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Which of the following compounds has a higher boiling point? CH3 A :0: ОН CH3 B :0: || ÖCH3

Which of the following compounds has a higher boiling point? CH3 A :0: ОН CH3 B :0: || ÖCH3

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Understanding Boiling Points of Compounds** The question presented is: "Which of the following compounds has a higher boiling point?" **Diagrams of Compounds:** - **Compound A**: - Structure: Acetic acid - Chemical Formula: CH₃COOH - Features a carbonyl group (C=O) and a hydroxyl group (–OH). - **Compound B**: - Structure: Methyl acetate - Chemical Formula: CH₃COOCH₃ - Features an ester linkage, with an oxygen atom bonded to a methyl group (–OCH₃). **Key Concepts:** 1. **Hydrogen Bonding**: - **Compound A** can form hydrogen bonds due to its hydroxyl (–OH) group. - **Compound B** does not have a –OH group and thus cannot form hydrogen bonds. 2. **Effect on Boiling Point**: - Hydrogen bonding typically increases the boiling point due to additional intermolecular forces. - Therefore, **Compound A** is likely to have a higher boiling point than **Compound B**. **Options:** - A) Compound A - B) Compound B Considering the ability to form hydrogen bonds, Compound A is expected to have a higher boiling point.
Transcribed Image Text:**Understanding Boiling Points of Compounds** The question presented is: "Which of the following compounds has a higher boiling point?" **Diagrams of Compounds:** - **Compound A**: - Structure: Acetic acid - Chemical Formula: CH₃COOH - Features a carbonyl group (C=O) and a hydroxyl group (–OH). - **Compound B**: - Structure: Methyl acetate - Chemical Formula: CH₃COOCH₃ - Features an ester linkage, with an oxygen atom bonded to a methyl group (–OCH₃). **Key Concepts:** 1. **Hydrogen Bonding**: - **Compound A** can form hydrogen bonds due to its hydroxyl (–OH) group. - **Compound B** does not have a –OH group and thus cannot form hydrogen bonds. 2. **Effect on Boiling Point**: - Hydrogen bonding typically increases the boiling point due to additional intermolecular forces. - Therefore, **Compound A** is likely to have a higher boiling point than **Compound B**. **Options:** - A) Compound A - B) Compound B Considering the ability to form hydrogen bonds, Compound A is expected to have a higher boiling point.
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