Which of these would be the best electrophile for an Sy1 reaction? A) CH;Br B) (CH3);CBr C) (CH3);CO- D) CH;O-

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**Which of these would be the best electrophile for an S<sub>N</sub>1 reaction?**

A) CH<sub>3</sub>Br  
B) (CH<sub>3</sub>)<sub>3</sub>CBr  
C) (CH<sub>3</sub>)<sub>3</sub>CO<sup>−</sup>  
D) CH<sub>3</sub>O<sup>−</sup>  

*Explanation:*  
In an S<sub>N</sub>1 reaction, the best electrophile is one that can form a stable carbocation. Typically, tertiary carbocations are more stable than secondary or primary ones due to hyperconjugation and inductive effects. 

- **Option A (CH<sub>3</sub>Br)**: Methyl bromide forms an unstable methyl cation.
- **Option B ((CH<sub>3</sub>)<sub>3</sub>CBr)**: Tertiary butyl bromide forms a stable tertiary carbocation.
- **Option C ((CH<sub>3</sub>)<sub>3</sub>CO<sup>−</sup>)**: Presents as a negative ion, not suitable as an electrophile.
- **Option D (CH<sub>3</sub>O<sup>−</sup>)**: Also a negative ion, unsuitable as an electrophile.

Thus, the best choice for an S<sub>N</sub>1 reaction is **Option B** - (CH<sub>3</sub>)<sub>3</sub>CBr.
Transcribed Image Text:**Which of these would be the best electrophile for an S<sub>N</sub>1 reaction?** A) CH<sub>3</sub>Br B) (CH<sub>3</sub>)<sub>3</sub>CBr C) (CH<sub>3</sub>)<sub>3</sub>CO<sup>−</sup> D) CH<sub>3</sub>O<sup>−</sup> *Explanation:* In an S<sub>N</sub>1 reaction, the best electrophile is one that can form a stable carbocation. Typically, tertiary carbocations are more stable than secondary or primary ones due to hyperconjugation and inductive effects. - **Option A (CH<sub>3</sub>Br)**: Methyl bromide forms an unstable methyl cation. - **Option B ((CH<sub>3</sub>)<sub>3</sub>CBr)**: Tertiary butyl bromide forms a stable tertiary carbocation. - **Option C ((CH<sub>3</sub>)<sub>3</sub>CO<sup>−</sup>)**: Presents as a negative ion, not suitable as an electrophile. - **Option D (CH<sub>3</sub>O<sup>−</sup>)**: Also a negative ion, unsuitable as an electrophile. Thus, the best choice for an S<sub>N</sub>1 reaction is **Option B** - (CH<sub>3</sub>)<sub>3</sub>CBr.
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