Which of the following is a substitution reaction? "人一X II. I. OH IV. メー人 III. Br SH O1)1 2) 11 O 3) II 4) IV

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Chapter1: Chemical Foundations
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**Question:**

Which of the following is a substitution reaction?

I. ![Reaction 1](images/reaction1.png)
- Starting compound: Alkyl group with an -OH group
- Products: Alkyl group with a =O^(-) group

II. ![Reaction 2](images/reaction2.png)
- Starting compound: Alkyl group
- Products: Alkyl group with a -Cl group

III. ![Reaction 3](images/reaction3.png)
- Starting compound: Alkyl group with a -Br group
- Products: Alkyl group with a -SH group

IV. ![Reaction 4](images/reaction4.png)
- Starting compound: Alkyl group with a -Cl group
- Products: Alkene

**Options:**

- 1) I
- 2) II
- 3) III
- 4) IV

**Explanation:**

- **Substitution Reaction:** A type of chemical reaction where an atom, ion, or group of atoms in a molecule is replaced by another atom, ion, or group of atoms.

**Diagram Descriptions:**

- **I:** Shows the conversion of an alcohol (OH group) to an alkoxide ion (O^(-)), a form of elimination.
  
- **II:** Depicts an alkyl group gaining a chlorine atom (addition rather than substitution).
  
- **III:** Illustrates the replacement of a bromine atom (Br) with a thiol group (SH), a classic substitution reaction.

- **IV:** Shows the transformation of an alkyl chloride to an alkene, a form of elimination reaction.

**Correct Answer:** 3) III
Transcribed Image Text:**Question:** Which of the following is a substitution reaction? I. ![Reaction 1](images/reaction1.png) - Starting compound: Alkyl group with an -OH group - Products: Alkyl group with a =O^(-) group II. ![Reaction 2](images/reaction2.png) - Starting compound: Alkyl group - Products: Alkyl group with a -Cl group III. ![Reaction 3](images/reaction3.png) - Starting compound: Alkyl group with a -Br group - Products: Alkyl group with a -SH group IV. ![Reaction 4](images/reaction4.png) - Starting compound: Alkyl group with a -Cl group - Products: Alkene **Options:** - 1) I - 2) II - 3) III - 4) IV **Explanation:** - **Substitution Reaction:** A type of chemical reaction where an atom, ion, or group of atoms in a molecule is replaced by another atom, ion, or group of atoms. **Diagram Descriptions:** - **I:** Shows the conversion of an alcohol (OH group) to an alkoxide ion (O^(-)), a form of elimination. - **II:** Depicts an alkyl group gaining a chlorine atom (addition rather than substitution). - **III:** Illustrates the replacement of a bromine atom (Br) with a thiol group (SH), a classic substitution reaction. - **IV:** Shows the transformation of an alkyl chloride to an alkene, a form of elimination reaction. **Correct Answer:** 3) III
### Understanding Second Order Nucleophilic Substitution Reactions

The provided chemical reaction is an example of a nucleophilic substitution reaction taking place under the following conditions:

- **Reactants:** 
  - An alcohol (represented by the structure with an -OH group)
  - Sodium bromide (NaBr)

- **Catalyst:** Sulfuric acid (H₂SO₄)

- **Products:** 
  - An alkyl bromide
  - Water (H₂O)

#### Question:
What does it mean to say that this nucleophilic substitution reaction is second order?

#### Options:
1. **Reaction rate is dependent on the concentration of the nucleophile only.**

2. **Reaction rate is dependent on the concentrations of both nucleophile and substrate.**

3. **Reaction rate is dependent on the concentration of the substrate only.**

4. **Reaction rate is independent of the concentrations of both nucleophile and substrate.**

#### Explanation:
In a second-order reaction, the rate is proportional to the product of the concentrations of two reactants. Thus, the correct answer is:

- **Option 2:** Reaction rate is dependent on the concentrations of both nucleophile and substrate.

This selection suggests that both the nucleophile and the substrate play a crucial role in determining the speed of the reaction, characteristic of a bimolecular nucleophilic substitution (S_N2) process.
Transcribed Image Text:### Understanding Second Order Nucleophilic Substitution Reactions The provided chemical reaction is an example of a nucleophilic substitution reaction taking place under the following conditions: - **Reactants:** - An alcohol (represented by the structure with an -OH group) - Sodium bromide (NaBr) - **Catalyst:** Sulfuric acid (H₂SO₄) - **Products:** - An alkyl bromide - Water (H₂O) #### Question: What does it mean to say that this nucleophilic substitution reaction is second order? #### Options: 1. **Reaction rate is dependent on the concentration of the nucleophile only.** 2. **Reaction rate is dependent on the concentrations of both nucleophile and substrate.** 3. **Reaction rate is dependent on the concentration of the substrate only.** 4. **Reaction rate is independent of the concentrations of both nucleophile and substrate.** #### Explanation: In a second-order reaction, the rate is proportional to the product of the concentrations of two reactants. Thus, the correct answer is: - **Option 2:** Reaction rate is dependent on the concentrations of both nucleophile and substrate. This selection suggests that both the nucleophile and the substrate play a crucial role in determining the speed of the reaction, characteristic of a bimolecular nucleophilic substitution (S_N2) process.
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