Which metal center does not obey the 18-electron rule? a. Fe in Fe(n5-C5H4COME)2 b. Co in Co2(CO)8 (single metal-metal bond) C. Ru in [Ru(n6-C6ME6)2]2+ d. V in V(CO)6

Q: 4. State whether you expect the following complexes to exhibit. strong or weak distortion? a.…

A: Jahn teller distortion:- Jahn Teller distortion is a geometric distortion of a non-linear molecule…

Q: What is the formula for bromobis(ethylenediamine)vana a. [VBr3(en)2] O b. [VBr(en)2]Br C.…

A: Iupac nomenclature of coordination compound is written by ligands and centeral atom

Q: The quantities provided were used for Step 1 in the synthesis of FeC₂O4 • 2 H₂O. (NH₂)₂…

A: #Q.1: The balanced equation for thesynthesis of FeC2O4*2H2O is: (NH4)2[Fe(H2O)6](SO4)2(aq) +…

Q: What is meant by fixing C and N? What metal centers are used for this chemistry?

A: Nitrogen fixation :The nitrogen fixation is the process in which atmospheric nitrogen is converted…

Q: The π* orbital of NO is partially filled with an unpaired electron, which makes it less efficient in…

A: We have to tell between NO and CO which one is stronger π-acceptor ligand.

Q: Choose the correct shape, weak or strong field, and number of unpaired electrons for…

A:

Q: ase exp

A: Coordination complexes are formed by joining the central metal ion with the negatively charged…

Q: Consider the coordination compound (NH4)2[Os(en)(CN)4], the coordination number (C.N.) and oxidation…

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Q: which of the following has the greatest No. of unpaired electron? Select one: а. [Mn(CN)2- b.…

A: Unpaired electron represents single electron in 1 orbital .

Q: Determine if the following metal complexes obey the 18-electron rule. а. НMn(CO)4 b. [W(CO);CI] c.…

A:

Q: Answer the following: What is the primary and secondary valence of the central metal in Na₂[CuCl4]?…

A: A) Primary valency and secondary valency of NA2[CuCl4] are 2 and 4 respectively B) D orbit split in…

Q: A. Determine the oxidation state of the metal ion in  [Fe(CN)6]4−. B. Determine the coordination…

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Q: Draw all possible stereoisomers, including any enantiomers for the following compounds. a.…

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Q: 19. Which of the following is diamagnetic?  Z of Kr= 36,  Cu = 29,   K = 19,  Mn = 55 a. K b. Kr…

A: Diamagnetic elements are detemined by observing the number of  electrons in their subshells. The…

Q: Which pair of complex and magnetic properties is correct? Select one: O a. [Fe(en), (NH3)2 ]CI₂;…

A: This question belong to coordination compounds.  Paramagnetic: unpaired electron Diamagnetic: No…

Q: The following show optical isomerism, EXCEPT:

A: Optical activity : the property of  rotation of plane polarised light is called optical activity…

Q: Which one of the following cannot exhibit linkage isomerism? O K2[Ni(NC)2CI2] O Cu(NO2)2(NH3)2 O…

A: Linkage isomerism: Isomer complex in which the ligand co ordinates to the metal. For eg. Nitrite

Q: Select the metal centre with d2sp3 hybridization. a.[Rh(acac)3] b.[RuMe2(bpy)2] c.[RhCl3(PMe3)]…

A: The above problem can be solved using the valancy bond theory.  Which states about strong field and…

Q: What is the coordination of the cobalt ion in the compound: K[Co(ox)2CI(H2O)] ? А. 4-coordinate,…

A: Given-> K2[Co(ox)2Cl(H2O)]

Q: Consider the coordination compound [Pt(NH3)4(OH)2]SO4 and identify ligands ? a. NH3 , OH- O b. OH ,…

A: Ligands in the above coordinated complex are given below

Q: Co(NH3)6+3 (Kf = 5.0 x 1031) is more stable as compared to Ag(CN)2 (Kf = 1.0 x1021) True O False

A: The given formation constant values along with the chemical equation are: Co3+(aq) + 6NH3(aq) ⇌…

Q: i Melting point of Nacl is lower than Mgo why? ii. Br is less reactive than F, why? I iil. Complete…

A: According to the Q & A guidelines of Bartleby, I am allowed to answer only three sub-parts of…

Q: What is the geometry for the [Cr(H2O)4CI2] compound? O A. Square planar B. Tetrahedral OC. Trigonal…

A: We have to tell which option is correct from given choices of options by telling what is geometry of…

Q: Determine the oxidation state of the metal ion in [Co(NH3)5Br]2+ Determine the coordination number…

A: To determine the oxidation state and coordination number of the given complexes. Answering the first…

Q: For the complex [Co(H20)61*, is the magnetic moment, Pobs. O a. Temp. dep and Hobs<Hs.0 O b. almost…

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Q: Consider the compound: bis(ethylenediamine)-cis-dinitratroiron(X) cation. Where X is the appropriate…

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Q: What is the oxidation number of the metal center? (please show the charges of the ligands).

A:

Q: Complex or Compound Name Metal Metal d Charge electrons Molecular Geometry Obeys 18- electron rule?

A: Here we have to write the name of the given complex, the oxidation state of Ru , number of metal d…

Q: 18. Isomeric cobalt compounds and [Co(NH3)sBr]SO4 are red and violet respectively. Which of the…

A: Isomeric structures are [Co(NH3)5Br]SO4    and [Co(NH3)5SO4]Br Among them [Co(NH3)5SO4]Br is red in…

Q: Consider the coordination compound [Ni(C204)2(H20)2]Cl2 and identify ligands O a. H20, CI- O b. C204…

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Q: Determine if the following satisfy the 18-electron rule. Show all work! [Co(NH3)5Cl]2+ [V(CO)5H]+…

A: 18 electron rule says that thermodynamically most stable transition metal compounds contain 18…

Q: Draw the structures and label the type for all the isomers of each ion. a. (Cr(CO),(NH,),+ b.…

A: Isomers are having the same number of atoms of each element but different arrangements of atoms in…

Q: Which iron species will have the greatest propensity to bond to carbon monoxide (remember CO binds…

A: Transition metals can form coordination complexes with carbon monoxide ligands using synergistic pi…

Q: 23. Which of the following statements is/are TRUE? o In a tetrahedral crystal field, the d electrons…

A: Tetrahedra complexes are always high spin complexes but octahedral complexes form both high spin and…

Q: Name these coordination compounds. formula Na [AUCI, (H₂O)] [VC1,(CO),]C!, [PtBr₂ (NH₂). Cl₂ name 0…

A: 1) Na[AuCl4(H2O)2]The name of this coordination compound is Sodium tetrachloroaurate(III)…

Q: Consider the following oxidation reaction [Cr(H2O)6]²* [Cr(H2O);]³* + e- a. Calculate the change in…

A: CFSE is the amount of energy gained by the orbital after preferential filling of the orbital by the…

Q: a. Cu(s) b. [Cu(H₂O)]2+ (aq) c. Cu(OH)2(s) d. CuO(s)

A: The objective of the question is to identify the substances in which copper is an ion or an atom.

Q: 4. Which element has higher second ionization energy? Cr or Mn:

A: Since you have asked multiple question, we will solve the first question for you. If you want any…

Q: How many isomers are possible for the species [Co(en)2(CI)2]*, Cr(NH3)3(OH)3, and tetrahedral…

A: Number of isomers possible depends upon the different type of arrangements of atom with the central…

Q: 23. A prussian blue precipitate of is an indication that Nitrogen is present. " Na4[Fe(CN)6] O…

A: Below attached file showing the details answer.  All the best

Q: Select the metal centre with d2sp3 hybridization. О а. [Rh(acac)3] O b. [Ru(acac)2(H2O)2] Ос.…

A:

Q: Which of the elements go into complete addition solution (space positions or interstitial) with Ni?

A: Given

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.