When exposed to air benzaldehyde oxidizes to benzoic acid. If the benzaldehyde used in the thesis of benzoin is contaminated with benzoic acid, how would this affect the pH of the reaction ture? What purpose does the NaOH serve in the thiamine catalyzed condensation of benzaldehyde to pare benzoin? Propose a detailed mechanism for the thiamine catalyzed condensation of benzaldehyde to form zoin

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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2
benzaldehyde
Scheme 1. Multi-Step Synthesis of Phenytoin
thiamine HCI
NaOH, EtOH
oso
HẠN NH2
NaOH
EtOH
OH
benzoin
HN,
-NH
5,5-diphenylhydantoin
(DilantinE)
HNO3
benzil
Q1) When exposed to air benzaldehyde oxidizes to benzoic acid. If the benzaldehyde used in the
synthesis of benzoin is contaminated with benzoic acid, how would this affect the pH of the reaction
mixture?
Q2) What purpose does the NaOH serve in the thiamine catalyzed condensation of benzaldehyde to
prepare benzoin?
Q3) Propose a detailed mechanism for the thiamine catalyzed condensation of benzaldehyde to form
benzoin
Transcribed Image Text:2 benzaldehyde Scheme 1. Multi-Step Synthesis of Phenytoin thiamine HCI NaOH, EtOH oso HẠN NH2 NaOH EtOH OH benzoin HN, -NH 5,5-diphenylhydantoin (DilantinE) HNO3 benzil Q1) When exposed to air benzaldehyde oxidizes to benzoic acid. If the benzaldehyde used in the synthesis of benzoin is contaminated with benzoic acid, how would this affect the pH of the reaction mixture? Q2) What purpose does the NaOH serve in the thiamine catalyzed condensation of benzaldehyde to prepare benzoin? Q3) Propose a detailed mechanism for the thiamine catalyzed condensation of benzaldehyde to form benzoin
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