Which of the following combinations would be best to buffer an aqueous solution at a pH of 9.0?  NH4+ and NH3, Ka = 5.7E-10  HNO2 and NO2–, Ka = 4.5E-4  H2PO4– and HPO42–, Ka2 = 6.2E-8  CH3CO2H and CH3COO–, Ka = 1.8E-5  H3PO4 and H2PO4–, Ka1 = 7.5E-3

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Which of the following combinations would be best to buffer an aqueous solution at a pH of 9.0?


 NH4+ and NH3Ka = 5.7E-10
 HNO2 and NO2Ka = 4.5E-4
 H2PO4 and HPO42–Ka2 = 6.2E-8
 CH3CO2H and CH3COOKa = 1.8E-5
 H3PO4 and H2PO4Ka1 = 7.5E-3
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