Which buffer system is the best choice to create a buffer with pH = 7.30 ? HCIO2/KCIO2 HC2H3O2/KC2H3O2 NH3/NHẠC1 HCIO/KCIO Previous Answers Correct The effective range for a buffering system is one pH unit on either side of pKa . Therefore, calculate the pKa for each buffer system. For HC2H302/KC2H302 pKa - log Ka - log(1.8 x 10-5 4.74 For HCIO2/KCIO2 ,pKa = 1.96 ; for HCIO/KCIO , pKa = 7.54 ; and, for NH3/NHẠC1 pka = 14.00 – pKb = 14.00 – 4.754 9.25 So, HCIO/КCIO is the best choice to create a buffer with pH = 7.30 because HCIO has the pKa value that is closest to 7.30. Part B For the best system, calculate the ratio of the masses of the buffer components required to make the buffer. Express your answer to two significant figures.
Which buffer system is the best choice to create a buffer with pH = 7.30 ? HCIO2/KCIO2 HC2H3O2/KC2H3O2 NH3/NHẠC1 HCIO/KCIO Previous Answers Correct The effective range for a buffering system is one pH unit on either side of pKa . Therefore, calculate the pKa for each buffer system. For HC2H302/KC2H302 pKa - log Ka - log(1.8 x 10-5 4.74 For HCIO2/KCIO2 ,pKa = 1.96 ; for HCIO/KCIO , pKa = 7.54 ; and, for NH3/NHẠC1 pka = 14.00 – pKb = 14.00 – 4.754 9.25 So, HCIO/КCIO is the best choice to create a buffer with pH = 7.30 because HCIO has the pKa value that is closest to 7.30. Part B For the best system, calculate the ratio of the masses of the buffer components required to make the buffer. Express your answer to two significant figures.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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need help with part B

Transcribed Image Text:MISSED THIS? Read Section 18.3 (Pages 799 - 802) .
The following table shows the values of ionization constants for a number of
acids and bases at 25 °C :
Which buffer system is the best choice to create a buffer with pH = 7.30 ?
Formula
Ка
Kb
HC1O2/KC1O2
HC2H302
1.8 × 10–5
HC102
HC2H302/KC2H3O2
1.1 x 10–2
NH3
1.76 × 10–5
NH3/NHẠC1
HCIO
2.9 × 10–8
HC10/KCIO
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Previous Answers
v Correct
The effective range for a buffering system is one pH unit on either side of pKa . Therefore, calculate the pKa for each buffer system. For HC2H3O2/KC2H3O2
- log Ka
- log(1.8 x 10-9
pKa
4.74
For HC102/KC1O2
, pKa = 1.96 ; for HC10/KCIO
, pKa= 7.54
; and, for NH3/NH4C1
pKa =
14.00 — рКъ
14.00 – 4.754
9.25
So, HC10/KC1O
is the best choice to create a buffer with pH = 7.30
because HC10 has the pKa value that is closest to 7.30.
Part B
For the best system, calculate the ratio of the masses of the buffer components required to make the buffer.
Express your answer to two significant figures.
i (3 ED ?
Не
Be
m(KC10)
= |0.578
m(HCIO)
Submit
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