Which solvent listed below will result in the highest rate of this reaction?YонO 1.0.1 % Aqueous sodium hydroxide solutionO2 EthanolO 3. CyclohexaneO 4. Diethylether

Given reactant is 3° butyl chloride hence it undergo through SN1 mechanism. In SN1 mechanism carbocation intermediate is formed in the first step. It is polar intermediate and it's stable is more in polar-protic solvents (like Ethanol) Alkylhalides upon dehydraohalogenation gives alkenes. 3° R-X undergo elimination reactions through E1 mechanism. Again in E1 mechanism also intermediate is carbocation. Polar protic solvents favoured.Overall 3° alkylhalides undergo substitution as well as elimination. In both the cases intermediate is carbocation, hence polar-protic solvent (Ethanol) favoured. Note: 3° butanol is the substitution product And Isobutene is the elimination product

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Which solvent listed below will result in the highest rate of this reaction?

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter14: Elimination

Section: Chapter Questions

Problem 18CTQ

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Which solvent listed below will result in the highest rate of this reaction?
Y
он
O 1.0.1 % Aqueous sodium hydroxide solution
O2 Ethanol
O 3. Cyclohexane
O 4. Diethylether

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