Which of the following would have the highest boiling point? [Show work] A. A 1.5 M solution of AlCl3 B. A 2.0 M solution of NaCl C. A 2.5 M solution of Na2S D. A 3.0 M solution HCl

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Which of the following would have the highest boiling point? [Show work] A. A 1.5 M solution of AlCl3 B. A 2.0 M solution of NaCl C. A 2.5 M solution of Na2S D. A 3.0 M solution HCl
Expert Solution
Step 1

This problem can be solved by using a Fajan's rule of polarization in inorganic chemistry.

According to this rule,

" Covalent character is inversely proportional to boiling point" 

And for Cation

Covalentnt character proportional to charge on cation and inversely proportional to size of cation. 

And For Anion 

 Covalent character proportional to charge and size of anion

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