Which substance exhibits stronger attractive intermolecular forces?  SiF4  SiCl4 Which substance has the higher normal boiling point?  SiF4  SiCl4 Which substance has the lower vapor pressure at -100°C?  SiF4  SiCl4 Which substance will evaporate more slowly at -60°C?  SiCl4  SiF4

Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter8: Molecules And Materials
Section: Chapter Questions
Problem 8.51PAE: 8.51 Suppose that three unknown pure substances are liquids at room temperature. You determine that...
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At 36°C the vapor pressure of silicon tetrachloride is 0.5 atm.

At -97°C the vapor pressure of silicon tetrafluoride is 0.5 atm.

Predict the answers to all of the following questions by selecting the correct molecular substance in each case.

 

Which substance exhibits stronger attractive intermolecular forces?
 SiF4
 SiCl4
Which substance has the higher normal boiling point?
 SiF4
 SiCl4
Which substance has the lower vapor pressure at -100°C?
 SiF4
 SiCl4
Which substance will evaporate more slowly at -60°C?
 SiCl4
 SiF4
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