Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Which of the following forces does methanol (CH3-OH) exhibit? Select all that apply.
hydrogen bonding
London forces
dipole-dipole attractions
Expert Solution
Introduction
Hydrogen bonding -
- Electrostatic force of attraction.
- It exists between hydrogen atom that is bonded to more electronegative atom and another electronegative atom.
- Strong IMF.
Types-
- Intramolecular H-bonding (within molecule)
- Intermolecular H-bonding (between molecules)
London forces -
- Also known as London dispersion forces or Van der Waals forces.
- These are the temporary attractive forces that occur due to motion of electrons.
- Exists between polar, non-polar, ions , noble gases.
- Bond strength is high.
- Molecule with instantaneous dipole moment show dipole-dipole attractions.
Dipole-dipole attractions
- Electrostatic interaction and attractive forces between polar molecule.
- Partial positive end of polar molecule is attracted tp partial negative end of another polar molecule.
- Occur due to unequal sharing of electrons
- Bond strength is weak.
- Molecule with permanent dipole moment show dipole-dipole attractions.
Step 2
- London forces exists between all types of molecules.
- It has hydrogen boding between H attached to electronegative O atom and oxygen of another methanol molecule.
- This is intermolecular hydrogen bonding.
- Methanol is a polar molecule.
- It is permanent dipole moment.
- Dipole -dipole attraction is between partial positive H atom and partial negative oxygen atom.
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