Would it be easy to determine the molecular weight of starch by measuring the freezing point depression?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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**Question:** Would it be easy to determine the molecular weight of starch by measuring the freezing point depression?

**Explanation:** 

This question explores the feasibility of using the colligative property of freezing point depression to determine the molecular weight of starch. Freezing point depression occurs when the freezing point of a liquid (solvent) is lowered by adding another compound to it (solute). The magnitude of this depression can be used to calculate the molecular weight of the solute. However, due to the large and complex structure of starch molecules, practical limitations may arise, making this method less suitable for starch compared to smaller molecules.
Transcribed Image Text:**Question:** Would it be easy to determine the molecular weight of starch by measuring the freezing point depression? **Explanation:** This question explores the feasibility of using the colligative property of freezing point depression to determine the molecular weight of starch. Freezing point depression occurs when the freezing point of a liquid (solvent) is lowered by adding another compound to it (solute). The magnitude of this depression can be used to calculate the molecular weight of the solute. However, due to the large and complex structure of starch molecules, practical limitations may arise, making this method less suitable for starch compared to smaller molecules.
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Introduction

A polymeric carbohydrate known as starch or amylum is made up of many glucose units connected by glycosidic linkages. Most green plants synthesize this polysaccharide as a means of storing energy. It is the most prevalent carbohydrate in human diets worldwide and is present in significant levels in common foods like wheat, potatoes, maize (corn), rice, and cassava (manioc). A white, flavorless, and odorless powder known as pure starch is insoluble in both cold water and alcohol. It is made up of two different kinds of molecules: branched amylopectin and linear and helical amylose. Depending on the plant, starch often has a weight ratio of 75 to 80% amylopectin and 20 to 25% amylose. Glycogen, an animal's energy reserve, is a more branched form of amylopectin.

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