**Which of the following equations does NOT show the correct main products?****a.**- Reactants: - HO-CH2CH=CH2 - 1. BH3, THF - 2. H2O2/NaOH- Products: - HO-CH2CH2CH2OH**b.**- Reactants: - HO-CH2CH=CH2 - Hg(OAc)2, H2SO4, H2O- Products: - HO-CH2CHO**c.**- Reactants: - HO-CH2CH=CH2 - 1. Hg(OAc)2, H2O - 2. NaBH4/NaOH- Products: - HO-CH2CH2CH2OH**d.**- Reactants: - HO-CH2CH=CH2 - 1. BHSia2, THF - 2. H2O2/NaOH- Products: - HO-CH(CH3)CHO---For understanding:- **Option a**: Hydroboration-oxidation results in syn hydration to form a 1,3-diol.- **Option b**: Oxymercuration-reduction leads to the formation of an aldehyde.- **Option c**: Oxymercuration-reduction produces a diol, which is correct for similar reactions.- **Option d**: Hydroboration with BHSia2 forms an aldehyde, indicating a syn addition with rearrangement.The incorrect main product in this sequence is under option **b**, since typical oxymercuration should lead to a Markovnikov addition of water without further oxidation to an aldehyde.

Given are four organic reactions, Out of which , a and d are hydroboration followed by oxidation…

Which of the following equations does NOT show the correct main products? O a. HO 1. Вн, THF 2. H2O NaOH но но. Ob. но Hg(OAc)2 HSO, HO но H. О с. HO 1. Hg(OAc)2, H2O 2. NaBH/NAOH HO, O d. 1. BHSI ,, THF. 2. H2ON2OH но но

Which of the following equations does NOT show the correct main products? O a. HO 1. Вн, THF 2. H2O NaOH но но. Ob. но Hg(OAc)2 HSO, HO но H. О с. HO 1. Hg(OAc)2, H2O 2. NaBH/NAOH HO, O d. 1. BHSI ,, THF. 2. H2ON2OH но но

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

**Which of the following equations does NOT show the correct main products?**

**a.**

- Reactants:
- HO-CH2CH=CH2
- 1. BH3, THF
- 2. H2O2/NaOH
- Products:
- HO-CH2CH2CH2OH

**b.**

- Reactants:
- HO-CH2CH=CH2
- Hg(OAc)2, H2SO4, H2O
- Products:
- HO-CH2CHO

**c.**

- Reactants:
- HO-CH2CH=CH2
- 1. Hg(OAc)2, H2O
- 2. NaBH4/NaOH
- Products:
- HO-CH2CH2CH2OH

**d.**

- Reactants:
- HO-CH2CH=CH2
- 1. BHSia2, THF
- 2. H2O2/NaOH
- Products:
- HO-CH(CH3)CHO

---

For understanding:

- **Option a**: Hydroboration-oxidation results in syn hydration to form a 1,3-diol.
- **Option b**: Oxymercuration-reduction leads to the formation of an aldehyde.
- **Option c**: Oxymercuration-reduction produces a diol, which is correct for similar reactions.
- **Option d**: Hydroboration with BHSia2 forms an aldehyde, indicating a syn addition with rearrangement.

The incorrect main product in this sequence is under option **b**, since typical oxymercuration should lead to a Markovnikov addition of water without further oxidation to an aldehyde.

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