Which of the following sets of compounds di we expect to have the same boiling point? ČI or

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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**Question:**

Which of the following sets of compounds do we expect to have the same boiling point?

1. A pair of cyclic compounds, each with a six-membered ring attached to a linear chain. The first structure has a double bond in the chain, while the second does not.

2. A pair of cyclic compounds with a six-membered ring attached to a carbon chain with a chlorine atom. Both structures are chiral, indicated by wedge and dash bonds connected to the carbon bonded to chlorine.

3. A pair of cyclic compounds, each with a six-membered ring attached to a simple linear chain with no double bonds or additional elements.

Each set is represented by a checkbox to denote selection.
Transcribed Image Text:**Question:** Which of the following sets of compounds do we expect to have the same boiling point? 1. A pair of cyclic compounds, each with a six-membered ring attached to a linear chain. The first structure has a double bond in the chain, while the second does not. 2. A pair of cyclic compounds with a six-membered ring attached to a carbon chain with a chlorine atom. Both structures are chiral, indicated by wedge and dash bonds connected to the carbon bonded to chlorine. 3. A pair of cyclic compounds, each with a six-membered ring attached to a simple linear chain with no double bonds or additional elements. Each set is represented by a checkbox to denote selection.
Expert Solution
Step 1

Boiling point means required energy to break the bond 

Boiling point increase as the attraction increase in molecules

In 1set one is trans and other is Cis

So cis molecule have high boiling point

In 2 set of molecule both are same molecule just mirror image to eqch other 

So have same boiling point 

 

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