Which of the following alkyl halides gives the slowest SN2 reaction? O 1-chloro ethane O 1-chloro-2-methyl propane 2-chloro-2-methyl butane 1-chloro-2-methyl butane
Which of the following alkyl halides gives the slowest SN2 reaction? O 1-chloro ethane O 1-chloro-2-methyl propane 2-chloro-2-methyl butane 1-chloro-2-methyl butane
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Question:**
Which of the following alkyl halides gives the *slowest* S<sub>N</sub>2 reaction?
**Options:**
- ○ 1-chloro ethane
- ○ 1-chloro-2-methyl propane
- ○ 2-chloro-2-methyl butane
- ○ 1-chloro-2-methyl butane
This question asks about the rate of S<sub>N</sub>2 reactions for different alkyl halides. In S<sub>N</sub>2 reactions, the nucleophile attacks the electrophilic carbon from the rear side, leading to the simultaneous displacement of the leaving group. The rate of the reaction is influenced by steric hindrance around the electrophilic carbon; hence, primary alkyl halides typically have faster S<sub>N</sub>2 reactions than secondary or tertiary ones. The question requires analyzing which compound is most sterically hindered and thus reacts the slowest via an S<sub>N</sub>2 mechanism.
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