Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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#10.

Transcribed Image Text:Which of the following compounds has the highest boiling point?
tou
OH
OH
OH
OH
HO
IV
Multiple Choice
IV
Expert Solution

Step 1
Boiling point of alcohols :
1). Alcohols can form hydrogen bonding(a strong intermolecular force). Hence if more number of hydroxy groups (-OH groups) are present then it can form more hydrogen bonding. Hence more will be the boiling point.
2). If the two alcohols are the constitutional isomers(i.e. Same molecular formula but different connectivity) then Larger molecules(long chain) has higher boiling point. Because larger molecules have the greater surface area, so more energy needed. Therefore more boiling point.
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