Write a valid Lewis structure of the compound with the elemental composition C3H7I that gives the following ¹H-NMR spectrum. EXPLAIN your reasoning. .A. C3H7I 7 4.5 4.3 5 S 2.0 1.8 4 μ (ppm) 3 TMS

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**NMR Spectrum Analysis for Compound C₃H₇I**

This document presents a proton NMR (¹H NMR) spectrum for a compound with the molecular formula C₃H₇I. The goal is to write a valid Lewis structure for this compound and explain the reasoning behind it based on the NMR data provided.

### NMR Spectrum Description:

- **Chemical Shifts (δ in ppm):**
  - **4.5 to 4.3 ppm:** A multiplet appears in this region, likely indicating protons near an electronegative atom such as iodine.
  - **2.0 ppm:** A singlet appears, suggesting protons in an environment with no neighboring protons (e.g., methyl group).
  - **1.8 ppm:** Another singlet, indicating similar environmental conditions as the 2.0 ppm signal but involving different protons.

- **Integration:**
  - The integration curve shows the relative area under each peak, representing the number of hydrogens contributing to each signal.

- **TMS (Tetramethylsilane) Reference:**
  - The peak at 0 ppm is not visible here but would typically serve as the reference for chemical shift values.

### Explanation:

Based on typical chemical shifts and splitting patterns, this spectrum provides insights into the structure:
- **4.5 to 4.3 ppm Region:** The presence of a multiplet indicates coupling with neighboring protons. This suggests an environment where protons are near a halogen (iodine), possibly attached to a carbon in a primary or secondary position.
  
- **2.0 and 1.8 ppm Regions:** The singlets here suggest isolated methyl groups or protons attached to carbons with no nearby protons for splitting.

### Conclusion:

The spectral data suggest the compound could be either 1-iodopropane (with coupling seen if iodine is attached at one end) or 2-iodopropane (more likely if the protons are more isolated). Consider the neighboring carbon environment and use additional spectroscopic or chemical information to finalize the structure decision.

**Note to Educators:**
This exercise helps students apply NMR analysis to determine molecular structure, assessing both chemical environment and proton coupling.
Transcribed Image Text:**NMR Spectrum Analysis for Compound C₃H₇I** This document presents a proton NMR (¹H NMR) spectrum for a compound with the molecular formula C₃H₇I. The goal is to write a valid Lewis structure for this compound and explain the reasoning behind it based on the NMR data provided. ### NMR Spectrum Description: - **Chemical Shifts (δ in ppm):** - **4.5 to 4.3 ppm:** A multiplet appears in this region, likely indicating protons near an electronegative atom such as iodine. - **2.0 ppm:** A singlet appears, suggesting protons in an environment with no neighboring protons (e.g., methyl group). - **1.8 ppm:** Another singlet, indicating similar environmental conditions as the 2.0 ppm signal but involving different protons. - **Integration:** - The integration curve shows the relative area under each peak, representing the number of hydrogens contributing to each signal. - **TMS (Tetramethylsilane) Reference:** - The peak at 0 ppm is not visible here but would typically serve as the reference for chemical shift values. ### Explanation: Based on typical chemical shifts and splitting patterns, this spectrum provides insights into the structure: - **4.5 to 4.3 ppm Region:** The presence of a multiplet indicates coupling with neighboring protons. This suggests an environment where protons are near a halogen (iodine), possibly attached to a carbon in a primary or secondary position. - **2.0 and 1.8 ppm Regions:** The singlets here suggest isolated methyl groups or protons attached to carbons with no nearby protons for splitting. ### Conclusion: The spectral data suggest the compound could be either 1-iodopropane (with coupling seen if iodine is attached at one end) or 2-iodopropane (more likely if the protons are more isolated). Consider the neighboring carbon environment and use additional spectroscopic or chemical information to finalize the structure decision. **Note to Educators:** This exercise helps students apply NMR analysis to determine molecular structure, assessing both chemical environment and proton coupling.
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