Which of the following acids cannot be used with ammonia (NH3) as a solvent due to the leveling effect? ethanol acetone OH pKa = 16.0 H pKa = 19.2 H- acetylene pKa = 25 H
Which of the following acids cannot be used with ammonia (NH3) as a solvent due to the leveling effect? ethanol acetone OH pKa = 16.0 H pKa = 19.2 H- acetylene pKa = 25 H
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Which of the following acids cannot be used with ammonia (NH3) as a solvent due to the leveling effect?
ethanol
acetone
OH
pKa = 16.0
H
pka = 19.2
H
acetylene
acetic acid
pKa = 25
'OH
pka = 4.75
-H
Expert Solution

Step 1
The leveling effect is described as the inability of a solvent to differentiate among relative strengths of all stronger acids than the solvent’s conjugate acid. Essentially, the effects of a strong acid or base are ‘leveled,’ or limited, in the presence of water.
OR
Leveling effect or solvent leveling refers to the effect of solvent on the properties of acids and bases. The strength of a strong acid is limited by the basicity of the solvent. Similarly the strength of a strong base is leveled by the acidity of the solvent. All the power, not all the cost.
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