Which functional group might be present in a compound if it shows IR absorptions at 1715 cm1 and 2500-3100 cm¯1 (broad)? A) alcohol B) ether C) ester D) carboxylic acid E) aldehyde
Which functional group might be present in a compound if it shows IR absorptions at 1715 cm1 and 2500-3100 cm¯1 (broad)? A) alcohol B) ether C) ester D) carboxylic acid E) aldehyde
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Infrared Spectroscopy in Functional Group Identification**
**Question:**
Which functional group might be present in a compound if it shows IR absorptions at 1715 cm⁻¹ and 2500-3100 cm⁻¹ (broad)?
**Answer Choices:**
- A) Alcohol
- B) Ether
- C) Ester
- D) Carboxylic acid
- E) Aldehyde
**Explanation:**
Infrared (IR) spectroscopy is a powerful tool for identifying functional groups in organic compounds. Specific absorption bands correspond to different molecular vibrations, which are characteristic of certain functional groups.
- **1715 cm⁻¹**: This absorption is typically associated with the C=O (carbonyl) stretch.
- **2500-3100 cm⁻¹ (broad)**: This broad band indicates the presence of O-H stretch, often seen in carboxylic acids due to hydrogen-bonded hydroxyl groups.
Based on the absorption characteristics provided, the functional group that fits these IR absorption ranges is **D) Carboxylic acid**. This group features both a carbonyl stretch around 1715 cm⁻¹ and a broad O-H stretch between 2500-3100 cm⁻¹.
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