
coh
N
i?N
Td
C?
On
Select C, with
highest n; then, are the nC
perpendicular to C?
N
N
Dr
N
N
Dr
na?
nd
n
N
c.
i?
Ct
IN
Cnv na
N
S2
Y
n
San
C.
Transcribed Image Text:Molecule Y Linear Two or more C n2? i? coh N i?N Td C? On Select C, with highest n; then, are the nC perpendicular to C? N N Dr N N Dr na? nd n N c. i? Ct IN Cnv na N S2 Y n San C.
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