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Which reagents follow Markovnikov's Rule? Reagents sheet provided on exam. Some changes to the reagent sheet may occur. NaOMe КОBu or KOC(CH)з 1. TsCl, pyridine 2. nucleophile HBr H;SO: (concentrated, sometimes shown with heat or A) NaNH (or NaH) NANH2 (excess) 1. NANH2 (3 eq) H2, Pt (or Pd) H2, Lindlar Na, NH3 HgSO4, H,SO4, H2O 1. R,BH (like (sia),BH or 9-BBN) 2. H,O2, NaOH HBr (1 eq) 2. Н.О H2, Pt (or Pd) X2 like Br2 Br2, H,O H2SO4, H2O (or "dilute sulfuric acid," or H;O*, or H*, H2O) HBr 1. Hg(OAc), H,о 1. BH, | 1. O. | 1. OsO4 mcpba (or RCO,H) HBr (excess, or 2 eq) Br2 (1 eq) Br, (excess, or 2 eq) Br2, hv 2. NaBH4 2. H,О, NaOH 2. DMS ((CH3)2S) (or Zn/H2O) 2. NaHSO3, H2O HBr, ROOR

Which reagents follow Markovnikov's Rule? Reagents sheet provided on exam. Some changes to the reagent sheet may occur. NaOMe КОBu or KOC(CH)з 1. TsCl, pyridine 2. nucleophile HBr H;SO: (concentrated, sometimes shown with heat or A) NaNH (or NaH) NANH2 (excess) 1. NANH2 (3 eq) H2, Pt (or Pd) H2, Lindlar Na, NH3 HgSO4, H,SO4, H2O 1. R,BH (like (sia),BH or 9-BBN) 2. H,O2, NaOH HBr (1 eq) 2. Н.О H2, Pt (or Pd) X2 like Br2 Br2, H,O H2SO4, H2O (or "dilute sulfuric acid," or H;O*, or H*, H2O) HBr 1. Hg(OAc), H,о 1. BH, | 1. O. | 1. OsO4 mcpba (or RCO,H) HBr (excess, or 2 eq) Br2 (1 eq) Br, (excess, or 2 eq) Br2, hv 2. NaBH4 2. H,О, NaOH 2. DMS ((CH3)2S) (or Zn/H2O) 2. NaHSO3, H2O HBr, ROOR

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Which reagents follow Markovnikov's Rule? Reagents sheet provided on exam. Some changes to the reagent sheet may occur. NaOMe КОBu or KOC(CH)з 1. TsCl, pyridine 2. nucleophile HBr H;SO: (concentrated, sometimes shown with heat or A) NaNH (or NaH) NANH2 (excess) 1. NANH2 (3 eq) H2, Pt (or Pd) H2, Lindlar Na, NH3 HgSO4, H,SO4, H2O 1. R,BH (like (sia),BH or 9-BBN) 2. H,O2, NaOH HBr (1 eq) 2. Н.О H2, Pt (or Pd) X2 like Br2 Br2, H,O H2SO4, H2O (or "dilute sulfuric acid," or H;O*, or H*, H2O) HBr 1. Hg(OAc), H,о 1. BH, | 1. O. | 1. OsO4 mcpba (or RCO,H) HBr (excess, or 2 eq) Br2 (1 eq) Br, (excess, or 2 eq) Br2, hv 2. NaBH4 2. H,О, NaOH 2. DMS ((CH3)2S) (or Zn/H2O) 2. NaHSO3, H2O HBr, ROOR
Transcribed Image Text:Which reagents follow Markovnikov's Rule? Reagents sheet provided on exam. Some changes to the reagent sheet may occur. NaOMe КОBu or KOC(CH)з 1. TsCl, pyridine 2. nucleophile HBr H;SO: (concentrated, sometimes shown with heat or A) NaNH (or NaH) NANH2 (excess) 1. NANH2 (3 eq) H2, Pt (or Pd) H2, Lindlar Na, NH3 HgSO4, H,SO4, H2O 1. R,BH (like (sia),BH or 9-BBN) 2. H,O2, NaOH HBr (1 eq) 2. Н.О H2, Pt (or Pd) X2 like Br2 Br2, H,O H2SO4, H2O (or "dilute sulfuric acid," or H;O*, or H*, H2O) HBr 1. Hg(OAc), H,о 1. BH, | 1. O. | 1. OsO4 mcpba (or RCO,H) HBr (excess, or 2 eq) Br2 (1 eq) Br, (excess, or 2 eq) Br2, hv 2. NaBH4 2. H,О, NaOH 2. DMS ((CH3)2S) (or Zn/H2O) 2. NaHSO3, H2O HBr, ROOR
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