Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question

Transcribed Image Text:**Question:** Which structure do you expect to have the longest λ_max?
**Structures:**
1. **Structure 1:** A cyclopentene ring with a conjugated diene system, where one alkene is exocyclic.
2. **Structure 2:** A cyclopentane ring with a single alkene group attached.
3. **Structure 3:** A cyclopentene ring featuring a conjugated dienic system.
4. **Structure 4:** A cyclopentadiene ring with a fully conjugated dienic system.
**Analysis:**
The structures depict different levels of conjugation. λ_max refers to the wavelength at which maximum absorbance occurs in a compound's UV-Vis spectrum, usually correlating with the degree of conjugation. More conjugated systems typically have higher λ_max values due to lower energy transitions.
- Structure 1 has a partially conjugated system with one exocyclic double bond.
- Structure 2 has no conjugation.
- Structure 3 has internal conjugation within the ring.
- Structure 4 is fully conjugated.
**Conclusion:** Structure 4 is expected to have the longest λ_max due to its fully conjugated diene system, which allows for extended electron delocalization and lower energy transitions.
Expert Solution

Step 1
We are given 4 different molecules to select the one with the longest
Longer the conjugated system present in a molecule, larger is the wavelength it will absorb.
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