Which of the following would have the lowest vapor pressure? I. CH4 II. CH3OCH3 III. CH3CH₂OH IV. CH3CH2CH3 O a. I O b. IV O c. ||| O d. V e. Il V. CH3CH3

Chemistry
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Question:**

Which of the following would have the lowest vapor pressure?

I. CH₄  
II. CH₃OCH₃  
III. CH₃CH₂OH  
IV. CH₃CH₂CH₃  
V. CH₃CH₃  

**Options:**

a. I  
b. IV  
c. III  
d. V  
e. II  

**Explanation:**

This question is about determining which of the given compounds has the lowest vapor pressure. The vapor pressure of a substance is influenced by the strength of intermolecular forces within the substance. Substances with stronger intermolecular forces typically have lower vapor pressures because it is more difficult for molecules to escape into the gas phase.

1. **CH₄ (Methane)** - Non-polar, weak dispersion forces.
2. **CH₃OCH₃ (Dimethyl ether)** - Polar, dipole-dipole interactions.
3. **CH₃CH₂OH (Ethanol)** - Polar, hydrogen bonding (strongest intermolecular force here).
4. **CH₃CH₂CH₃ (Propane)** - Non-polar, weak dispersion forces.
5. **CH₃CH₃ (Ethane)** - Non-polar, weak dispersion forces.

Given these compounds, ethanol (CH₃CH₂OH) with hydrogen bonding would have the strongest intermolecular forces, leading to the lowest vapor pressure. The correct answer is:

c. III
Transcribed Image Text:**Question:** Which of the following would have the lowest vapor pressure? I. CH₄ II. CH₃OCH₃ III. CH₃CH₂OH IV. CH₃CH₂CH₃ V. CH₃CH₃ **Options:** a. I b. IV c. III d. V e. II **Explanation:** This question is about determining which of the given compounds has the lowest vapor pressure. The vapor pressure of a substance is influenced by the strength of intermolecular forces within the substance. Substances with stronger intermolecular forces typically have lower vapor pressures because it is more difficult for molecules to escape into the gas phase. 1. **CH₄ (Methane)** - Non-polar, weak dispersion forces. 2. **CH₃OCH₃ (Dimethyl ether)** - Polar, dipole-dipole interactions. 3. **CH₃CH₂OH (Ethanol)** - Polar, hydrogen bonding (strongest intermolecular force here). 4. **CH₃CH₂CH₃ (Propane)** - Non-polar, weak dispersion forces. 5. **CH₃CH₃ (Ethane)** - Non-polar, weak dispersion forces. Given these compounds, ethanol (CH₃CH₂OH) with hydrogen bonding would have the strongest intermolecular forces, leading to the lowest vapor pressure. The correct answer is: c. III
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